Doped ta-C Cover Layer for Fuel Cell Bipolar Plate Corrosion

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Solution Overview

Problem

Bipolar plates in fuel cells face corrosion and dissolution under aggressive operating conditions, leading to reduced long-term stability despite corrosion-protective coatings, which fail under unfavorable conditions.

Innovation Solution

A layer system comprising a first metallic layer, a second metallic layer doped with non-metals, and a cover layer of doped tetrahedral amorphous carbon (ta-C:X) with specific dopants, providing excellent corrosion protection and high electrical conductivity, produced through physical vapor deposition techniques.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If a corrosion-protective coating is applied to a metallic bipolar plate substrate, then corrosion protection is improved, but the coating fails under unfavorable operating conditions leading to localized corrosion

Engineering Contradiction:
Improvecorrosion protectionVSAvoidcoating damage and localized corrosion
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent applies a multi-layer composite coating system consisting of a metallic first layer (e.g., titanium, nickel, or their alloys), a non-metallic second layer (e.g., diamond-like carbon, ceramic, or polymer), and an intermediate layer. This composite structure combines the corrosion resistance of metals with the chemical inertness and mechanical stability of non-metals, creating a coating system that maintains integrity under aggressive fuel cell operating conditions and prevents localized corrosion.

Inventive Principle:
Principle #40Composite materials

2Duration of action of stationary object

If a corrosion-protective coating is applied to a metallic bipolar plate substrate, then long-term stability is improved, but electrical conductivity may be compromised

Engineering Contradiction:
Improvelong-term stabilityVSAvoidelectrical conductivity
Core Design Contradiction:
Duration of action of stationary objectVSReliability

Solution Approach 1:

The patent employs different materials with optimized properties for specific functions in different layers: the metallic first layer provides electrical conductivity and corrosion resistance, the intermediate layer ensures adhesion and stress management, and the non-metallic second layer provides chemical inertness and long-term stability. This local optimization of material properties throughout the coating thickness achieves both high electrical conductivity and long-term stability.

Inventive Principle:
Principle #3Local quality

3Reliability

If multiple layers are used to improve corrosion protection, then corrosion resistance is improved, but manufacturing complexity increases

Engineering Contradiction:
Improvecorrosion resistanceVSAvoidlayer system complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent divides the corrosion protection function into three specialized layers, each with a specific role: the metallic first layer for corrosion and conductivity protection, the intermediate layer for adhesion and stress relief, and the non-metallic second layer for chemical resistance. This segmentation allows each layer to be optimized independently while simplifying the overall manufacturing process through standardized deposition techniques.

Inventive Principle:
Principle #1Segmentation

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The layer system ensures long-term stability and high electrical conductivity while minimizing material requirements, offering effective corrosion protection for metallic substrates in bipolar plates and electrode units.

Implementation Method 1

produced through physical vapor deposition techniques

Methodology Applied
Scientific EffectPhysical vapor deposition: Physical Vapour Deposition

Data Source

PatentUS20220246950A1Layer system for coating a bipolar plate, bipolar plate, and fuel cell
Publication Date: 2022.08.04 SCHAEFFLER TECHNOLOGIES AG & CO KG
  • US20220246950A1 patent drawing
  • US20220246950A1 patent drawing
  • US20220246950A1 patent drawing

AI summary

A layer system (1, 1′, 1″, Ia) for coating a bipolar plate (10) or an electrode unit (10a, 10b), including at least one first layer (2, 2a, 2b), at least one second layer (3), and at least one cover layer (4, 4a, 4b) arranged on the at least one second layer (3) made of a doped tetrahedral amorphic carbon ta-C:X, wherein as the dopant X, at least one element is provided from the group including titanium, niobium, tungsten, zirconium, tantalum, hafnium, molybdenum, copper, silicon, platinum, palladium, ruthenium, iridium, silver, boron, nitrogen, phosphor, fluorine, hydrogen, and oxygen, and the dopant X is provided in the cover layer (4, 4a, 4b) in a concentration of >0 to 20 at.-%. A bipolar plate (10) or an electrode unit (10a, 10b) having such a layer system and a fuel cell (100) and a redox flow cell (110) are also provided.