Dual Catalyst Exhaust Treatment for Continuous Methane Oxidation
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Solution Overview
Problem
Existing catalysts for oxidizing unburnt hydrocarbons in natural gas-fired engine exhaust quickly deactivate due to contamination, requiring frequent regeneration, which is impractical or costly, and result in unacceptable emissions.
Innovation Solution
An exhaust treatment system with a reactor chamber and an adjacent regeneration chamber, using multiple catalyst blocks that can be alternately positioned between the two chambers for continuous operation, with one catalyst in the reactor chamber oxidizing hydrocarbons while the other undergoes regeneration, facilitated by a combustible fluid to maintain reaction temperature and a regeneration fluid to remove contaminants.
Engineering Contradictions & Design Principles
Engineering Contradiction Analysis
1Device complexity
If a single catalyst block is used in the reactor chamber, then the system structure is simple, but the catalyst quickly deactivates due to contamination requiring frequent regeneration
Solution Approach 1:
The catalyst system is segmented into multiple catalyst blocks (first catalyst block, second catalyst block) that can be independently positioned in the reactor chamber or regeneration chamber. This segmentation allows one catalyst to be actively treating exhaust while another is being regenerated, preventing single-catalyst deactivation and maintaining continuous system reliability.
Solution Approach 2:
The system employs dynamic positioning of catalyst blocks between the reactor chamber and regeneration chamber. The catalyst blocks are movable and can be switched between chambers based on their regeneration status, enabling continuous operation without system shutdown and maintaining constant catalyst activity.
2Reliability
If frequent catalyst regeneration is performed, then catalyst activity is maintained, but system operation is interrupted and costs increase
Solution Approach 1:
The system maintains continuous useful action by having multiple catalyst blocks in different operational states simultaneously. While one catalyst block is actively oxidizing hydrocarbons in the reactor chamber, another is being regenerated in the regeneration chamber, ensuring uninterrupted catalyst activity and continuous exhaust treatment without system shutdowns.
Solution Approach 2:
The system performs preliminary regeneration action on a standby catalyst block before it is needed in the reactor chamber. The regeneration process is completed in advance in the regeneration chamber, so when the active catalyst deactivates, a freshly regenerated catalyst is already ready to immediately take over, maintaining continuous operation.
3Productivity
If multiple catalyst blocks are used with alternate positioning, then continuous operation is achieved, but device complexity increases
Solution Approach 1:
The system merges the reactor chamber and regeneration chamber into a single integrated exhaust treatment system with shared components. The combustor, catalyst positioning mechanisms, and exhaust flow paths are combined across both chambers, reducing overall system complexity despite having multiple catalyst blocks and enabling continuous operation.
Applied Scientific Principles
This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.
Function Achieved in This Case
Enables continuous operation of natural gas-fired engines with constant methane reduction, reducing system complexity, cost, and frequency of catalyst regeneration.
Implementation Method 1
a first catalyst block, wherein the first catalyst block is configured to oxidize unburnt hydrocarbons in an exhaust stream from the engine
Implementation Method 2
a first catalyst block configured to oxidize unburnt hydrocarbons in an exhaust stream from the engine when positioned in the reactor chamber
Implementation Method 3
heating the first catalyst block within the reactor chamber based on reacting the combustible fluid with the first catalyst block
Data Source
AI summary
An exhaust treatment system comprises a reactor chamber configured to be fluidly coupled to an exhaust outlet of an engine, a regeneration chamber adjacent the reactor chamber, a regeneration system fluidly coupled to the regeneration chamber that is configured to generate a flow of regeneration fluid in the regeneration chamber, a first catalyst block, and a second catalyst block. The first catalyst block and the second catalyst block are configured to oxidize unburnt hydrocarbons in an exhaust stream from the engine. The treatment system can also include a combustible fluid injector for injecting a combustible fluid to raise the temperature of the first catalyst block and second catalyst block to a reaction temperature during use.


