Dual Spacer Plasma Densification for Semiconductor Etching

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Solution Overview

Problem

In semiconductor processes, the use of a single-layer spacer can lead to damage to the substrate and lightly-doped source/drain regions due to over-etching and material similarity, affecting the electrical performance of MOS transistors.

Innovation Solution

A semiconductor process involving a plasma process without oxygen is performed on a dual spacer to densify the oxide layer, preventing consumption during subsequent etching processes and maintaining the integrity of the oxide layer.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Device complexity

If a single-layer spacer is used to form recesses, then the process is simple, but the oxide layer is consumed during etching processes

Engineering Contradiction:
Improvespacer structureVSAvoidoxide layer consumption
Core Design Contradiction:
Device complexityVSLoss of substance

Solution Approach 1:

The spacer structure is divided into two distinct layers: a first spacer layer (e.g., silicon nitride) and a second spacer layer (oxide layer). This segmentation allows the etching process to selectively remove the first spacer layer while the densified second spacer layer remains intact, preventing oxide layer consumption while maintaining processability.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The dual spacer structure combines materials with different etching properties - a silicon nitride first spacer layer that is easily removed by phosphoric acid, and an oxide second spacer layer that is densified to resist etching. This composite structure resolves the contradiction between ease of removal and resistance to consumption.

Inventive Principle:
Principle #40Composite materials

2Ease of operation

If a single-layer spacer is removed after epitaxial layer formation, then the recess is accessible, but the substrate and lightly-doped source/drain regions are damaged due to over-etching

Engineering Contradiction:
Improverecess accessibilityVSAvoidsubstrate damage
Core Design Contradiction:
Ease of operationVSObject-affected harmful factors

Solution Approach 1:

The first spacer layer acts as an intermediary sacrificial layer that protects the substrate and lightly-doped source/drain regions during the etching process. It can be completely removed after serving its protective function, while the densified second spacer layer remains to prevent over-etching damage.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The dual spacer structure provides beforehand cushioning by having the densified oxide layer in place before the etching process begins. This layer acts as a protective barrier that prevents over-etching from reaching and damaging the substrate and lightly-doped regions.

Inventive Principle:
Principle #11Beforehand cushioning (Prior cushioning)

3Ease of manufacture

If the oxide layer is not densified, then the plasma process is simple, but the oxide layer is consumed during wet etching processes

Engineering Contradiction:
Improveprocess simplicityVSAvoidoxide layer integrity
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The oxide layer is densified through a plasma process before the wet etching step. This preliminary action enhances the oxide layer's resistance to etching, ensuring it remains intact during subsequent processing steps while adding minimal complexity to the overall manufacturing process.

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The plasma process without oxygen strengthens the oxide layer, preventing its consumption during etching and protecting the first spacer and lightly-doped source/drain regions, thereby enhancing the electrical performance of MOS transistors.

Implementation Method 1

A plasma process without oxygen is performed to densify the oxide layer

Methodology Applied
Scientific EffectPlasma process: Plasma

Data Source

PatentUS8697508B2Semiconductor process
Publication Date: 2014.04.15 UNITED MICROELECTRONICS CORP
  • US8697508B2 patent drawing
  • US8697508B2 patent drawing
  • US8697508B2 patent drawing

AI summary

A semiconductor process includes the following steps. A gate structure is formed on a substrate. An oxide layer is formed and covers the gate structure and the substrate. A plasma process without oxygen is performed to densify the oxide layer. A material layer is formed and covers the oxide layer. The material layer and the oxide layer are etched to form a dual spacer.