Dual-Dispersant UV Absorber Dispersion for Uniform Static Dyeing

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Solution Overview

Problem

The static dyeing process experiences differential pressure issues due to the inclusion of UV absorber preparations containing benzotriazoles, benzotriazines, and benzophenones, leading to uneven dye deposition and faulty dyeing, especially with finer fibers and higher substrate densities.

Innovation Solution

A mixture of at least two different dispersants, comprising 75-95% of a specific compound and 5-25% of a formaldehyde condensation product, is combined with UV absorbers to reduce differential pressure, along with an aqueous dispersion containing 5-40% UV absorbers and 5-30% dispersants, which are used in conjunction with stabilizing agents to enhance dyeing uniformity.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If UV absorber preparations containing benzotriazoles, benzotriazines, and benzophenones are included in the static dyeing process, then textiles are protected from ultraviolet light damage, but differential pressure increases causing uneven dye deposition

Engineering Contradiction:
ImproveUV protection of textilesVSAvoiduniformity of dye deposition
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

A dispersing agent mixture comprising a polyether carboxylic acid component and a formaldehyde condensation product of aromatic sulfonic acid is introduced as an intermediary substance. This mixture mediates between the UV absorbers and the dyeing system, preventing the harmful interaction that causes differential pressure while maintaining UV protection functionality

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent changes the chemical composition parameters of the dispersing system by using a specific mixture of two dispersing agents with defined weight ratios (75-95% component A and 5-25% component B). This parameter change transforms the dyeing system from one that generates differential pressure to one that maintains uniform pressure and even dye deposition

Inventive Principle:
Principle #35Parameter changes

2Manufacturing precision

If the dye bath temperature is elevated to transport dyes into the fiber, then dye exhaustion is achieved, but the pressure differential increases causing uneven circulation

Engineering Contradiction:
Improvedye exhaustion into fiberVSAvoiddifferential pressure in dye bath
Core Design Contradiction:
Manufacturing precisionVSStress or pressure

Solution Approach 1:

The dispersing agent mixture acts as a thermal intermediary that stabilizes pressure conditions during temperature elevation. It enables the dye bath to undergo necessary temperature increases for dye exhaustion while maintaining uniform pressure distribution throughout the circulation system

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent modifies the chemical environment parameters by introducing the dispersing agent mixture, which changes the physical-chemical properties of the dye bath. This allows the system to tolerate higher temperatures without generating harmful pressure differentials, thus achieving both dye exhaustion and pressure stability

Inventive Principle:
Principle #35Parameter changes

3Ease of operation

If dispersants commonly used for synthetic fibers are applied, then dyeing process is facilitated, but differential pressure problems worsen with certain UV absorbers and dyes

Engineering Contradiction:
Improvefacilitation of dyeing processVSAvoiduniformity of dyeing
Core Design Contradiction:
Ease of operationVSManufacturing precision

Solution Approach 1:

The patent creates a composite dispersing system by combining two different dispersing agents (polyether carboxylic acid component and formaldehyde condensation product) in specific proportions. This composite approach provides the benefits of facilitation while eliminating the harmful differential pressure effects that occur with conventional single dispersants

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The invention changes the compositional parameters of the dispersing system from conventional single-agent formulations to a dual-component mixture with specific weight ratios. This parameter change transforms the interaction between dispersants, UV absorbers, and dyes, eliminating differential pressure while maintaining process facilitation

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution significantly reduces or eliminates differential pressure, ensuring uniform dyeing and improving light and rub fastness on synthetic fibers, particularly polyester, with stable dispersions maintaining effectiveness up to 130°C.

Implementation Method 1

the differential pressure can be substantially reduced or even eliminated when a specific mixture of at least two different dispersants is combined with UV absorbers

Methodology Applied
Scientific EffectDifferential pressure reduction: Pressure Drop

Implementation Method 2

preparations, containing benzotriazoles, substituted benzotriazoles, benzotriazines, or benzophenones as the active agents, are used to protect textiles from the damaging effects of ultraviolet light

Methodology Applied
Scientific EffectUV absorption: Absorption (EM radiation)

Data Source

PatentUS8491671B2Mixture of dispersing agents
Publication Date: 2013.07.23 HUNTSMAN INTERNATIONAL LLC
  • US8491671B2 patent drawing
  • US8491671B2 patent drawing
  • US8491671B2 patent drawing

AI summary

The present invention relates to a mixture of at least two different dispersing agents, an aqueous dispersion containing a UV absorber selected from benzotriazoles, benzotriazines and benzophenones and a mixture of at least two different dispersing agents and a method for reducing the differential pressure in the static dyeing process.