Dual-Cure Microcapsules for Linear Fragrance Release

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Solution Overview

Problem

Existing fabric conditioners fail to provide a consistent and long-lasting fragrance across multiple stages of the laundry process, as free perfume oil is too weak and encapsulated technologies often release perfume at a single specific stage rather than providing a linear release profile.

Innovation Solution

A fabric conditioning composition comprising a mixture of two types of microcapsules with different curing temperatures and times, where one capsule is cured at or above 100°C and the other below, ensuring stability and controlled release of fragrance throughout the laundry process.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Illumination intensity

If free perfume oil is used, then initial fragrance intensity is strong, but fragrance dissipates quickly and is washed away

Engineering Contradiction:
Improveinitial fragrance intensityVSAvoidfragrance longevity
Core Design Contradiction:
Illumination intensityVSDuration of action of stationary object

Solution Approach 1:

The perfume is segmented into multiple encapsulated forms with different release characteristics. The invention uses a combination of encapsulated perfume (in microcapsules) and free perfume, where the encapsulated portion provides sustained release while the free perfume provides initial intensity. This segmentation allows different portions of the perfume to serve different temporal functions.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The invention changes the physical state and delivery parameters of the perfume by using encapsulation technology. The encapsulated perfume is contained in microcapsules that control release through diffusion or mechanical rupture, fundamentally changing how the perfume is delivered compared to free perfume oil. This parameter change enables controlled release over time.

Inventive Principle:
Principle #35Parameter changes

2Duration of action of stationary object

If encapsulated perfume is used, then fragrance delivery is controlled and sustained, but release occurs at specific stages rather than providing linear release across all stages

Engineering Contradiction:
Improvefragrance delivery controlVSAvoidrelease profile flexibility
Core Design Contradiction:
Duration of action of stationary objectVSAdaptability or versatility

Solution Approach 1:

The invention merges multiple encapsulation technologies with different release characteristics into a single composition. Specifically, it combines microencapsulated perfume (providing sustained release) with macroencapsulated perfume (providing friction-based release). This merging creates a synergistic effect where both encapsulation types work together to provide comprehensive coverage across all laundry stages.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The perfume composition is designed to be universal across multiple laundry stages. The combination of different encapsulation types ensures the perfume functions effectively during washing, drying, ironing, and storage stages. Each encapsulation type contributes to different stages, making the overall composition universally effective throughout the entire laundry process.

Inventive Principle:
Principle #6Universality (Multi-functionality)

3Device complexity

If single-type encapsulation is used, then perfume release mechanism is simple, but release profile is limited to specific stages

Engineering Contradiction:
Improveencapsulation system simplicityVSAvoidrelease coverage across stages
Core Design Contradiction:
Device complexityVSDuration of action of stationary object

Solution Approach 1:

The encapsulation system is segmented into distinct types with different release mechanisms. The invention uses both microencapsulation (for diffusion-based sustained release) and macroencapsulation (for friction-based release). This segmentation allows each type to target specific release needs, collectively providing coverage across all laundry stages while maintaining relatively simple individual mechanisms.

Inventive Principle:
Principle #1Segmentation

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composition achieves a linear fragrance release profile across multiple stages, enhancing perfume perception and stability, maintaining fragrance intensity during wear and storage, and providing a consistent scent experience.

Implementation Method 1

the first and second capsules differ in properties due to their polymer walls having been made using the same polymer and different cure temperatures, curing times

Methodology Applied
Scientific EffectPolymerization: Photopolymerisation

Implementation Method 2

diffusive action, wherein perfume is released by diffusion through the outer wall of the encapsulate

Methodology Applied
Scientific EffectDiffusion: Diffusion

Implementation Method 3

shear sensitive action, where the perfume core is released in response to mechanical rupture of the encapsulate

Methodology Applied
Scientific EffectMechanical rupture: Fracture Mechanics

Data Source

PatentEP3068858B2Fabric conditioners comprising encapsulated active material
Publication Date: 2020.06.10 UNILEVER PLC
  • EP3068858B2 patent drawing
  • EP3068858B2 patent drawing
  • EP3068858B2 patent drawing

AI summary

A fabric conditioning composition comprising: (a) at least 8 wt % of a fabric conditioning active; (b) a first capsule containing an active material, wherein the first capsule comprises a cured polymeric wall and a core; and (c) a second capsule containing an active material wherein the second capsule comprises a cured polymeric wall and a core; wherein the first and second capsules differ in properties due to their polymer walls having been made using the same polymer and different cure temperatures, curing times, or a combination thereof.