Downhole Mass Spectrometer Operating Above 10-2 Torr

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Solution Overview

Problem

Downhole analysis of wellbore fluids and gases is complicated by the small diameter of wellbores and stringent operating conditions, including vibrations, elevated temperatures, and high pressures, which constrain the design of measurement tools and limit their effectiveness.

Innovation Solution

The integration of a gas chromatograph and a mass spectrometer, including an ion trap or quadrupole mass analyzer, within a wellbore tool that can operate at pressures greater than 10−2 Torr, using robust components such as scroll pumps and rotary valves to withstand harsh conditions, allowing for onsite analysis of formation fluid compositions.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Measurement precision

If a mass spectrometer is used for downhole analysis, then measurement precision is improved, but the device cannot operate under high pressure conditions (greater than 10^-2 Torr)

Engineering Contradiction:
Improvedetection sensitivityVSAvoidoperability under pressure
Core Design Contradiction:
Measurement precisionVSReliability

Solution Approach 1:

The patent modifies the operating parameters of the mass spectrometer to function at pressures greater than 10^-2 Torr, which is a significant departure from conventional vacuum operation. This involves adjusting the ionization source, mass analyzer, and detector parameters to maintain performance under elevated pressure conditions, thereby enabling downhole operation without sacrificing measurement precision

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent replaces traditional mechanical vacuum pumping systems with alternative pressure management mechanisms that can operate in high-pressure downhole environments. This substitution allows the mass spectrometer to function without requiring a deep vacuum, making it suitable for wellbore conditions where vacuum maintenance is impractical

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

2Ease of operation

If the wellbore diameter is small (five inches or less), then the measurement tool can be deployed in the wellbore, but the geometry of the tool components is constrained

Engineering Contradiction:
ImprovedeployabilityVSAvoidcomponent geometry
Core Design Contradiction:
Ease of operationVSDevice complexity

Solution Approach 1:

The patent employs a nested configuration where the mass spectrometer components are arranged concentrically and in series to minimize the radial footprint. The ionization source, mass analyzer, and detector are positioned in a compact, nested arrangement that fits within the constrained diameter of the wellbore while maintaining functional integrity

Inventive Principle:
Principle #7Nested doll (Nesting)

Solution Approach 2:

The patent transitions from a traditional horizontal or radial layout to a vertical or axial arrangement of components, utilizing the length dimension rather than the radial dimension. This dimensional reconfiguration allows the instrument to fit within small-diameter wellbores by extending along the axis of the wellbore rather than requiring radial space

Inventive Principle:
Principle #17Another dimension (Dimensionality change)

3Reliability

If robust components (scroll pumps, rotary valves) are used to withstand harsh conditions, then reliability under vibration and temperature is improved, but the device complexity increases

Engineering Contradiction:
Improvewithstand capabilityVSAvoidcomponent robustness
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent selects robust components such as scroll pumps and rotary valves that serve multiple functions: they provide the necessary pressure management and sample injection while simultaneously being designed to withstand vibrations, elevated temperatures, and high pressures. This multi-functionality reduces the need for additional protective components, thereby limiting the increase in overall device complexity

Inventive Principle:
Principle #6Universality (Multi-functionality)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Enables accurate and sensitive analysis of wellbore fluid components, including hydrogen sulfide, mercaptans, and oxidants, improving worksite safety and informing decisions on wellbore casing and tool selection by providing detailed information on hydrocarbon maturity and reservoir properties.

Implementation Method 1

a gas chromatograph having a column configured to separate a fluid sample into at least partially separated components

Methodology Applied
Scientific EffectChromatography: Chromatography

Implementation Method 2

The mass spectrometer is configured to operate downhole at a pressure greater than 10−2 Torr and includes at least one of (a) an ion trap analyzer and (b) a quadrupole mass analyzer

Methodology Applied
Scientific EffectIonization: Ionisation

Implementation Method 3

a mass spectrometer configured to receive the at least partially separated components from the gas chromatograph. The mass spectrometer is configured to operate downhole at a pressure greater than 10−2 Torr and includes at least one of (a) an ion trap analyzer and (b) a quadrupole mass analyzer

Methodology Applied
Scientific EffectElectromagnetic field separation: Electromagnetic Induction

Data Source

PatentUS20180094522A1Gas chromatograph mass spectrometer for downhole applications
Publication Date: 2018.04.05 SCHLUMBERGER TECH CORP
  • US20180094522A1 patent drawing
  • US20180094522A1 patent drawing
  • US20180094522A1 patent drawing

AI summary

Wellbore tools in accordance with the present disclosure may include a gas chromatograph; and a mass spectrometer, wherein the mass spectrometer is configured to operate at a pressure greater than 10−2 Torr. Systems in accordance with the present disclosure may include a gas chromatograph; and a mass spectrometer, wherein the mass spectrometer is configured to operate at a pressure greater than 10−2 Torr. Methods in accordance with the present disclosure may include emplacing a wellbore tool in a wellbore, the wellbore tool containing a gas chromatograph and a mass spectrometer, wherein the mass spectrometer is configured to operate at a pressure greater than 10−2 Torr; drawing a sample of a fluid from the wellbore into the wellbore tool; and determining a molecular weight of one or more components of the fluid.