Dual Adsorbent Media for Metal Deposition Solution Purification

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Solution Overview

Problem

Existing methods for purifying process solutions in surface treatment, such as electrolytes for metal deposition, are limited in their ability to remove both organic and inorganic impurities effectively, often leading to increased operational costs and reduced solution lifespan due to filter clogging, high energy demands, and inability to handle dissolved substances.

Innovation Solution

A method involving the use of at least two distinct adsorbent media, including polymer resins and ion exchange resins, to selectively adsorb and remove organic and inorganic impurities from the process solution, with the ability to regenerate these media using specific solutions, allowing for continuous purification and adaptation to different impurities.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Measurement precision

If filtration methods are used to remove particles from process solutions, then particle removal efficiency is improved, but filter clogging and flow resistance increase

Engineering Contradiction:
Improveparticle removal efficiencyVSAvoidflow resistance
Core Design Contradiction:
Measurement precisionVSProductivity

Solution Approach 1:

The invention extracts and removes particles from the process solution using filtration methods, separating the harmful particles from the useful electrolyte. The filter device is designed to continuously remove particles without significant flow resistance increase by implementing a system that can handle the filter cake formation without clogging.

Inventive Principle:
Principle #2Taking out (Extraction)

2Measurement precision

If micro- or ultra-filtration with small pore size membranes is used, then particle retention power is improved, but flow resistance increases significantly

Engineering Contradiction:
Improveparticle retention powerVSAvoidflow resistance
Core Design Contradiction:
Measurement precisionVSProductivity

Solution Approach 1:

The invention applies different pore sizes and filtration characteristics to different regions or stages of the filtration process. The filter device may incorporate multiple filtration layers or zones with varying pore structures, allowing high retention power in critical areas while maintaining adequate flow channels in other regions to minimize overall flow resistance.

Inventive Principle:
Principle #3Local quality

3Measurement precision

If UV/H2O2 oxidation is used to remove organic decomposition products, then organic impurity removal is improved, but inorganic contraries cannot be removed and additives must be redosed

Engineering Contradiction:
Improveorganic impurity removalVSAvoidimpurity removal scope
Core Design Contradiction:
Measurement precisionVSAdaptability or versatility

Solution Approach 1:

The invention implements a multi-functional purification system that combines multiple treatment methods (filtration, oxidation, and other removal techniques) into a single integrated device. This universal system can handle both organic and inorganic impurities, eliminating the need for separate treatment processes and avoiding the drawback of having to redose additives after oxidation treatment.

Inventive Principle:
Principle #6Universality (Multi-functionality)

4Measurement precision

If liquid-liquid extraction is used to remove impurities, then selective impurity removal is improved, but the method is limited to non-mixable extraction systems and cannot remove inorganic contraries

Engineering Contradiction:
Improveselective impurity removalVSAvoidimpurity removal scope
Core Design Contradiction:
Measurement precisionVSAdaptability or versatility

Solution Approach 1:

The invention merges multiple purification methods including filtration, oxidation, and extraction into a single integrated filter device. By combining these different purification mechanisms, the system achieves both selective organic impurity removal and inorganic contrary removal, overcoming the limitations of individual methods.

Inventive Principle:
Principle #5Merging (Combining)

5Ease of operation

If extensive industrial instrumentation is used to maintain constant filter flow resistance, then flow resistance control is improved, but device complexity increases

Engineering Contradiction:
Improveflow resistance controlVSAvoidinstrumentation complexity
Core Design Contradiction:
Ease of operationVSDevice complexity

Solution Approach 1:

The filter device is designed with self-regulating features that automatically maintain constant flow resistance without requiring extensive external instrumentation. The system may incorporate self-cleaning mechanisms, automatic filter replacement, or design features that naturally prevent flow resistance buildup, allowing the filter to maintain optimal performance through its own structural characteristics rather than complex control systems.

Inventive Principle:
Principle #25Self-service

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enables efficient, cost-effective removal of a wide range of impurities, including organic decomposition products and foreign ions, extending the service life of process solutions and reducing operational costs by allowing for independent regeneration of adsorbent media.

Implementation Method 1

contacting the process solution with at least two distinct adsorbent media to remove the impurities from the process solution, wherein the adsorbent media are distinct from each other with respect to species of impurities adsorbed thereon

Methodology Applied
Scientific EffectAdsorption: Adsorption

Implementation Method 2

a second polymer resin is an ion exchange resin charged with an ion source corresponding to an ingredient contained in the process solution before the contacting, which ion source is at least partially transferred from the ion exchange resin into the process solution during the contacting

Methodology Applied
Scientific EffectIon exchange: Ion Exchange

Data Source

PatentUS8202431B2Method for removing impurities from a metal deposition process solution
Publication Date: 2012.06.19 MACDERMID ENTHONE INC
  • US8202431B2 patent drawing
  • US8202431B2 patent drawing

AI summary

A method and apparatus involving at least two distinct adsorbent media for adsorptive removal of impurities from a metal deposition composition such as an electroless or electrolytic deposition composition.