Double-Dipped Nitrile Gloves for Snug Fit and Stress Retention

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Solution Overview

Problem

Existing elastomeric gloves face challenges in providing a snug fit without being restrictive and in adjusting stress retention for different applications, with current formulations and methods being costly and time-consuming to modify.

Innovation Solution

A double-dipped glove construction using two layers of nitrile butadiene rubber compositions, with varying amounts of metal oxides and cross-linking agents, including sulfur, to achieve stress retention of greater than 50% and adjust properties for specific applications.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Adaptability or versatility

If a single-layer glove formulation is used, then manufacturing is simpler and cost-effective, but the glove cannot achieve both snug fit and desired stress retention for different applications

Engineering Contradiction:
Improvestress retention adjustment for different applicationsVSAvoidglove construction complexity
Core Design Contradiction:
Adaptability or versatilityVSDevice complexity

Solution Approach 1:

The glove is divided into two distinct layers with different formulations. The first layer (inner layer) contains a first nitrile butadiene rubber composition optimized for skin comfort and fit, while the second layer (outer layer) contains a second nitrile butadiene rubber composition optimized for stress retention and durability. This segmentation allows each layer to be independently formulated for its specific function, enabling the glove to achieve both snug fit and high stress retention without requiring complex multi-component systems.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The invention uses composite material construction by combining two different nitrile butadiene rubber formulations in a layered structure. The first composition and second composition have different ratios of polybutadiene, polysulfide, and other additives, creating a composite glove that exhibits superior overall performance compared to single-layer gloves. This composite approach allows optimization of each layer's properties for its intended function while maintaining manufacturing simplicity.

Inventive Principle:
Principle #40Composite materials

2Reliability

If glove formulation is changed to adjust stress retention for different applications, then performance is optimized, but manufacturing cost and time increase

Engineering Contradiction:
Improvestress retentionVSAvoidformulation modification cost and time
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The double-layer glove construction provides a universal solution that can serve multiple applications (medical, industrial, laboratory) without requiring formulation changes. By optimizing the thickness ratios and compositions of the two layers, the same basic glove structure can achieve different stress retention levels suitable for various applications, eliminating the need to develop and validate new formulations for each use case.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Solution Approach 2:

Instead of changing the chemical formulation for different applications, the invention achieves performance adjustment by changing physical parameters such as the thickness of each layer and the ratio of components within each layer's formulation. This allows flexible optimization of stress retention for different applications while maintaining the same manufacturing process and base formulations.

Inventive Principle:
Principle #35Parameter changes

3Manufacturing precision

If a snug-fitting glove is designed, then hand protection is improved, but the glove becomes uncomfortably restrictive

Engineering Contradiction:
Improveglove fit to handVSAvoidhand comfort
Core Design Contradiction:
Manufacturing precisionVSEase of operation

Solution Approach 1:

The first layer (inner layer) is specifically formulated with different composition ratios compared to the second layer, creating local quality differences that optimize comfort where it matters most - against the skin. The first layer uses a formulation that provides softness and flexibility for comfort, while the second layer uses a formulation optimized for durability and stress retention, allowing the glove to be snug without being uncomfortably restrictive.

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The double-dipped glove design ensures a snug fit without being restrictive, with stress retention ranging from 50% to 70%, allowing for cost-effective and efficient adjustment of properties for different applications, such as medical and industrial use, while reducing defect rates and improving tensile strength and elongation.

Implementation Method 1

a first composition comprising a first nitrile butadiene rubber, a first metal oxide, and sulfur; applying a second composition to the first layer, wherein the second composition comprises a second nitrile butadiene rubber, a second metal oxide, and sulfur, thereby forming a second layer

Methodology Applied
Scientific EffectCross-linking: Chemical Bonding

Data Source

PatentUS7730554B2Double dipped gloves
Publication Date: 2010.06.08 ENCOMPASS MEDICAL SUPPLIES
  • US7730554B2 patent drawing
  • US7730554B2 patent drawing

AI summary

A method of making a glove is described. The method comprises dipping a glove form into two different formulations. Each formulation comprises a carboxylated nitrile butadiene rubber with different amounts of covalent and ionic cross linkers. The gloves preferably have a stress retention value of greater than 50%.