Downhole NMR Lithium Sensing in Inhomogeneous Borehole Fields

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Solution Overview

Problem

Current downhole NMR tools are incapable of measuring lithium concentrations inside wellbores due to the challenge of distinguishing lithium signals from other nuclei, particularly in inhomogeneous fields, and existing tools use an 'inside-out' geometry that projects magnetic and RF fields outside the tool, limiting their capability.

Innovation Solution

The development of NMR-based downhole tools with a centralized or single-sided inside-out magnet-coil geometry and tunable RF coils that match the Larmor frequency of lithium, allowing direct measurement and separation of lithium signals from confounding signals using relaxation distributions.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Measurement precision

If conventional downhole NMR tools with inside-out geometry are used, then the tool structure is simple and easy to manufacture, but the tool cannot distinguish lithium signals from other nuclei in inhomogeneous fields

Engineering Contradiction:
Improvelithium concentration measurement capabilityVSAvoidmagnet-coil geometry complexity
Core Design Contradiction:
Measurement precisionVSDevice complexity

Solution Approach 1:

The NMR tool employs separate magnet assemblies and RF coil assemblies positioned at different locations within the tool body. The magnet section generates the static magnetic field while the RF coil section transmits and receives signals, allowing independent optimization of each component for lithium signal detection while maintaining manageable structural complexity

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The tool uses localized magnet assemblies positioned to create specific field geometries that enhance lithium signal detection in particular regions of interest. The RF coils are configured with specific orientations and positions to optimize sensitivity to lithium nuclei while filtering out signals from other nuclei, achieving measurement precision through localized field optimization

Inventive Principle:
Principle #3Local quality

2Productivity

If surface laboratory analysis is used, then lithium concentration can be measured accurately, but the process is time-consuming and does not provide real-time data

Engineering Contradiction:
Improvereal-time measurement capabilityVSAvoidlithium signal detection accuracy
Core Design Contradiction:
ProductivityVSMeasurement precision

Solution Approach 1:

The patent replaces the mechanical sampling and transportation process with an in-situ NMR measurement system that directly detects lithium concentrations downhole. The NMR tool uses magnetic field interactions rather than physical sample handling, enabling real-time measurements while maintaining measurement precision through sophisticated signal processing and relaxation distribution analysis

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The NMR tool acts as an intermediary between the lithium-bearing formation and the surface analysis system. It performs the measurement function downhole using NMR physics, transmitting only the essential concentration data to the surface, thereby eliminating the time-consuming steps of sample collection, transport, and laboratory analysis while preserving measurement accuracy

Inventive Principle:
Principle #24Intermediary (Mediator)

3Measurement precision

If in-situ NMR measurement is implemented, then real-time lithium concentration data is obtained, but the ability to distinguish lithium signals from confounding signals in inhomogeneous fields becomes problematic

Engineering Contradiction:
Improvelithium signal separation capabilityVSAvoidsignal discrimination in inhomogeneous fields
Core Design Contradiction:
Measurement precisionVSDifficulty of detecting and measuring

Solution Approach 1:

The tool utilizes differences in Larmor frequencies and relaxation times of lithium nuclei compared to other nuclei as distinguishing parameters. By tuning the RF coil to the specific Larmor frequency of lithium and analyzing relaxation distributions, the system can separate lithium signals from confounding signals even in the inhomogeneous fields present in downhole environments

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The NMR measurement process dynamically samples the signal decay over time, capturing the characteristic relaxation behavior of lithium nuclei. This temporal dimension provides an additional parameter for signal discrimination, allowing the system to distinguish lithium signals from other nuclei based on their unique relaxation signatures even when spatial field homogeneity is limited

Inventive Principle:
Principle #15Dynamics

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Enables accurate, in-situ measurement of lithium concentrations in subterranean formations and wellbores, providing real-time data for reservoir quality evaluation and zone-specific production assessment, overcoming the limitations of existing tools.

Implementation Method 1

nuclear magnetic resonance (hereinafter 'NMR') measurements

Methodology Applied
Scientific EffectNuclear magnetic resonance:

Implementation Method 2

at least one tunable radiofrequency (RF) coil tuned to match a first Larmor frequency of a nucleus of lithium

Methodology Applied
Scientific EffectLarmor frequency:

Data Source

PatentUS12571934B2NMR-based lithium measuring and monitoring downhole tools, methods of using said downhole tools, and methods of measuring lithium concentrations based on NMR measurements acquired by said downhole tools
Publication Date: 2026.03.10 SCHLUMBERGER TECH CORP
  • US12571934B2 patent drawing
  • US12571934B2 patent drawing
  • US12571934B2 patent drawing

AI summary

NMR-based lithium measuring and monitoring downhole tools and methods measure at least one lithium concentration of a fluid in a borehole and/or a surrounding formation of the borehole, wherein the downhole tool has an NMR sensor having a magnet-coil geometry with at least one magnet and a RF coil tuned to match a Larmor frequency of a nucleus of lithium. The downhole tools and methods acquire an NMR-based lithium concentration measurement of a fluid at a sensitive region within the wellbore and/or formation that is defined by the magnet-coil geometry of the NMR sensor and determine a lithium concentration of the fluid at the sensitive region based on the acquired NMR-based lithium concentration measurement. The downhole tools and methods may interpret an acquired signal based on relaxation distributions of total acquired signals, wherein the acquired signal is indicative of the acquired NMR-based lithium concentration measurement and separate a lithium signal from confounding signals deriving from other non-lithium nuclei based on the interpretated acquired signal.