Downhole Mass Spectrometer Ionization for Hydrocarbon Analysis

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Solution Overview

Problem

Surface mud gas logging techniques face limitations due to contamination and inaccuracy in measuring hydrocarbon compositions, particularly in determining the depth and quality of oil reservoirs, as they rely on inferred measurements and are prone to contamination from air and previous drilling fluids.

Innovation Solution

A method utilizing a mass spectrometer to analyze fluid properties downhole, combining electron and chemical ionization to calculate hydrocarbon concentrations, which involves creating a tool response matrix to accurately determine component concentrations in the presence of methane and iso-butane, accounting for chemical ionization effects and pressure dependencies.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of operation

If surface mud gas logging is used to analyze hydrocarbon composition, then gas analysis can be performed onsite, but the measurements are prone to contamination from air and previously drilled layers

Engineering Contradiction:
Improveonsite gas analysis capabilityVSAvoidmeasurement accuracy
Core Design Contradiction:
Ease of operationVSReliability

Solution Approach 1:

The measurement process is segmented into two distinct locations: surface-level gas extraction and downhole mass spectrometric analysis. By separating the sampling function (at surface) from the analysis function (at downhole), the system eliminates contamination risks during sample transport and depth inference, while maintaining ease of onsite operation.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent introduces an intermediary system - the downhole mass spectrometer with chemical ionization capability - that acts as a mediator between the drilled formation and surface analysis equipment. This intermediary performs the critical measurement function at the optimal location (downhole) while allowing surface-level operational simplicity.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Device complexity

If depth is inferred from gross measurements of mud transit time and average mud velocity, then depth estimation is simple, but the measurements are intrinsically inaccurate

Engineering Contradiction:
Improvedepth measurement simplicityVSAvoiddepth accuracy
Core Design Contradiction:
Device complexityVSMeasurement precision

Solution Approach 1:

Instead of inferring depth from surface measurements (traditional approach), the patent inverts the approach by directly measuring depth and composition at the downhole location where the mass spectrometer is positioned. This eliminates the need for indirect calculations based on mud transit time and velocity, providing both operational simplicity and measurement accuracy simultaneously.

Inventive Principle:
Principle #13The other way round (Inversion)

3Measurement precision

If combined electron and chemical ionization is used in mass spectrometry, then hydrocarbon concentration accuracy is improved, but the device complexity increases

Engineering Contradiction:
Improvehydrocarbon concentration accuracyVSAvoidionization system complexity
Core Design Contradiction:
Measurement precisionVSDevice complexity

Solution Approach 1:

The patent merges two ionization techniques (electron ionization and chemical ionization) into a single mass spectrometer system. By combining these methods, the system achieves superior hydrocarbon concentration accuracy through complementary detection capabilities, while the integrated design minimizes the complexity increase that would result from separate systems.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The mass spectrometer is designed with multi-functionality, capable of performing both electron ionization and chemical ionization analyses within a single instrument. This universal design allows the system to handle diverse hydrocarbon analysis requirements accurately without requiring multiple specialized devices, thereby managing complexity efficiently.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enhances the accuracy of hydrocarbon composition analysis by reducing contamination errors and providing real-time, precise data for geosteering and reservoir mapping, improving well placement and reservoir continuity.

Implementation Method 1

A method utilizing a mass spectrometer to analyze fluid properties downhole, combining electron and chemical ionization

Methodology Applied
Scientific EffectElectron ionization: Ionisation

Implementation Method 2

A method utilizing a mass spectrometer to analyze fluid properties downhole, combining electron and chemical ionization

Methodology Applied
Scientific EffectChemical ionization: Ionisation

Data Source

PatentUS8912000B2Downhole mass spectrometric hydrocarbon determination in presence of electron and chemical ionization
Publication Date: 2014.12.16 SCHLUMBERGER TECH CORP
  • US8912000B2 patent drawing
  • US8912000B2 patent drawing
  • US8912000B2 patent drawing

AI summary

Methods and apparatus for obtaining a mass spectrum of a sample and determining a concentration of a component of the sample by utilizing a model of chemical and electron ionization and the obtained mass spectrum.