Dual Cement Composition for Rapid Setting and Fluid Loss Control

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Solution Overview

Problem

Current cement compositions used to prevent fluid loss in subterranean formations often have issues with thickening time and compressive strength, leading to equipment damage or prolonged waiting times for setting, and may not effectively fill highly-permeable areas such as vugs and fissures.

Innovation Solution

A method involving the simultaneous introduction of two cement compositions, one containing aluminate cement and the other a pozzolan, which mix in the formation to form a mixed cement composition with rapid thickening and setting properties, allowing effective filling of permeable areas and preventing fluid loss.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional cement compositions are used to prevent fluid loss, then fluid loss prevention is achieved, but thickening time is excessive and compressive strength is insufficient

Engineering Contradiction:
Improvefluid loss preventionVSAvoidthickening time
Core Design Contradiction:
ReliabilityVSLoss of time

Solution Approach 1:

The patent changes the chemical parameters of the cement composition by incorporating specific additives including accelerators (such as calcium chloride, calcium nitrate, or phosphates) and admixtures that modify the hydration rate. These parameter changes enable the cement to achieve rapid thickening (within 5-30 minutes) while maintaining adequate compressive strength and fluid loss prevention properties.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite cement system by combining conventional cement (Class G or H) with aluminate cement in specific proportions (1:4 to 4:1 ratio), along with various additives including viscosifiers, fluid loss control agents, and accelerators. This composite formulation achieves synergistic effects that simultaneously provide rapid thickening, high compressive strength, and effective fluid loss prevention.

Inventive Principle:
Principle #40Composite materials

2Reliability

If conventional cement compositions are used, then fluid loss prevention is achieved, but compressive strength is insufficient leading to equipment damage

Engineering Contradiction:
Improvefluid loss preventionVSAvoidcompressive strength
Core Design Contradiction:
ReliabilityVSStrength

Solution Approach 1:

The patent modifies the chemical composition parameters by adding accelerators such as calcium chloride (0.1-5% by weight), calcium nitrate, or phosphate-based accelerators that significantly enhance the rate of strength development. These parameter changes enable the cement to achieve high compressive strength (exceeding 1000 psi) within 6-24 hours, preventing equipment damage while maintaining fluid loss prevention.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent formulates a composite cement system combining Class G or H cement with aluminate cement and high-early-strength additives. This composite material achieves superior compressive strength properties through the synergistic interaction of different cementitious materials and chemical accelerators, ensuring both fluid loss prevention and equipment protection.

Inventive Principle:
Principle #40Composite materials

3Ease of operation

If cement composition sets slowly, then pumpability is maintained, but waiting time for setting is excessive

Engineering Contradiction:
ImprovepumpabilityVSAvoidsetting time
Core Design Contradiction:
Ease of operationVSLoss of time

Solution Approach 1:

The patent creates a dynamic thickening profile by incorporating retarded accelerators that provide an initial induction period maintaining pumpability, followed by rapid acceleration of the setting process. This dynamic behavior allows the cement to remain pumpable during injection, then quickly set (within 5-30 minutes thickening time) to minimize waiting time and restore production.

Inventive Principle:
Principle #15Dynamics

Solution Approach 2:

The patent uses chemical additives including retarders and accelerators that dynamically change the rheological parameters during the setting process. These parameter changes enable the cement to maintain low viscosity and pumpability during injection, then rapidly increase viscosity and set to minimize overall setting time and restore well productivity.

Inventive Principle:
Principle #35Parameter changes

4Reliability

If cement composition does not fill permeable areas effectively, then fluid loss continues, but thickening time increases

Engineering Contradiction:
Improvefluid loss controlVSAvoidthickening time
Core Design Contradiction:
ReliabilityVSLoss of time

Solution Approach 1:

The patent modifies the rheological parameters by adding viscosifiers and fluid loss control agents that increase the viscosity and gel strength of the cement slurry. These parameter changes enable the cement to rapidly thicken and set in highly permeable formations, effectively plugging vugs and fissures to stop fluid loss within 5-30 minutes without requiring extended thickening times.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The mixed cement composition achieves rapid thickening and high compressive strength, effectively inhibiting fluid loss into the subterranean formation by quickly forming a solid barrier in permeable areas, enhancing operational efficiency and reducing costs.

Implementation Method 1

rapid thickening and setting properties

Methodology Applied
Scientific EffectThickening:

Implementation Method 2

rapid thickening and setting properties

Methodology Applied
Scientific EffectSetting:

Implementation Method 3

high compressive strength

Methodology Applied
Scientific EffectCompressive strength development:

Data Source

PatentUS10487256B2Cement compositions having fast setting times and high compressive strengths
Publication Date: 2019.11.26 HALLIBURTON ENERGY SERVICES INC
  • US10487256B2 patent drawing
  • US10487256B2 patent drawing
  • US10487256B2 patent drawing

AI summary

A method of treating a subterranean formation comprising: introducing a first cement composition into the subterranean formation, wherein the first cement composition comprises: (A) a first aluminate cement; and (B) a base fluid; simultaneously introducing a second cement composition into the subterranean formation, wherein the second cement composition comprises: (A) a second cement consisting of cement or a pozzolan; and (B) a base fluid, wherein at least a portion of the first and second cement compositions mix together after introduction into the subterranean formation to form a mixed cement composition, and wherein at least some of the first and second cement compositions or at least some of the mixed cement composition enters into a highly-permeable area located within the subterranean formation; and allowing the mixed cement composition to set. The base fluid can be an aqueous liquid or a hydrocarbon liquid.