Drop Test Weight Percent Analysis for Catalyst Bed Resistance

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Solution Overview

Problem

Existing methods for selecting catalysts and carriers for epoxidation processes face challenges in maintaining selectivity and lifetime while avoiding costly disruptions in manufacturing, as adjustments often result in concurrent decrements in efficiency or require conditions that are not reproducible within the process.

Innovation Solution

A method involving an improved drop test that analyzes weight percent of nonintact structures rather than number percent, allowing for the selection of structures that exhibit minimized bed resistance increase during the first year of operation, thereby predicting catalyst bed selectivity and lifetime prior to use.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Measurement precision

If conventional drop tests using number percent are used to select structures, then the selection process is simple, but the predicted bed resistance increase is inaccurate

Engineering Contradiction:
Improveprediction accuracy of bed resistance increaseVSAvoidtest method complexity
Core Design Contradiction:
Measurement precisionVSDevice complexity

Solution Approach 1:

The patent changes the measurement parameter from number percent to weight percent in the drop test methodology. This parameter change improves the correlation between test results and actual bed resistance increase, providing more accurate predictions of catalyst bed performance while maintaining the fundamental simplicity of the drop test approach.

Inventive Principle:
Principle #35Parameter changes

2Reliability

If catalyst adjustments are made to improve selectivity or lifetime, then one performance metric improves, but another metric deteriorates

Engineering Contradiction:
Improvecatalyst lifetimeVSAvoidcatalyst efficiency
Core Design Contradiction:
ReliabilityVSProductivity

Solution Approach 1:

The patent applies preliminary action by conducting drop tests with weight percent analysis before catalyst deployment to predict bed resistance increase. This allows selection of structures that will maintain stable performance over time, preventing future productivity losses from premature catalyst deactivation or excessive pressure drop, thus extending effective catalyst lifetime without sacrificing initial efficiency.

Inventive Principle:
Principle #10Preliminary action

3Productivity

If catalyst bed resistance increases significantly during operation, then manufacturing disruptions occur, but maintaining low resistance requires frequent catalyst changes

Engineering Contradiction:
Improvemanufacturing continuityVSAvoidcatalyst replacement frequency
Core Design Contradiction:
ProductivityVSEase of manufacture

Solution Approach 1:

The patent implements feedback by using weight percent drop test results to predict future bed resistance increase. This predictive feedback allows manufacturers to select structures that will maintain acceptable pressure drop characteristics throughout the catalyst lifecycle, enabling informed decisions about catalyst selection that balance manufacturing continuity with replacement frequency without requiring frequent interruptions.

Inventive Principle:
Principle #23Feedback

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The method effectively identifies structures that can maintain up to 15% increase in bed resistance during the first year of operation, reducing costly disruptions and extending catalyst life, thus enhancing manufacturing efficiency.

Implementation Method 1

causing a plurality of intact structures having a total weight to contact a surface by releasing the plurality of structures at a distance above the surface

Methodology Applied
Scientific EffectImpact force: Impact Force

Data Source

PatentEP2715311B1Methods for testing structures, and selection methods using these
Publication Date: 2023.03.15 DOW TECHNOLOGY INVESTMENTS LLC
  • EP2715311B1 patent drawingFigure 1A~1C
  • EP2715311B1 patent drawingFigure 2
  • EP2715311B1 patent drawingFigure 3A

AI summary

Test method for structures, e.g., such as carriers and/or catalysts. The methods may be used to select the carriers and/or catalysts for future use. Carriers and catalysts so selected, and processes making use of these, are also provided.