Dual-Laser Nanoparticle Printing for Durable Hybrid Structures

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Solution Overview

Problem

Current additive manufacturing technologies face challenges in printing hybrid structures and devices with complex functionalities, such as piezoelectric and optoelectronic devices, due to imperfections like lack of fusions, gas pores, and weak bonding between material systems, which lead to fatigue failures under cyclic loading.

Innovation Solution

An additive nanomanufacturing method involving in-situ generation and real-time sintering of multifunctional nanoparticles in the gas phase at atmospheric pressure, using two laser beams for ablation and sintering, allowing for the formation of durable hybrid structures with complex functionalities, including ferroelectric and ferromagnetic materials, and enabling precise deposition and sintering.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Device complexity

If conventional additive manufacturing is used to print hybrid structures, then manufacturing complexity is reduced, but structural integrity deteriorates due to lack of fusion, gas pores, and weak bonding

Engineering Contradiction:
Improvemanufacturing complexityVSAvoidstructural integrity
Core Design Contradiction:
Device complexityVSStrength

Solution Approach 1:

The patent changes the physical state parameters of material delivery from conventional paste or powder through gas-phase nanoparticle delivery. This parameter change enables superior fusion and bonding because the nanoparticles can be sintered more effectively, eliminating gas pores and weak bonding issues while maintaining manufacturing simplicity

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses composite approach by combining laser ablation for nanoparticle generation with laser sintering for consolidation. This composite process integrates material synthesis and consolidation in one system, achieving both manufacturing simplicity and structural integrity through the synergistic combination of gas-phase delivery and laser sintering

Inventive Principle:
Principle #40Composite materials

2Ease of manufacture

If conventional additive manufacturing is used, then ease of manufacture is improved, but reliability deteriorates due to fatigue failures under cyclic loading

Engineering Contradiction:
Improveease of manufactureVSAvoidfatigue resistance
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The patent changes the material state to gas-phase nanoparticles and uses laser sintering parameters that produce dense, pore-free structures. This parameter change directly improves fatigue resistance by eliminating stress concentration sites while keeping the manufacturing process simple and accessible

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent replaces conventional mechanical consolidation methods with laser sintering. This substitution creates stronger, more reliable bonds that resist fatigue failures while maintaining ease of manufacture through the non-contact, automated laser process

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

3Strength

If gas-phase nanoparticle delivery with laser sintering is used, then structural integrity is improved, but device complexity increases due to multiple laser beams and gas flow systems

Engineering Contradiction:
Improvestructural integrityVSAvoidsystem complexity
Core Design Contradiction:
StrengthVSDevice complexity

Solution Approach 1:

The patent applies multi-functionality by using lasers for multiple purposes: ablation to generate nanoparticles, heating to control gas flow and nanoparticle delivery, and sintering to consolidate material. This universal use of laser technology achieves superior structural integrity while minimizing the number of separate system components

Inventive Principle:
Principle #6Universality (Multi-functionality)

Solution Approach 2:

The patent merges material synthesis (nanoparticle generation via ablation) and material consolidation (sintering) into a single integrated system. This merging eliminates the need for separate material preparation and printing systems, reducing overall device complexity while maintaining excellent structural integrity

Inventive Principle:
Principle #5Merging (Combining)

4Ease of operation

If conventional additive manufacturing is used, then ease of operation is improved, but manufacturing precision deteriorates due to inability to achieve nanoscale resolution

Engineering Contradiction:
Improveease of operationVSAvoidnanoscale resolution
Core Design Contradiction:
Ease of operationVSManufacturing precision

Solution Approach 1:

The patent replaces mechanical material deposition with gas-phase nanoparticle delivery and laser sintering. This substitution enables nanoscale precision because the laser can be focused to very small spots and the nanoparticles can be precisely controlled in the gas phase, while the process remains easy to operate through automated control

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The patent changes the material delivery parameter from viscous paste or powder to gas-phase nanoparticles. This parameter change enables nanoscale resolution through precise gas flow control and laser focusing, while maintaining ease of operation through automated process control

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Enables the creation of durable hybrid structures with enhanced structural integrity and functionality, overcoming limitations of existing technologies by providing nanoscale precision and digital delivery of ligand-free nanoparticle building blocks, facilitating the production of next-generation devices in energy storage, conversion, and optoelectronics.

Implementation Method 1

a first laser configured to generate a first beam directed toward the target carousel to perform in-situ ablation to form a laser plume

Methodology Applied
Scientific EffectLaser ablation: Laser Ablation

Implementation Method 2

a gas flow system configured to supply gas into the chamber, such that the gas interacts with the laser plume and causes condensation and formation of nanoparticles

Methodology Applied
Scientific EffectCondensation: Condensation

Implementation Method 3

a second laser configured to generate a second beam directed through the interior of the chamber, through the aperture of the nozzle, and toward a substrate disposed outside the device, the second laser beam configured to sinter and crystalize on the substrate the nanoparticles exiting the nozzle

Methodology Applied
Scientific EffectSintering: Sintering

Implementation Method 4

a second laser configured to generate a second beam directed through the interior of the chamber, through the aperture of the nozzle, and toward a substrate disposed outside the device, the second laser beam configured to sinter and crystalize on the substrate the nanoparticles exiting the nozzle

Methodology Applied
Scientific EffectCrystallization: Crystallisation

Data Source

PatentUS20240247361A1Novel additive nanomanufacturing system and method
Publication Date: 2024.07.25 AUBURN UNIVERSITY
  • US20240247361A1 patent drawing
  • US20240247361A1 patent drawing
  • US20240247361A1 patent drawing

AI summary

A device including a chamber and a nozzle detachably connected to the chamber, the nozzle defining an aperture, a target carousel disposed within the chamber, a first laser configured to generate a first beam directed toward the target carousel to perform in-situ ablation to form a laser plume, a gas flow system configured to supply gas into the chamber, such that the gas interacts with the laser plume and causes condensation and formation of nanoparticles, and a second laser configured to generate a second beam directed through the interior of the chamber, through the aperture of the nozzle, and toward a substrate disposed outside the device, the second laser beam configured to sinter and crystalize on the substrate the nanoparticles exiting the nozzle.