Radiation Dosimetry Gel Using Silicate and Organic Polymer

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Solution Overview

Problem

Conventional gel dosimeters prepared with gelatin face challenges such as temperature sensitivity and instability, making precise preparation difficult, and existing alternatives like clay-based dosimeters may not offer sufficient heat resistance and reproducibility.

Innovation Solution

A radiation dosimetry gel composed of a water-soluble organic polymer with an organic acid salt structure or anion structure, combined with silicate particles and a dispersant, which can be mixed at room temperature to create a heat-resistant, self-supporting gel for measuring radiation doses.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If gelatin is used as the gelator in conventional gel dosimeters, then the gel can be prepared easily, but the gel exhibits temperature sensitivity and dissolves at 25-30°C causing instability

Engineering Contradiction:
Improveease of gel preparationVSAvoidtemperature stability
Core Design Contradiction:
Ease of manufactureVSStability of the object's composition

Solution Approach 1:

The patent changes the fundamental parameter of gelation mechanism from protein-based (gelatin) to polysaccharide-based (hydroxypropylcellulose and methyl cellulose). This chemical parameter change eliminates temperature sensitivity while maintaining ease of preparation through simple mixing at room temperature without heating or cooling steps.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite gel system combining hydroxypropylcellulose and methyl cellulose with specific weight average molecular weights. This composite material approach provides synergistic effects that enhance both thermal stability and gel formation properties, resolving the contradiction between ease of preparation and temperature stability.

Inventive Principle:
Principle #40Composite materials

2Ease of manufacture

If gelatin is used for gel dosimeter preparation, then the process is simple, but heating and cooling steps are required making precise preparation difficult

Engineering Contradiction:
Improvesimplicity of preparation processVSAvoidpreparation precision
Core Design Contradiction:
Ease of manufactureVSManufacturing precision

Solution Approach 1:

The patent employs materials (hydroxypropylcellulose and methyl cellulose) that self-gelate at room temperature without requiring external heating or cooling. This self-service property eliminates complex temperature control steps, simultaneously improving both simplicity and precision of preparation.

Inventive Principle:
Principle #25Self-service

3Temperature

If clay-based dosimeters are used as alternatives, then heat resistance is improved, but reproducibility and self-supporting properties are insufficient

Engineering Contradiction:
Improveheat resistanceVSAvoidreproducibility
Core Design Contradiction:
TemperatureVSReliability

Solution Approach 1:

The patent creates a optimized composite system of hydroxypropylcellulose and methyl cellulose with specifically controlled molecular weights and ratios. This composite approach achieves superior heat resistance comparable to clay-based dosimeters while simultaneously providing excellent reproducibility and self-supporting properties that clay alternatives lack.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent systematically optimizes parameters including the weight average molecular weights of the polysaccharides (100,000-1,000,000 for hydroxypropylcellulose and 100,000-500,000 for methyl cellulose) and their ratios (0.1-10 mass% each). These parameter changes achieve the optimal balance of heat resistance, reproducibility, and self-supporting properties.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The gel exhibits superior heat resistance and can be produced uniformly at room temperature, maintaining its shape without support, enabling precise measurement of radiation doses and flexible dosimeter applications.

Implementation Method 1

a water-soluble organic polymer (A) having an organic acid salt structure or an organic acid anion structure, a silicate (B), and a dispersant (C) for the silicate

Methodology Applied
Scientific EffectGel formation: Gel

Implementation Method 2

polymer gel dosimeters contain monomers dispersed in a gel. Upon irradiation, a polymer is produced proportionately with the dose

Methodology Applied
Scientific EffectHydrogen bonding:

Implementation Method 3

a dispersant (C) for the silicate

Methodology Applied
Scientific EffectDispersion: Dispersion (of waves)

Implementation Method 4

having an organic acid salt structure or an organic acid anion structure

Methodology Applied
Scientific EffectElectrostatic repulsion: Ion Repulsion/Attraction

Implementation Method 5

the measurement principle of a chemical dosimeter. The use of a gel dosimeter provides an additional advantage in that amounts of energy deposited by radiation beams

Methodology Applied
Scientific EffectIonization: Ionisation

Implementation Method 6

integrating the amounts of deposited energy, a three-dimensional distribution of deposited energy (dose distribution)

Methodology Applied
Scientific EffectEnergy deposition:

Data Source

PatentUS10031241B2Radiation dosimetry gel and radiation dosimeter comprising the same as material for measuring radiation dose
Publication Date: 2018.07.24 RIKEN CO LTD
  • US10031241B2 patent drawing
  • US10031241B2 patent drawing
  • US10031241B2 patent drawing

AI summary

A radiation dosimetry gel is excellent in heat resistance, and a radiation dosimeter includes the radiation dosimetry gel as a material for measuring a radiation dose. A radiation dosimetry gel includes a water-soluble organic polymer (A) having an organic acid salt structure or an organic acid anion structure, a silicate (B), and a dispersant (C) for the silicate, and a radiation dosimeter includes the radiation dosimetry gel as a material for measuring a radiation dose.