Selective Etching of Doped Silicon Dioxide Tiers in 3D NAND Memory Arrays

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Solution Overview

Problem

Current methods for forming memory arrays, such as NAND architecture, face challenges in efficiently creating vertically-stacked memory cells with precise control over gate structures and charge-blocking regions, which affect the reliability and retention time of memory cells.

Innovation Solution

A 'gate-last' or 'replacement-gate' process is employed, where a stack of vertically-alternating insulative and conductive tiers is formed, with channel openings etched to create memory-block regions, and selective etching is used to divide charge-blocking and storage material strings into vertically-spaced segments, followed by the formation of conducting material to create wordlines and memory cells.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If conventional methods are used to form vertically-stacked memory cells, then the manufacturing process is simpler, but the precision and reliability of gate structures and charge-blocking regions deteriorate

Engineering Contradiction:
Improveprecision of gate structures and charge-blocking regionsVSAvoidcomplexity of manufacturing process
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The manufacturing process is divided into distinct sequential steps: forming the stack with insulative and conductive tiers, etching channel openings, depositing charge-blocking material, forming storage material, and creating gate structures. Each step builds upon the previous one to achieve precise control over gate structures and charge-blocking regions while maintaining a manageable process complexity through systematic segmentation.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The stack comprising vertically-alternating insulative and conductive tiers is formed in advance before the memory cells are actually created. This preliminary formation of the stacked structure with precisely controlled layers enables subsequent precise positioning of gate structures and charge-blocking regions without requiring complex real-time adjustments during cell formation.

Inventive Principle:
Principle #10Preliminary action

2Duration of action of stationary object

If vertically-stacked memory cells are formed with precise control over gate structures, then retention time improves, but manufacturing complexity increases

Engineering Contradiction:
Improveretention time of memory cellsVSAvoidcomplexity of forming process
Core Design Contradiction:
Duration of action of stationary objectVSDevice complexity

Solution Approach 1:

Different regions of the memory cell structure are given different materials and properties: insulative tiers for electrical isolation, conductive tiers for wordline formation, charge-blocking material for charge confinement, and storage material for data retention. This local differentiation of material properties enables precise control over gate structures and charge-blocking regions, improving retention time while keeping the overall process manageable through localized rather than global complexity.

Inventive Principle:
Principle #3Local quality

Data Source

PatentUS11495610B2Integrated circuitry, a method used in forming integrated circuitry, and a method used in forming a memory array comprising strings of memory cells
Publication Date: 2022.11.08 MICRON TECHNOLOGY INC
  • US11495610B2 patent drawing
  • US11495610B2 patent drawing
  • US11495610B2 patent drawing

AI summary

A method used in forming a memory array comprising strings of memory cells comprises forming a stack comprising vertically-alternating first tiers and second tiers. The second tiers comprise doped silicon dioxide and the first tiers comprise a material other than doped silicon dioxide. The stack comprises laterally-spaced memory-block regions. Channel-material-string constructions extend through the first tiers and the second tiers in the memory-block regions. The doped silicon dioxide that is in the second tiers is etched selectively relative to said other material that is in the first tiers and selectively relative to and to expose an undoped silicon dioxide-comprising string of a charge-blocking material that is part of individual of the channel-material-string constructions. Structure independent of method is disclosed.