Drag Reducing Polymer for Heavy Crude Oil Pipelines

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Solution Overview

Problem

Conventional polymeric drag reducers are ineffective in crude oils with low API gravity and high asphaltene content, leading to inefficiencies and increased costs due to pressure drops during pipeline transportation.

Innovation Solution

A method involving the introduction of a high molecular weight drag reducing polymer with at least 10,000 repeating units and a heteroatom into liquid hydrocarbons with high asphaltene content, specifically designed to maintain or increase viscosity and reduce pressure drop in pipelines.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Loss of energy

If conventional polymeric drag reducers are used in crude oils with low API gravity and high asphaltene content, then pressure drop is reduced in normal crude oils, but the drag reducers become ineffective in heavy crude oils with high asphaltene content

Engineering Contradiction:
Improvepressure dropVSAvoideffectiveness in high-asphaltene crude oils
Core Design Contradiction:
Loss of energyVSReliability

Solution Approach 1:

The patent applies parameter changes by modifying the molecular weight parameter of the polymer drag reducer to ultra-high molecular weights (exceeding five million), which enables the polymer to maintain effectiveness in high-asphaltene crude oils where conventional lower molecular weight polymers fail. This parameter change transforms the polymer's interaction with asphaltene-containing crude oils, allowing it to suppress turbulent eddies and reduce pressure drop even in these challenging conditions.

Inventive Principle:
Principle #35Parameter changes

2Productivity

If higher flow rates are desired through the pipeline, then throughput is increased, but more pressure must be applied due to increased pressure drop

Engineering Contradiction:
Improveflow rateVSAvoidpumping pressure
Core Design Contradiction:
ProductivityVSStress or pressure

Solution Approach 1:

The patent converts the harmful effect of turbulent flow and associated pressure drop into a beneficial situation by using ultra-high molecular weight polymers to suppress turbulent eddies. The polymers exploit the turbulent flow conditions themselves to achieve drag reduction, allowing higher flow rates to be maintained at lower pumping pressures. The turbulent flow that normally causes energy loss is transformed into an opportunity for the polymer to exert its drag-reducing effect.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

3Loss of energy

If molecular weight of polymer additive is increased to improve drag reduction, then drag reduction effectiveness is enhanced, but solubility in crude oil may be reduced

Engineering Contradiction:
Improvedrag reductionVSAvoidsolubility in crude oil
Core Design Contradiction:
Loss of energyVSStability of the object's composition

Solution Approach 1:

The patent applies parameter changes by carefully optimizing the molecular weight parameter to ultra-high levels (exceeding five million) while maintaining solubility in crude oil. This specific parameter range enables the polymer to achieve maximum drag reduction effectiveness while remaining sufficiently soluble in the crude oil to function properly. The parameter change represents a precise optimization point where both drag reduction and solubility requirements are satisfied simultaneously.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution effectively reduces pressure drop and enhances flow rates in pipelines carrying heavy crude oils with low API gravity and high asphaltene content, improving efficiency and reducing operational costs.

Implementation Method 1

The role of these additives is to suppress the growth of turbulent eddies, which results in higher flow rate at a constant pumping pressure

Methodology Applied
Scientific EffectTurbulence suppression: Turbulence

Implementation Method 2

a plurality of the repeating units comprise a heteroatom

Methodology Applied
Scientific EffectMolecular interaction: Absorption (physical)

Data Source

PatentUS9784414B2Drag reduction of asphaltenic crude oils
Publication Date: 2017.10.10 LIQUIDPOWER SPECIALTY PRODUCTS INC
  • US9784414B2 patent drawing
  • US9784414B2 patent drawing
  • US9784414B2 patent drawing

AI summary

A process for preparing a drag reducing polymer which is to be added to a liquid hydrocarbon. The liquid hydrocarbon has an asphaltene content of at least about 3 weight percent and an API gravity of less than about 26°. The drag reducing polymer can comprise the residues of a monomer having at least one heteroatom. Treatment of the liquid hydrocarbon with the drag reducing polymer allows a reduction in pressure drop associated with turbulent flow of the liquid hydrocarbon through a conduit.