Doped Proppant Neutron Logging for Fracture Detection

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Solution Overview

Problem

Current methods for locating induced subterranean fractures in hydraulic fracturing operations are limited by the need for radioactive materials, complex detection equipment, shallow investigation depth, potential hazards, and high costs, which hinder effective identification of fractured zones and their extent.

Innovation Solution

A method using a pulsed neutron capture tool or compensated neutron tool with proppants doped with thermal neutron absorbing materials like boron carbide or gadolinium oxide, allowing for the differentiation of propped and unpropped fractures through changes in neutron count rates and capture cross-sections, enabling deeper investigation and cost-effective fracture location.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Measurement precision

If radioactive materials and complex detection equipment are used to locate induced fractures, then measurement precision is improved, but device complexity and cost increase

Engineering Contradiction:
Improvefracture location detection accuracyVSAvoiddetection equipment complexity
Core Design Contradiction:
Measurement precisionVSDevice complexity

Solution Approach 1:

The patent extracts the detection function from complex radioactive equipment and implements it using simple neutron capture tools with doped proppants. The proppants are doped with thermal neutron absorbing materials like boron carbide or gadolinium oxide, which can be detected by standard neutron capture tools, eliminating the need for specialized radioactive detection equipment while maintaining fracture location accuracy.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent uses inexpensive doped proppants that can be easily prepared and disposed of after the fracturing operation. These proppants contain thermal neutron absorbing materials that provide detectable signals during the logging process, replacing expensive radioactive tracers with cost-effective alternatives that achieve the same detection purpose.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

2Measurement precision

If radioactive materials are used for fracture identification, then measurement precision is improved, but safety hazards increase

Engineering Contradiction:
Improvefracture zone identification accuracyVSAvoidradiation safety hazards
Core Design Contradiction:
Measurement precisionVSObject-affected harmful factors

Solution Approach 1:

The patent converts the potentially harmful radioactive materials into beneficial thermal neutron absorbing materials. By using boron carbide or gadolinium oxide-doped proppants, the system achieves fracture identification through neutron capture rather than radioactive decay, eliminating radiation safety hazards while improving detection capability through the unique neutron absorption properties of the dopant materials.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

3Length of stationary object

If conventional neutron tools are used, then investigation depth is limited, but if doped proppants are used with pulsed neutron capture tools, then investigation depth increases and fracture extent can be better determined

Engineering Contradiction:
Improvefracture investigation depthVSAvoidneutron tool complexity
Core Design Contradiction:
Length of stationary objectVSDevice complexity

Solution Approach 1:

The patent changes the physical parameter of the proppants by doping them with thermal neutron absorbing materials. This modification alters the neutron capture characteristics, enabling pulsed neutron capture tools to detect fractures at greater depths. The dopant materials create distinct neutron capture signatures that enhance the detection signal and extend the effective investigation depth beyond conventional tool capabilities.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach eliminates the need for radioactive materials and complex equipment, providing deeper fracture investigation and cost savings while accurately identifying fractured zones and their extent, facilitating more effective hydraulic fracturing operations.

Implementation Method 1

emitting neutrons from the neutron source into the borehole and formation and detecting in the borehole region thermal neutrons or capture gamma rays resulting from nuclear reactions of the source neutrons with elements in the borehole region and subterranean formation

Methodology Applied
Scientific EffectNeutron capture: Nuclear Fission

Implementation Method 2

a proppant in which all or a fraction of such proppant includes a thermal neutron absorbing material... having a macroscopic thermal neutron capture cross-section exceeding that of elements normally encountered in subterranean zones to be fractured

Methodology Applied
Scientific EffectThermal neutron absorption: Nuclear Fission

Data Source

PatentUS8214151B2Methods of identifying high neutron capture cross section doped proppant in induced subterranean formation fractures
Publication Date: 2012.07.03 CARBO CERAMICS INC
  • US8214151B2 patent drawing
  • US8214151B2 patent drawing
  • US8214151B2 patent drawing

AI summary

Methods are provided for determining the locations and heights of fractures in a subterranean formation using a neutron-emitting logging tool. Utilizing predetermined relationships (1) between logging tool count rates and associated apparent formation hydrogen index values and (2) between logging tool count rate ratios and associated apparent formation hydrogen index values, the methods detect the presence and heights in the formation of proppant containing high thermal neutron capture cross section material in a manner substantially eliminating proppant determination uncertainty resulting from a prior change in formation hydrogen index values. A second, associated, method employing logging tool count rates and count rate ratios to determine the presence of proppant containing high thermal neutron capture cross section absorbers utilizes a crossplot of count rate versus ratio. Logged intervals containing no proppant will fall on a trend/trendline on the crossplot, whereas logged intervals containing proppant will fall off from this trend/trendline.