Drilling Mud Hydroxide Treatment for H2S Neutralization

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Solution Overview

Problem

Existing methods for remediating hydrogen sulfide (H2S) and ammonia (NH3) contaminants in drilling operations are inefficient and costly, particularly in preventing their release into the atmosphere around drilling platforms, as they often require continuous treatment and are ineffective in gaseous forms.

Innovation Solution

Modifying drilling mud with a liquid treatment composition containing high concentrations of hydroxide compounds, chelating agents, and organic acids, which is pumped downhole to contact and remediate gaseous contaminants, preventing their escape into the atmosphere.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If existing remediation methods are used for H2S and NH3 contaminants, then treatment can be performed, but the methods are inefficient and costly, requiring continuous treatment and being ineffective in gaseous forms

Engineering Contradiction:
Improveremediation effectivenessVSAvoidtreatment efficiency
Core Design Contradiction:
ReliabilityVSProductivity

Solution Approach 1:

The treatment composition is added to drilling mud before use, preparing the remediation system in advance. The hydroxide compounds are pre-positioned in the drilling mud, ready to immediately neutralize H2S and NH3 contaminants as they are encountered during drilling operations, eliminating the need for separate continuous treatment systems.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

Drilling mud serves as an intermediary carrier that delivers the treatment composition to the contaminants. The drilling mud circulates through the wellbore, bringing hydroxide compounds into contact with H2S and NH3 gases, facilitating remediation without requiring direct injection of treatment chemicals into the gas stream.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Productivity

If treatment compositions are added to drilling mud, then continuous drilling operations can be maintained, but the composition must be effectively delivered to contact gaseous contaminants

Engineering Contradiction:
Improvecontinuous operation capabilityVSAvoidcontaminant contact efficiency
Core Design Contradiction:
ProductivityVSEase of operation

Solution Approach 1:

The treatment composition is integrated into the drilling mud circulation system, ensuring continuous remediation action throughout the drilling operation. As the drilling mud circulates continuously through the wellbore, it continuously contacts and neutralizes H2S and NH3 contaminants, maintaining uninterrupted drilling operations without requiring periodic treatment interruptions.

Inventive Principle:
Principle #20Continuity of useful action

Solution Approach 2:

The drilling mud performs multiple functions: it serves as both the drilling fluid for cuttings removal and cooling, and as the delivery medium for the H2S and NH3 treatment composition. This multi-functionality eliminates the need for separate treatment systems and maintains continuous drilling operations.

Inventive Principle:
Principle #6Universality (Multi-functionality)

3Loss of time

If high concentrations of hydroxide compounds are used, then rapid remediation occurs within seconds, but the cost and complexity of the treatment composition increases

Engineering Contradiction:
Improveremediation timeVSAvoidtreatment composition complexity
Core Design Contradiction:
Loss of timeVSDevice complexity

Solution Approach 1:

The treatment composition uses high concentrations of hydroxide compounds (35-55 wt%) to dramatically reduce remediation time from hours to seconds. This parameter change in concentration enables rapid neutralization of H2S and NH3 contaminants upon contact, allowing drilling operations to continue without interruption despite the increased chemical concentration.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Effectively reduces H2S and NH3 levels to safe concentrations within seconds, allowing continuous drilling operations by integrating the treatment composition into the drilling mud, ensuring efficient and economical remediation of toxic gases.

Implementation Method 1

a liquid treatment composition including water and collectively 35-55 weight percent of one or more hydroxide compounds

Methodology Applied
Scientific EffectChemical reaction (neutralization): Chemical Bonding

Implementation Method 2

pumping appropriate amounts of the modified drilling mud down hole into a well bore being drilled throughout a well drilling operation such that when any gasses are released from the well bore during the drilling operation the gasses contact the modified drilling mud

Methodology Applied
Scientific EffectAbsorption: Absorption (physical)

Data Source

PatentUS11905457B2Chemical compositions and methods of using same for remediating sulfur-containing compositions and other contaminants encountered in drilling wells
Publication Date: 2024.02.20 GAPS TECHNOLOGY LLC
  • US11905457B2 patent drawing

AI summary

A modified drilling mud is provided which addresses a problem of H2S and other gaseous contaminants in the environment around a well drilling platform or other well drilling operation by remediating or eliminating the gaseous contaminants in the fluids being extracted from the well. The drilling mud is modified by addition of a liquid treatment composition including water and collectively 35-55 weight percent of one or more hydroxide compounds, wherein a ratio of the liquid treatment composition to the drilling mud in the modified drilling mud is in a range of 10 gallons of the liquid treatment composition per 42,000 gallons of drilling mud to 100 gallons of the liquid treatment composition per 42,000 gallons of drilling mud.