Direct Reduced Iron Carbon Content via Biochar Mediator

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Solution Overview

Problem

Current direct reduction methods for producing Direct Reduced Iron (DRI) result in significant CO2 emissions, and while increasing hydrogen in the reducing gas reduces CO2 emissions, it also decreases the carbon content of the DRI product, which is crucial for transportability and subsequent steelmaking processes, posing a challenge to maintain carbon content without increasing the carbon footprint.

Innovation Solution

Mixing oxidized iron with biochar, produced by pyrolysis of biomass, and using a reducing gas with a high hydrogen content, preferably over 50% or 99% hydrogen, which is partly produced by electrolysis powered by renewable energy, to maintain carbon content in the DRI product while reducing CO2 emissions.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Object-generated harmful factors

If hydrogen content in reducing gas is increased to reduce CO2 emissions, then CO2 emissions are reduced, but carbon content in DRI product decreases

Engineering Contradiction:
ImproveCO2 emissionsVSAvoidcarbon content in DRI product
Core Design Contradiction:
Object-generated harmful factorsVSQuantity of substance

Solution Approach 1:

Biochar is introduced as an intermediary carbon source that reacts with the reducing gas to provide carbon to the DRI product. The biochar serves as a mediator between the hydrogen-rich reducing gas and the iron oxide, enabling carbon transfer without requiring carbon-rich fossil fuels, thus resolving the contradiction between low CO2 emissions and adequate carbon content in the product

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The invention changes the parameter of carbon source from traditional coke or coal to biochar, which has different carbonization characteristics. This parameter change allows the process to maintain carbon content in the DRI product while using hydrogen-rich reducing gas, thereby reducing CO2 emissions without sacrificing product carbon content

Inventive Principle:
Principle #35Parameter changes

2Ease of operation

If carbon content in DRI product is increased to improve transportability, then transportability improves, but carbon footprint increases

Engineering Contradiction:
Improvetransportability of DRI productVSAvoidcarbon footprint
Core Design Contradiction:
Ease of operationVSObject-generated harmful factors

Solution Approach 1:

Biochar is used as a temporary carbon source that is consumed during the reduction process to provide carbon to the DRI product. This disposable carbon source allows the system to achieve adequate carbon content in the product without relying on persistent carbon-intensive materials like coke, thereby improving transportability while reducing the overall carbon footprint

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

Solution Approach 2:

The invention converts the potential harm of biochar (which could be considered a waste product) into a beneficial carbon source. By utilizing biochar's carbon content in the reduction zone, the process achieves both carbonization of the DRI product and utilization of renewable carbon, thereby improving transportability without increasing the carbon footprint

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This method allows for the production of DRI with adequate carbon content, enhancing its transportability and combustion potential while minimizing the carbon footprint of the process by utilizing biochar as a carbon source and renewable energy for hydrogen production.

Implementation Method 1

biochar, produced by pyrolysis of biomass

Methodology Applied
Scientific EffectPyrolysis: Pyrolysis

Implementation Method 2

Oxygen contained in ores and pellets is removed in stepwise reduction of iron oxides in counter-current reaction between gases and oxide

Methodology Applied
Scientific EffectReduction: Reduction

Implementation Method 3

counter-current reaction between gases and oxide

Methodology Applied
Scientific EffectCounter-current reaction:

Implementation Method 4

Injection of natural gas in the transition zone is using sensible heat of the metallized product in the transition zone to promote hydrocarbon cracking and carbon deposition

Methodology Applied
Scientific EffectCracking:

Implementation Method 5

hydrogen, preferably over 50% or 99% hydrogen, which is partly produced by electrolysis powered by renewable energy

Methodology Applied
Scientific EffectElectrolysis: Electrolysis

Data Source

PatentUS20240254576A1A method for manufacturing direct reduced iron
Publication Date: 2024.08.01 ARCELORMITTAL SA
  • US20240254576A1 patent drawing
  • US20240254576A1 patent drawing
  • US20240254576A1 patent drawing

AI summary

A method for manufacturing direct reduced iron wherein oxidized iron is reduced in a direct reduction furnace by a reducing gas, the oxidized iron being first mixed with biochar to form a solid compound and the solid compound is charged into the direct reduction furnace.