Dry Cellulosic Compositions for Stable Reconstitution

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Solution Overview

Problem

Existing dry powdered compositions for liquid cleansing formulations face issues such as shelf life, uneven reconstitution, phase separation, and gel settling, which are not adequately addressed by existing technologies.

Innovation Solution

A dry composition comprising 30 to 90 wt% surfactant, 1 to 6 wt% chelating agent, 0.5 to 20 wt% preservative, and cellulosic polymer with a degree of substitution less than 0.7, which is reconstituted with a liquid carrier to form a stable liquid formulation with desired rheology and viscosity, avoiding gel settling and separation.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If dry powdered compositions are used as alternative to bottled liquid formulations, then packaging and handling costs are reduced and transport issues are avoided, but shelf life is compromised and reconstitution problems occur

Engineering Contradiction:
Improvepackaging and handling costsVSAvoidshelf life and reconstitution stability
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The patent applies parameter changes by carefully controlling the degree of substitution (DS) of cellulosic polymer to be between 0.6 and 0.8, and maintaining specific ratios of different cellulosic polymers. These parameter optimizations ensure the dry powder maintains stability during storage while reconstituting properly to form stable liquid formulations without phase separation or gel settling.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses composite materials by combining multiple cellulosic polymers with different degrees of substitution (DS 0.6-0.8 and DS 0.85-0.95) in specific ratios. This composite approach creates a synergistic effect where the mixture provides both the stability needed for dry powder storage and the solubility required for proper reconstitution, resolving the contradiction between storage reliability and reconstitution performance.

Inventive Principle:
Principle #40Composite materials

2Ease of operation

If dry powdered compositions are reconstituted to liquid formulations, then delivery and shelf stability are improved, but uneven reconstitution and phase separation occur

Engineering Contradiction:
Improvedelivery and shelf stabilityVSAvoidreconstitution uniformity and phase stability
Core Design Contradiction:
Ease of operationVSStability of the object's composition

Solution Approach 1:

The patent optimizes parameters by specifying cellulosic polymer degree of substitution within 0.6-0.8 and controlling the ratio between different polymer types. These parameter controls ensure uniform reconstitution by preventing both incomplete dissolution and phase separation, maintaining composition stability throughout the reconstitution process and final product storage.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent achieves homogeneity by using cellulosic polymers with controlled degree of substitution that ensure uniform dissolution in the liquid carrier. The specific polymer composition promotes homogeneous distribution of all formulation components, preventing phase separation and ensuring consistent reconstitution across different batches and storage conditions.

Inventive Principle:
Principle #33Homogeneity

3Loss of energy

If conventional dry powdered compositions are used, then transportation costs are reduced, but gel settling and separation of phases occur

Engineering Contradiction:
Improvetransportation costsVSAvoidgel settling and phase separation
Core Design Contradiction:
Loss of energyVSStability of the object's composition

Solution Approach 1:

The patent employs composite materials by formulating dry powder with a specific mixture of cellulosic polymers having different degrees of substitution (0.6-0.8 and 0.85-0.95). This composite structure prevents gel settling and phase separation by creating a balanced system that maintains colloidal stability, allowing the product to be transported in dry powder form without the high costs associated with liquid formulation transportation.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent applies parameter changes by optimizing the degree of substitution of cellulosic polymers to specific ranges (0.6-0.8 and 0.85-0.95) and controlling their ratios. These parameter optimizations ensure that the dry powder formulation remains stable during transportation and storage, preventing gel settling and phase separation upon reconstitution, thereby enabling cost-effective dry powder transportation.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composition allows for stable, easy delivery and increased shelf stability of liquid cleansing formulations with improved reconstitution properties, reducing handling and transportation costs.

Implementation Method 1

cellulosic polymer, wherein at most 50 wt% of the total weight of cellulosic polymer has degree of substitution less than 0.7

Methodology Applied
Scientific EffectGel formation and stabilization: Gel

Implementation Method 2

stable liquid formulation with desired rheology and viscosity, avoiding gel settling and separation

Methodology Applied
Scientific EffectPhase separation prevention: Emulsion

Implementation Method 3

A liquid formulation is obtained by reconstituting the dry composition according to the first aspect with a suitable liquid carrier

Methodology Applied
Scientific EffectDissolution: Solvation

Data Source

PatentEP4475962B1Dry compositions and methods for forming stable liquid cleansing formulations
Publication Date: 2025.08.06 UNILEVER IP HLDG BV
  • EP4475962B1 patent drawing
  • EP4475962B1 patent drawing
  • EP4475962B1 patent drawing

AI summary

This invention relates to dry compositions and methods for forming stable liquid personal cleansing formulations. The dry composition of the present invention comprises 30 to 90 wt% of surfactant; 1 to 6 wt% of chelating agent; 0.5 to 20 wt% preservative; and cellulosic polymer, wherein at most 50 wt% of the total weight of cellulosic polymer has degree of substitution less than 0.7.