Doping Capsules for Thermotropic Sun Protection

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Solution Overview

Problem

Current thermotropic materials for sun protection lack long-term stability and effective temperature-controlled optical effects due to unresolved reaction mechanisms and phase transitions, leading to inefficiencies in energy balance optimization and market viability.

Innovation Solution

Doping capsules with a substance exhibiting a rotator phase between 10 to 55°C, which decreases transparency with increasing temperature, are integrated into a polymer matrix, providing a thermodynamically stable thermotropic plastic material for sun protection and heat reflection.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If thermotropic materials are used for sun protection, then temperature-controlled optical effects are achieved, but long-term stability and thermodynamic stability are insufficient

Engineering Contradiction:
Improvelong-term stabilityVSAvoidthermodynamic stability
Core Design Contradiction:
ReliabilityVSStability of the object's composition

Solution Approach 1:

The patent changes the physical state parameter of the thermotropic material by using encapsulated liquid crystals in a rotator phase state, which provides both long-term stability and reversible temperature-dependent optical effects. The encapsulation prevents degradation while maintaining the phase transition properties needed for sun protection functionality.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention creates a composite system combining polymer matrix with encapsulated thermotropic material. This composite structure integrates the stability of the polymer matrix with the optical switching properties of the thermotropic material, achieving both long-term stability and functional performance.

Inventive Principle:
Principle #40Composite materials

2Ease of manufacture

If conventional thermotropic systems are used, then sun protection function is provided, but reaction mechanisms and phase transitions are not understood, leading to market delays

Engineering Contradiction:
Improvemarket viabilityVSAvoidreaction mechanism complexity
Core Design Contradiction:
Ease of manufactureVSDevice complexity

Solution Approach 1:

The patent extracts the thermotropic material from the polymer matrix into separate capsules. This separation simplifies the reaction mechanisms by eliminating the need for complex in-situ phase transitions within the polymer, while maintaining the sun protection function. The encapsulated material can be easily incorporated without triggering unwanted chemical reactions.

Inventive Principle:
Principle #2Taking out (Extraction)

3Reliability

If aliphatic compounds are introduced as thermotropic monomers, then sun protection is achieved, but migration to substrate surface occurs under thermal stress

Engineering Contradiction:
Improvesun protection functionVSAvoidmigration to substrate surface
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The patent nests the thermotropic material inside capsules, which are then incorporated into the polymer matrix. This nested structure prevents the thermotropic material from migrating to the substrate surface while maintaining its sun protection function. The capsule acts as a protective container that isolates the thermotropic material from the external environment.

Inventive Principle:
Principle #7Nested doll (Nesting)

4Stability of the object's composition

If thermotropic components are dissolved in polymer matrix, then homogeneity is achieved, but anisotropy is lost

Engineering Contradiction:
ImprovehomogeneityVSAvoidanisotropy for sun protection
Core Design Contradiction:
Stability of the object's compositionVSEase of manufacture

Solution Approach 1:

The patent segments the thermotropic material into discrete capsules rather than dissolving it throughout the polymer matrix. This segmentation maintains homogeneity at the macro level while preserving anisotropy at the capsule level. The capsules can be uniformly distributed in the polymer matrix, achieving both homogeneity and the necessary optical anisotropy for sun protection.

Inventive Principle:
Principle #1Segmentation

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution achieves a reversible temperature-dependent change in transparency, enhancing the material's stability and optical properties for efficient sun protection, allowing for cost-effective and continuous production of films suitable for energy balance optimization in buildings.

Implementation Method 1

doping capsules comprising at least one substance which has a rotator phase in a temperature range of 10 to 55° C.

Methodology Applied
Scientific EffectRotator phase: Liquid Crystals

Implementation Method 2

the capsules according to the invention are used for sun protection or heat reflection... display a decrease in transparency with increasing temperature

Methodology Applied
Scientific EffectThermotropic effect: Thermochromism

Data Source

PatentUS10133093B2Doping capsules, composite systems comprising these and also use thereof
Publication Date: 2018.11.20 FRAUNHOFER GESELLSCHAFT ZUR FORDERUNG DER ANGEWANDTEN FORSCHUNG EV
  • US10133093B2 patent drawing
  • US10133093B2 patent drawing

AI summary

The invention relates to doping capsules which have a substance which displays a decreasing transparency with increasing temperature within a defined temperature range due to physicochemical interactions with the polymer matrix to be doped. Likewise, the invention relates to composite systems which have a polymer matrix doped with the doping capsules. The capsules according to the invention are used for sun protection or heat reflection.