Dual Hole Transport Layer Structure for OLED Charge Balance

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Solution Overview

Problem

Current organic light-emitting devices (OLEDs) face challenges in achieving optimal hole transport and charge balance, leading to inefficiencies in light emission and reduced device lifetime due to the lack of a dual hole transport layer structure that effectively manages hole migration and exciton protection.

Innovation Solution

The implementation of a dual hole transport layer structure in OLEDs, where the first hole transport layer includes specific compounds represented by Formula 1 and the second hole transport layer includes compounds represented by Formula 2, facilitating controlled hole transport and exciton protection by optimizing the thickness and composition of these layers.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Device complexity

If a single hole transport layer is used in OLEDs, then the device structure is simple, but hole transport efficiency and charge balance are insufficient

Engineering Contradiction:
Improvehole transport layer structureVSAvoidhole transport efficiency
Core Design Contradiction:
Device complexityVSProductivity

Solution Approach 1:

The hole transport layer is divided into two distinct layers: a first hole transport layer adjacent to the anode and a second hole transport layer adjacent to the emission layer. Each layer uses different compounds with optimized properties for its specific function, enabling efficient hole transport while maintaining structural organization and charge balance.

Inventive Principle:
Principle #1Segmentation

2Reliability

If hole transport is enhanced, then charge balance improves, but exciton destruction may increase without proper protection

Engineering Contradiction:
Improvecharge balanceVSAvoidexciton destruction
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The second hole transport layer acts as an intermediary between the first hole transport layer and the emission layer. It facilitates controlled hole transport to maintain charge balance while protecting excitons from destruction by regulating the interaction between holes and the emission layer.

Inventive Principle:
Principle #24Intermediary (Mediator)

3Ease of manufacture

If conventional hole transport layers are used, then manufacturing is straightforward, but device lifetime is reduced due to poor charge balance

Engineering Contradiction:
Improvehole transport layer fabricationVSAvoiddevice lifetime
Core Design Contradiction:
Ease of manufactureVSDuration of action of stationary object

Solution Approach 1:

The hole transport system uses composite material architecture with two distinct compounds: a first compound in the first hole transport layer and a second compound in the second hole transport layer. This composite structure optimizes both manufacturability through standard deposition processes and device lifetime through improved charge balance and exciton protection.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This configuration enhances the efficiency and lifetime of OLEDs by improving charge balance, reducing exciton destruction, and maintaining high luminance with lower driving voltage, resulting in a more effective and durable organic light-emitting device.

Implementation Method 1

a first hole transport layer between the first electrode and the emission layer; and a second hole transport layer between the first hole transport layer and the emission layer

Methodology Applied
Scientific EffectHole transport:

Implementation Method 2

The holes and electrons recombine in the EML to generate excitons. When the excitons drop from an excited state to a ground state, light is emitted.

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Data Source

PatentUS9070893B2Organic light-emitting device
Publication Date: 2015.06.30 SAMSUNG DISPLAY CO LTD
  • US9070893B2 patent drawing
  • US9070893B2 patent drawing
  • US9070893B2 patent drawing

AI summary

An organic light-emitting device including a first electrode; a second electrode facing the first electrode; an emission layer between the first electrode and the second electrode; a first hole transport layer between the first electrode and the emission layer; and a second hole transport layer between the first hole transport layer and the emission layer, wherein the first hole transport layer includes a first compound represented by Formula 1 and the second hole transport layer includes a second compound represented by Formula 2: