Doped Silicon Capping Layer for High-k Gate Stack

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Solution Overview

Problem

The integration of high-k dielectric materials with traditional polycrystalline silicon gate electrodes in semiconductor devices leads to high threshold voltage and low channel mobility, primarily due to defects at the interface, resulting in unacceptably high AC gate impedance, which affects device performance and scalability.

Innovation Solution

The implementation of a doped silicon-comprising capping layer interposed between the metal and polycrystalline silicon layers in the gate electrode stack, which can react with a silicide-forming metal capping layer to form a metal silicide, reducing interfacial defects and enhancing conductivity.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If high-k dielectric materials are combined with traditional polycrystalline silicon gate electrodes, then gate insulation performance is improved, but threshold voltage increases and channel mobility decreases

Engineering Contradiction:
Improvegate insulation performanceVSAvoidinterface defects
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

A doped silicon capping layer is introduced as an intermediary between the high-k dielectric material and the polycrystalline silicon gate electrode. This intermediate layer reduces interfacial defects and improves the electrical characteristics of the gate stack, thereby resolving the contradiction between maintaining good gate insulation and avoiding threshold voltage shift and mobility degradation caused by interface defects.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Power

If metal gate layers are added to polycrystalline silicon electrodes, then DC resistance is reduced, but AC gate impedance becomes unacceptably high

Engineering Contradiction:
ImproveDC resistanceVSAvoidAC gate impedance
Core Design Contradiction:
PowerVSObject-generated harmful factors

Solution Approach 1:

The doped silicon capping layer serves as a mediator between the metal gate layer and the polycrystalline silicon electrode. This layer reduces defects at the metal/polycrystalline silicon interface that cause high AC gate impedance, while allowing the metal layer to maintain its low DC resistance property, thus resolving the contradiction between DC resistance reduction and AC impedance control.

Inventive Principle:
Principle #24Intermediary (Mediator)

3Productivity

If critical dimensions are reduced for technology scaling, then device density is improved, but leakage current increases

Engineering Contradiction:
Improvedevice densityVSAvoidleakage current
Core Design Contradiction:
ProductivityVSLoss of energy

Solution Approach 1:

The gate stack employs a composite structure consisting of high-k dielectric material combined with a doped silicon capping layer and metal gate layer. This composite material approach allows the use of thicker effective gate insulation to reduce leakage current while maintaining scaled dimensions, thereby enabling continued technology scaling without excessive leakage penalties.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This configuration effectively lowers AC impedance, improves device performance by reducing defects, and enables further scalability and compatibility with high-k dielectric gate insulators, enhancing the operational frequency and drive current of transistors.

Implementation Method 1

forming a doped silicon-comprising capping layer overlying the metal-comprising gate layer, and depositing a silicon-comprising gate layer overlying the doped silicon-comprising capping layer

Methodology Applied
Scientific EffectSilicide formation reaction: Chemical Bonding

Data Source

PatentUS8026539B2Metal oxide semiconductor devices having doped silicon-comprising capping layers and methods for fabricating the same
Publication Date: 2011.09.27 GLOBALFOUNDRIES US INC
  • US8026539B2 patent drawing
  • US8026539B2 patent drawing
  • US8026539B2 patent drawing

AI summary

Methods are provided for forming a semiconductor device comprising a semiconductor substrate. In accordance with an exemplary embodiment, a method comprises the steps of forming a high-k dielectric layer overlying the semiconductor substrate, forming a metal-comprising gate layer overlying the high-k dielectric layer, forming a doped silicon-comprising capping layer overlying the metal-comprising gate layer, and depositing a silicon-comprising gate layer overlying the doped silicon-comprising capping layer.