Dual-Function Surfactant for Wellbore Foaming and Corrosion Inhibition

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Solution Overview

Problem

The production of formation fluids such as oil and gas from subterranean formations is hindered by the hydrostatic pressure of produced fluids in the wellbore, which decreases the pressure differential between the formation and the surface, leading to reduced or ceased production. Existing foaming agents, such as fluorosurfactants, are costly, environmentally unfriendly, and corrosive to downhole equipment.

Innovation Solution

A foaming agent with both foaming and corrosion inhibition properties is introduced into the wellbore, comprising nonionic surfactant structures that can be protonated to provide cationic surfactant properties, reducing hydrostatic pressure and protecting downhole equipment from corrosion.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Stability of the object's composition

If fluorosurfactants are used as foaming agents, then foam formation is improved, but corrosion to downhole equipment increases and environmental friendliness deteriorates

Engineering Contradiction:
Improvefoam stabilityVSAvoidcorrosion to downhole equipment
Core Design Contradiction:
Stability of the object's compositionVSObject-affected harmful factors

Solution Approach 1:

The patent replaces expensive, corrosive fluorosurfactants with a biodegradable, non-corrosive surfactant composition derived from natural oils. The surfactant is designed to be environmentally friendly and non-toxic while maintaining effective foaming performance, eliminating the need for special handling and disposal procedures required by fluorosurfactants

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

Solution Approach 2:

The patent modifies the chemical structure of traditional surfactants by using esterification reactions between fatty acids from natural oils and polyols, creating a new class of biodegradable surfactants with appropriate HLB values (8-16) for effective foaming in hydrocarbon-based formation fluids without the corrosive properties of fluorinated compounds

Inventive Principle:
Principle #35Parameter changes

2Stability of the object's composition

If fluorosurfactants are used as foaming agents, then foam formation is improved, but environmental friendliness deteriorates

Engineering Contradiction:
Improvefoam stabilityVSAvoidenvironmental friendliness
Core Design Contradiction:
Stability of the object's compositionVSReliability

Solution Approach 1:

The patent replaces expensive, corrosive fluorosurfactants with a biodegradable, non-corrosive surfactant composition derived from natural oils. The surfactant is designed to be environmentally friendly and non-toxic while maintaining effective foaming performance, eliminating the need for special handling and disposal procedures required by fluorosurfactants

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

Solution Approach 2:

The patent creates an environmentally benign chemical environment by using naturally derived, biodegradable surfactants that break down into harmless substances. The formulation avoids persistent organic pollutants and toxic fluorinated compounds, ensuring the treatment does not harm underground aquifers or surface ecosystems

Inventive Principle:
Principle #39Inert atmosphere (Inert environment)

3Productivity

If the density of the column of formation fluid is reduced by foaming, then production efficiency is improved, but foam stability becomes difficult to achieve

Engineering Contradiction:
Improveproduction efficiencyVSAvoidfoam stability
Core Design Contradiction:
ProductivityVSStability of the object's composition

Solution Approach 1:

The patent modifies the chemical structure of traditional surfactants by using esterification reactions between fatty acids from natural oils and polyols, creating a new class of biodegradable surfactants with appropriate HLB values (8-16) for effective foaming in hydrocarbon-based formation fluids without the corrosive properties of fluorinated compounds

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses composite surfactant systems combining multiple natural oil-derived surfactants with complementary properties. This composite approach allows optimization of both foam stability and gas loading capacity, creating a synergistic effect that improves foam quality and durability while maintaining environmental compatibility

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The foaming agent effectively reduces hydrostatic pressure, enhancing fluid production by forming a stable foam and providing corrosion resistance to downhole equipment, thus extending its lifespan and maintaining production efficiency.

Implementation Method 1

Some efforts have been made to reduce the density of the column of formation fluid such as by foaming

Methodology Applied
Scientific EffectFoaming: Foam

Implementation Method 2

The foaming agent may provide surfactant properties thereby allowing hydrocarbons and/or hydrocarbons and water present the wellbore to be foamed

Methodology Applied
Scientific EffectSurfactant properties: Surfactant

Implementation Method 3

the foaming agent may provide some degree of corrosion resistance to tubulars and other downhole equipment

Methodology Applied
Scientific EffectCorrosion inhibition:

Data Source

PatentUS10800964B2Dual functioning corrosion inhibitor and foaming agent
Publication Date: 2020.10.13 HALLIBURTON ENERGY SERVICES INC
  • US10800964B2 patent drawing
  • US10800964B2 patent drawing
  • US10800964B2 patent drawing

AI summary

A method may include: placing into a wellbore penetrating a subterranean formation a foaming agent, wherein the wellbore comprises a produced fluid from the subterranean formation; and foaming the produced fluid. The foaming agent may include at least one of the following structures:wherein R1 and R2 are individually selected from an alkyl group, an alkenyl group, a heteroatom substituted alkyl group, or a heteroatom substituted alkenyl group, wherein R1 comprises 5 carbon atoms to 22 carbon atoms in length, and wherein R2 comprises 1 carbon atom to 8 carbon atoms.