Dual Host Organic Light Emitting Device for Efficiency

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Solution Overview

Problem

There is a need for improved materials in organic light emitting devices to enhance efficiency, driving voltage, and lifetime characteristics.

Innovation Solution

The use of a specific organic light emitting device structure incorporating a light emitting layer with two host compounds, represented by Chemical Formulas 1 and 2, which include specific aryl and heteroaryl groups, to optimize hole and electron transport capabilities.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If a single host compound is used in the light emitting layer, then the device structure is simple, but the efficiency and lifetime characteristics are insufficient

Engineering Contradiction:
ImproveefficiencyVSAvoidlight emitting layer composition
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The patent employs a composite host system comprising two distinct compounds: a first host compound (Formula 1) with electron-transport characteristics and a second host compound (Formula 2) with hole-transport characteristics. This composite approach allows simultaneous optimization of electron and hole transport pathways, achieving improved device efficiency and lifetime without excessive structural complexity.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The invention assigns different functional characteristics to different regions of the light emitting layer by incorporating host compounds with specific transport properties. The first host compound predominantly facilitates electron transport, while the second host compound predominantly facilitates hole transport, creating localized functional zones that work synergistically to enhance overall device performance.

Inventive Principle:
Principle #3Local quality

2Reliability

If conventional host materials are used, then the manufacturing process is simple, but the driving voltage and lifetime characteristics are poor

Engineering Contradiction:
Improvelifetime characteristicsVSAvoidmaterial synthesis complexity
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent systematically modifies molecular parameters of the host compounds, including substituting hydrogen atoms with deuterium atoms and varying the aryl/heteroaryl group configurations. These parameter changes optimize the HOMO-LUMO energy levels and charge transport properties, resulting in improved lifetime characteristics while maintaining manufacturability through established organic synthesis methodologies.

Inventive Principle:
Principle #35Parameter changes

3Productivity

If the light emitting layer uses standard organic materials, then the device is easy to manufacture, but the efficiency and driving voltage performance are insufficient

Engineering Contradiction:
ImproveefficiencyVSAvoidchemical structure complexity
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The dual host compound system acts as intermediary carriers that facilitate efficient charge transport between the electrodes and the emissive dopant. The first host compound mediates electron injection and transport, while the second host compound mediates hole injection and transport, enabling efficient exciton formation and light emission through optimized charge carrier dynamics.

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This configuration improves the light emitting device's efficiency, driving voltage, and lifetime by maintaining a proper ratio of holes to electrons in the light emitting layer, leading to enhanced performance.

Implementation Method 1

The organic light emitting device uses the organic light emitting phenomenon where electric energy is converted into light energy by using an organic material. When voltage is applied between electrodes, holes are injected from anode into the organic material layer and electrons are injected from cathode into the organic material layer, and when the injected holes and electrons meet each other, an exciton is formed, and light is emitted when the exciton falls to a ground state again.

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Data Source

PatentUS20240341175A1Organic light emitting device
Publication Date: 2024.10.10 LG CHEM LTD
  • US20240341175A1 patent drawing
  • US20240341175A1 patent drawing
  • US20240341175A1 patent drawing

AI summary

An organic light emitting device comprising an anode; a cathode; and a light emitting layer between the anode and the cathode, the light emitting layer comprising a first compound of Chemical Formula 1 and a second compound of Chemical Formula 2:wherein: Ar1 and Ar2 are each independently a substituted or unsubstituted C6-60 aryl; R is deuterium or a substituted or unsubstituted C6-60 aryl or C2-60 heteroaryl containing at least one of N, O and S, provided that carbazolyl and benzocarbazolyl are excluded from R; X is O or S; R1 and R10 are each independently hydrogen, deuterium, or a substituent of Chemical Formula 3, provided that one of R1 to R10 is a substituent of Chemical Formula 3:and the other substituents are as defined in the specification, the device exhibiting improved driving voltage, luminous efficiency and lifetime.