Dry Electrode Film Processing for Binder Fibrilization Control

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Solution Overview

Problem

Existing methods for manufacturing dry electrodes for electrochemical devices face challenges such as micronization of active materials and degradation of mechanical properties due to high-shear mixing processes, which also lead to uneven drying and potential defects in the electrode active layer.

Innovation Solution

A dry manufacturing process is employed to produce a dry electrode film with a binder resin crystallinity of 10% or less, using a method that includes preparing a powdery blend, kneading, pulverizing, and calendering to achieve improved mechanical properties and uniformity.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If high-shear mixing process is used to manufacture dry electrode, then binder fibrilization is maximized, but active material is micronized and mechanical properties are degraded

Engineering Contradiction:
Improvemechanical propertiesVSAvoidactive material particle size
Core Design Contradiction:
StrengthVSManufacturing precision

Solution Approach 1:

The mixing process is divided into multiple stages with different shear rates. A low-shear mixing stage is used first to prevent active material micronization, followed by a high-shear mixing stage to achieve binder fibrilization. This segmentation allows each mixing stage to perform its specific function without compromising the other, resolving the contradiction between maintaining active material particle size and achieving binder fibrilization.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The mixing process uses dynamic adjustment of shear rate throughout the mixing cycle. The shear rate is kept low during initial mixing to protect active material particles, then increased to high levels for binder fibrilization. This dynamic control of mixing intensity allows the system to adapt to different process requirements at different times, preventing micronization while achieving maximum binder fibrilization.

Inventive Principle:
Principle #15Dynamics

2Quantity of substance

If conventional drying process is used to remove solvent from electrode mixture, then solvent is removed, but pinholes and cracks are generated in electrode active layer

Engineering Contradiction:
Improvesolvent removalVSAvoidelectrode active layer quality
Core Design Contradiction:
Quantity of substanceVSManufacturing precision

Solution Approach 1:

The solvent is completely extracted from the electrode mixture before the drying process. By removing all solvent through filtration or decantation prior to drying, there is no solvent remaining to evaporate and cause pinholes or cracks in the electrode active layer. This extraction approach eliminates the harmful evaporation process while still achieving complete solvent removal.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The solvent removal step is performed as a preliminary action before drying. By completely removing solvent through filtration or decantation before the drying process begins, the subsequent drying step only needs to remove moisture, which occurs without forming pinholes or cracks. This preliminary solvent extraction prevents the formation of defects that would otherwise occur during solvent evaporation.

Inventive Principle:
Principle #10Preliminary action

3Manufacturing precision

If uniform drying process is implemented to prevent powder floating, then drying uniformity is improved, but manufacturing cost and time increase significantly

Engineering Contradiction:
Improvedrying uniformityVSAvoidmanufacturing cost and time
Core Design Contradiction:
Manufacturing precisionVSProductivity

Solution Approach 1:

The solvent is extracted and removed before drying, eliminating the need for prolonged drying processes. This preliminary removal of bulk solvent through filtration or decantation allows subsequent drying to be completed quickly and uniformly without the need for expensive, time-consuming controlled drying equipment, thus maintaining drying uniformity while improving productivity.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The process uses simple, inexpensive drying methods rather than expensive, complex drying equipment. By removing solvent beforehand through basic filtration or decantation, the drying step can be performed using simple ovens or even air drying, replacing the need for costly controlled atmosphere drying equipment while achieving sufficient drying uniformity.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

4Manufacturing precision

If dry manufacturing process is used to eliminate solvent, then solvent-related defects are prevented, but binder fibrilization is insufficient without high-shear mixing

Engineering Contradiction:
Improveelectrode qualityVSAvoidbinder fibrilization
Core Design Contradiction:
Manufacturing precisionVSStrength

Solution Approach 1:

The mixing process is segmented into low-shear and high-shear stages. The low-shear stage mixes ingredients without causing active material micronization, while the subsequent high-shear stage achieves充分的 binder fibrilization. This segmentation allows the dry manufacturing process to achieve both electrode quality and binder fibrilization without the compromises of single-stage mixing.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The mixing process dynamically adjusts shear rate to match process requirements. Low shear is applied during initial mixing to protect active material particles in the dry state, then high shear is applied to achieve maximum binder fibrilization. This dynamic control enables the dry manufacturing process to overcome the limitation of insufficient binder fibrilization while maintaining electrode quality.

Inventive Principle:
Principle #15Dynamics

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The method minimizes micronization of active materials, maximizes binder fibrilization, and enhances the mechanical properties of the dry electrode, such as flexibility and strength, while allowing for easier control of processing conditions.

Implementation Method 1

the binder resin contained in the dry electrode film has a crystallinity of 10% or less

Methodology Applied
Scientific EffectCrystallization: Crystallisation

Data Source

PatentUS20250192183A1Electrode for Electrochemical Device Comprising Dry Electrode Film and Method for Manufacturing the Same
Publication Date: 2025.06.12 LG ENERGY SOLUTION LTD
  • US20250192183A1 patent drawing
  • US20250192183A1 patent drawing

AI summary

Disclosed is a method for manufacturing a dry electrode. The method allows determination of the micro-fibrilization degree of a binder resin from the crystallinity of the binder resin. Based on this, the processing conditions of mixed powder for electrode or an electrode film may be controlled. In this manner, it is possible to check and control the processing conditions easily and efficiently. In addition, the method for manufacturing a dry electrode includes a kneading step using a kneader under a low speed and high temperature and pulverization step. Therefore, there is no problem of blocking of a flow path caused by aggregation of the ingredients, which is favorable to mass production.