Dual-Character Polysaccharide for Cotton Soil Release

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Solution Overview

Problem

Conventional soil release polymers are ineffective on cotton fabrics and blended fabrics, as they do not adequately remove hydrophilic and hydrophobic soils, leading to incomplete stain removal and increased reliance on other cleaning technologies, which can be costly and inefficient.

Innovation Solution

Development of a fabric care composition featuring a randomly substituted polysaccharide backbone with specific functional groups, including alkoxy, nitrogen-containing, and anionic substitutions, which effectively modifies the fabric surface to enhance soil release and cleaning, particularly on cotton and blended fabrics.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional soil release polymers are used, then they are effective on polyester or synthetic fabrics, but they have little or no effect on cotton articles and blended fabrics

Engineering Contradiction:
Improvesoil release effectivenessVSAvoidfabric type compatibility
Core Design Contradiction:
ReliabilityVSAdaptability or versatility

Solution Approach 1:

The patent modifies the chemical parameters of soil release polymers by introducing cationic functional groups (quaternary ammonium, tertiary amine) and controlling the degree of substitution (0.1-2.0 per anhydroglucosyl unit). These parameter changes enable the polymer to interact effectively with cotton and blended fabrics through electrostatic and hydrogen bonding mechanisms, while maintaining effectiveness on synthetic fabrics.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention creates a composite polymer structure by combining a polysaccharide backbone (providing water solubility and biodegradability) with cationic functional groups (providing fabric affinity and soil release capability). This composite structure achieves universal effectiveness across different fabric types by integrating multiple functional properties into a single material system.

Inventive Principle:
Principle #40Composite materials

2Reliability

If multiple cleaning technologies are combined to remove all types of soils, then complete soil removal is achieved, but cost and formulation complexity increase

Engineering Contradiction:
Improvesoil removal completenessVSAvoidformulation complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent designs a multi-functional soil release polymer that simultaneously addresses hydrophobic soil removal, hydrophilic soil removal, and fabric surface modification. The polymer's dual character (hydrophobic hydrocarbon chains and hydrophilic polysaccharide backbone with cationic groups) enables it to perform multiple cleaning functions, reducing the need for separate cleaning technologies and simplifying formulation.

Inventive Principle:
Principle #6Universality (Multi-functionality)

3Reliability

If conventional surfactants and polymers are used, then some soil removal is achieved, but complete removal of greasy/oily stains and colored stains is not achieved, especially at low water temperatures

Engineering Contradiction:
Improvestain removal effectivenessVSAvoidwater temperature dependency
Core Design Contradiction:
ReliabilityVSTemperature

Solution Approach 1:

The patent creates a composite polymer structure combining hydrophobic hydrocarbon chains (for grease and oil interaction) with hydrophilic polysaccharide backbone and cationic functional groups (for fabric affinity and soil suspension). This composite structure enables effective stain removal at low temperatures by providing both hydrophobic interaction with oils and hydrophilic interaction with water, eliminating temperature dependency.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composition achieves improved soil release and cleaning on cotton and blended fabrics, reducing the need for other cleaning technologies and allowing for more cost-effective formulations while enhancing consumer noticeability of cleaning performance.

Implementation Method 1

the polymers of the present invention provide soil release and cleaning benefits in fabric care products... effectively modifies the fabric surface to enhance soil release and cleaning

Methodology Applied
Scientific EffectAdsorption: Adsorption

Data Source

PatentEP2350246B1Dual character polymer useful in fabric care products
Publication Date: 2017.12.20 PROCTER & GAMBLE CO
  • EP2350246B1 patent drawing
  • EP2350246B1 patent drawing
  • EP2350246B1 patent drawing

AI summary

New fabric care compositions including soil release polymers containing anionic substitution, nitrogen containing substitution, and alkoxy substitution are disclosed. In particular, fabric care compositions containing modified polysaccharides having anionic substitution, nitrogen containing substitution, and alkoxy substitution and methods of forming the same are disclosed