Water-Based Drilling Fluid Thermal Stability via Alkanolamine

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Solution Overview

Problem

Stuck pipe issues and thermal instability of drilling fluids pose significant challenges in hydrocarbon recovery, particularly in high-angle and horizontal wells, leading to substantial losses and operational difficulties due to differential and mechanical sticking, as well as chemical degradation at elevated temperatures.

Innovation Solution

The development of water-based drilling fluids containing manganese tetroxide and barium sulfate as weighting agents, combined with an alkanolamine thermal stabilizer, which maintains stable rheological properties between 100°F to 450°F, reducing high temperature high pressure fluid loss and enhancing operational efficiency.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Temperature

If conventional drilling fluids are used at high temperatures, then drilling operations can proceed, but the fluid components undergo chemical degradation with undesirable reduction of viscosity

Engineering Contradiction:
Improvedrilling temperatureVSAvoidfluid composition stability
Core Design Contradiction:
TemperatureVSStability of the object's composition

Solution Approach 1:

The patent applies parameter changes by modifying the chemical composition parameters of the drilling fluid - specifically using a calcium carbonate-based system with controlled pH (8.5-10.5) and specific additive concentrations. This compositional parameter optimization enables the fluid to maintain stability at high temperatures up to 250°F that would otherwise cause degradation of conventional fluid components

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs composite materials by creating a multi-component drilling fluid system comprising calcium carbonate base, specific polymers, surfactants, and additives formulated together. This composite formulation synergistically provides thermal stability, viscosity control, and protective functions that individual components cannot achieve alone, resolving the contradiction between high temperature operation and composition stability

Inventive Principle:
Principle #40Composite materials

2Productivity

If drilling operations continue in high-angle and horizontal wells, then production goals can be met, but stuck pipe incidents increase due to differential and mechanical sticking

Engineering Contradiction:
Improvedrilling productivityVSAvoiddrilling operation reliability
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The patent applies the taking out principle by removing harmful components and conditions that cause stuck pipe - specifically eliminating formulations that create thick filter cakes or excessive gel strength. The calcium carbonate-based fluid with optimized rheology reduces mechanical sticking by preventing cuttings accumulation and hole caving, while controlled pH prevents differential sticking, thereby maintaining reliability during continuous drilling operations

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent changes rheological parameters of the drilling fluid - specifically optimizing viscosity, gel strength, and filter cake properties through calcium carbonate formulation and pH control (8.5-10.5). These parameter adjustments prevent both mechanical sticking (by reducing cuttings accumulation) and differential sticking (by optimizing filter cake characteristics), enabling reliable continuous drilling in high-angle and horizontal wells

Inventive Principle:
Principle #35Parameter changes

3Length of stationary object

If drilling depth increases to access subsurface formations, then hydrocarbon recovery potential increases, but thermal stability of drilling fluids deteriorates

Engineering Contradiction:
Improvewell depthVSAvoiddrilling fluid thermal stability
Core Design Contradiction:
Length of stationary objectVSStability of the object's composition

Solution Approach 1:

The patent applies parameter changes by optimizing the thermal stability parameters of the drilling fluid through calcium carbonate base formulation and controlled pH (8.5-10.5). This enables the fluid to maintain compositional stability at elevated temperatures encountered at greater depths up to 250°F, preventing the chemical degradation that would otherwise limit drilling depth

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses composite materials by formulating a thermally stable multi-component system with calcium carbonate, heat-stable polymers, and specialized additives. This composite formulation maintains rheological and chemical stability at high temperatures associated with increased depth, removing the thermal stability barrier to deeper drilling operations

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The formulation of drilling fluids with manganese tetroxide and barium sulfate, along with an alkanolamine, significantly reduces stuck pipe incidents and nonproductive time by maintaining stable rheological properties and minimizing fluid loss at high temperatures, resulting in improved drilling performance and cost savings.

Implementation Method 1

Water-based drilling fluids disclosed and described here contain specific weighting agents... An embodiment includes a drilling fluid composition containing an aqueous base containing manganese tetroxide and barium sulfate functioning as weighting agents

Methodology Applied
Scientific EffectDensity increase via weighting agents:

Implementation Method 2

The drilling fluid composition contains... an alkanolamine... The drilling fluid composition is formulated such that it has stable rheological properties at a temperature ranging between about 100° F. to about 450° F.

Methodology Applied
Scientific EffectThermal stabilization:

Implementation Method 3

One such method includes the steps of introducing into a wellbore a drilling fluid... and circulating the drilling fluid through the subterranean formation during drilling

Methodology Applied
Scientific EffectFluid circulation:

Data Source

PatentUS11118094B2Compositions and methods of use of water-based drilling fluids with increased thermal stability
Publication Date: 2021.09.14 SAUDI ARABIAN OIL CO

AI summary

Provided here are water-based drilling fluids containing weighting agents and an alkanolamine, and methods of using such compositions during drilling operations for recovery of hydrocarbons. The weighting agents can include manganese tetroxide and barium sulfate. The alkanolamine can be monoethanolamine. Various other embodiments may be disclosed and claimed.