Doped Graphene Substrate Regions for Electronic Property Differentiation

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Solution Overview

Problem

Existing electronic devices lack the ability to efficiently create regions with distinct electronic properties on a graphene substrate, limiting their functionality in forming advanced components like diodes, transistors, and sensors.

Innovation Solution

The creation of graphene substrates with defined regions differing in electronic properties through chemical functionalization with specific dopant species, allowing for the formation of semiconducting junctions and various electronic components by varying the dopant species, concentrations, and attachment patterns.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Adaptability or versatility

If chemical functionalization with dopant species is applied to graphene substrate, then regions with distinct electronic properties (n-type, p-type) can be formed, but the manufacturing complexity and process difficulty increase

Engineering Contradiction:
Improveelectronic property differentiationVSAvoidfabrication process simplicity
Core Design Contradiction:
Adaptability or versatilityVSEase of manufacture

Solution Approach 1:

The patent applies local quality by functionalizing specific defined regions of the graphene substrate with different dopant species (n-type dopants like nitrogen in one region, p-type dopants like boron in another region). This creates spatially differentiated electronic properties (electron-rich n-type regions and hole-rich p-type regions) within the same graphene sheet, enabling region-specific electronic behavior without affecting the entire substrate.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent segments the graphene substrate into multiple defined regions, each with distinct dopant functionalization. This segmentation allows independent control of electronic properties in different areas, creating n-type and p-type regions that can be independently optimized and integrated into complex electronic device architectures.

Inventive Principle:
Principle #1Segmentation

2Adaptability or versatility

If multiple dopant species are used to create distinct electronic regions, then functionality for advanced components (diodes, transistors, sensors) is enabled, but device complexity increases

Engineering Contradiction:
Improvecomponent functionalityVSAvoidstructure complexity
Core Design Contradiction:
Adaptability or versatilityVSDevice complexity

Solution Approach 1:

The patent applies universality by using a single graphene substrate material that can serve multiple functional roles through differential dopant functionalization. The same base material (graphene) provides both n-type and p-type regions, as well as neutral interconnect regions, eliminating the need for multiple different material layers and simplifying the overall device structure while maintaining high functionality.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Solution Approach 2:

By applying different dopant species to different defined regions of the graphene substrate, the patent creates local quality variations that enable distinct electronic functions (rectification in diodes, switching in transistors, detection in sensors) within a unified structure, reducing the need for complex multi-material assemblies.

Inventive Principle:
Principle #3Local quality

3Adaptability or versatility

If dopant concentration and attachment pattern are varied to tailor electronic properties, then performance optimization is achieved, but manufacturing precision requirements increase

Engineering Contradiction:
Improveelectronic property tailoringVSAvoiddopant concentration control
Core Design Contradiction:
Adaptability or versatilityVSManufacturing precision

Solution Approach 1:

The patent applies parameter changes by systematically varying dopant concentration, dopant species type, and attachment patterns across different defined regions of the graphene substrate. This enables precise tuning of electronic properties (carrier density, mobility, Fermi level positioning) in each region to optimize performance for specific device functions while maintaining controllable manufacturing parameters.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Enables the fabrication of advanced electronic and optoelectronic devices with tailored properties, enhancing their performance and functionality by forming regions with specific electronic characteristics, such as n-type and p-type regions, and adjusting Fermi levels, band structures, and carrier populations.

Implementation Method 1

The first dopant species may be adsorbed onto the graphene substrate (e.g., chemisorbed or physisorbed), chemically bound to the substrate (e.g., covalently bound), or intercalated in the graphene substrate

Methodology Applied
Scientific EffectChemisorption: Chemisorption

Implementation Method 2

The first dopant species may be adsorbed onto the graphene substrate (e.g., chemisorbed or physisorbed), chemically bound to the substrate (e.g., covalently bound), or intercalated in the graphene substrate

Methodology Applied
Scientific EffectPhysisorption: Physisorption

Data Source

PatentUS8278643B2Doped graphene electronic materials
Publication Date: 2012.10.02 ENTERPRISE SCIENCE FUND LLC
  • US8278643B2 patent drawing
  • US8278643B2 patent drawing
  • US8278643B2 patent drawing

AI summary

A graphene substrate is doped with one or more functional groups to form an electronic device.