Double Staining Process for Integrated Circuit Junction Visualization

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Solution Overview

Problem

Conventional methods for staining integrated circuit samples, particularly for PMOS active areas, face challenges in achieving a correct cut and stain profile due to the critical nature of overcutting, leading to incomplete or excessive exposure of junction profiles, making it difficult to visually distinguish doping defects using microscopy.

Innovation Solution

A double staining process is employed, where a first staining procedure selectively removes shallow trench isolation to expose the active area, and a second procedure selectively stains the doped substrate regions, forming voids that connect to each other, allowing for better visualization of the junction profile without the need for overcutting the sample.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Measurement precision

If a single chemical solution is used to stain the target regions, then the junction profile can be visualized, but the sample must be overcut into the entire active area which becomes increasingly difficult as critical dimension is downsized

Engineering Contradiction:
Improvevisualization of junction profileVSAvoidovercutting the sample
Core Design Contradiction:
Measurement precisionVSEase of manufacture

Solution Approach 1:

The single staining process is segmented into two sequential staining procedures. The first staining procedure uses a first chemical solution to selectively remove shallow trench isolation and expose the active area. The second staining procedure uses a second chemical solution to selectively stain the doped substrate regions. This segmentation eliminates the need for precise overcutting while achieving complete visualization of the junction profile.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The first staining procedure performs a preliminary action by selectively removing the shallow trench isolation to expose the active area before the second staining procedure stains the doped substrate regions. This preliminary exposure ensures that subsequent staining can access and visualize the junction profile without requiring the sample to be overcut.

Inventive Principle:
Principle #10Preliminary action

2Measurement precision

If the sample is overcut to expose the junction profile, then the staining can be performed, but the junction profile may be insufficiently left for the staining procedure

Engineering Contradiction:
Improveexposure of junction profileVSAvoidextent of overcut
Core Design Contradiction:
Measurement precisionVSManufacturing precision

Solution Approach 1:

The staining process is divided into two independent procedures with different objectives. The first procedure targets the shallow trench isolation removal to expose the active area, while the second procedure targets the doped substrate regions for staining. This segmentation allows each procedure to operate with its own optimized parameters without the constraints of precise overcutting control.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The first staining procedure acts as an intermediary step that prepares the sample by removing the shallow trench isolation and exposing the active area. This intermediary action creates favorable conditions for the second staining procedure to effectively stain the doped substrate regions, eliminating the need for precise overcut control.

Inventive Principle:
Principle #24Intermediary (Mediator)

3Measurement precision

If microscopy is used to detect doping profile defects, then the defects can be identified, but different doping profiles provide no contrast and cannot be visually distinguished

Engineering Contradiction:
Improvedetection of doping defectsVSAvoidvisual distinction of doping profiles
Core Design Contradiction:
Measurement precisionVSDifficulty of detecting and measuring

Solution Approach 1:

The second chemical solution selectively stains the doped substrate regions, creating visible color or contrast changes that differentiate the junction profile from the surrounding substrate. This staining action transforms the invisible doping profile into a visually distinguishable feature that can be easily detected using microscopy.

Inventive Principle:
Principle #32Color changes

Solution Approach 2:

The staining process changes the physical-chemical parameters of the doped substrate regions by introducing stainable compounds that alter the optical properties of the regions. This parameter change creates contrast between different doping profiles, enabling visual detection of doping defects through microscopy.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This method ensures a good stain profile is achieved, enabling effective visualization of the junction profile and facilitating the detection of doping defects, thereby improving the controllability and accuracy of the staining process.

Implementation Method 1

a first staining procedure is carried out to selectively remove the shallow trench isolation to form a first void and to at least partially expose the active area

Methodology Applied
Scientific EffectChemical etching:

Implementation Method 2

a second staining procedure is carried out to selectively stain the first doped substrate region and the second doped substrate region to form a second void

Methodology Applied
Scientific EffectChemical staining:

Data Source

PatentUS8298838B2Method for staining sample
Publication Date: 2012.10.30 UNITED MICROELECTRONICS CORP
  • US8298838B2 patent drawing
  • US8298838B2 patent drawing
  • US8298838B2 patent drawing

AI summary

A method for staining a sample includes the following steps. A test device is provided. The test device is sampled to obtain a sample. The sample includes a substrate, an active area disposed within the substrate and having a first doped substrate region and a second doped substrate region, at least one gate disposed between the first doped substrate region and the second doped substrate region, and an exposed shallow trench isolation embedded in the substrate and surrounding the active area. A first staining procedure is then carried out to selectively remove the shallow trench isolation to form a first void and to entirely expose the active area. A second staining procedure is subsequently carried out to selectively stain the first doped substrate region and the second doped substrate region to form a second void.