Dual-Stage Hydrocracking for Lube Base Stocks

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Current refining processes face challenges in producing high-quality lubricating oil base stocks and distillate fuels simultaneously, as they are typically optimized for one type of product, leading to limited yields and degradation of lubricant basestocks due to high recycle ratios and different processing severities required for fuels and lubricants.

Innovation Solution

A process involving two consecutive hydroprocessing steps with separate or combined reactors, where the first step targets heavy oil specifications and the second step targets light oil specifications, allowing for continuous production of high-quality lubricating oil base stocks with middle distillate fuels as by-products, using a divided wall fractionator for product separation and common finishing units for hydrodewaxing and hydrofinishing.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Quantity of substance

If a single hydrocracking system is optimized for fuel production with high recycle ratios, then fuel yield is improved, but lube basestock quality deteriorates and lube fraction yield is limited

Engineering Contradiction:
Improvefuel yieldVSAvoidlube basestock quality
Core Design Contradiction:
Quantity of substanceVSManufacturing precision

Solution Approach 1:

The single hydrocracking system is segmented into two separate hydrocracking units: a first hydrocracking unit optimized for lube basestock production with low recycle ratios, and a second hydrocracking unit optimized for fuel production with high recycle ratios. This segmentation allows each unit to operate under optimal conditions for its specific product, resolving the contradiction between fuel yield and lube quality.

Inventive Principle:
Principle #1Segmentation

2Productivity

If high conversion is applied in hydrocracking to increase fuel production, then fuel yield is improved, but lube basestock performance deteriorates due to excessive conversion and degradation

Engineering Contradiction:
Improvefuel production rateVSAvoidlube basestock performance
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The hydrocracking process is segmented into two independent units with different conversion levels. The first unit operates at low conversion specifically for lube basestock to preserve performance indicia, while the second unit operates at high conversion for fuel production. This eliminates the degradation issue caused by high conversion in a single-unit system.

Inventive Principle:
Principle #1Segmentation

3Quantity of substance

If blocked operation mode is used to produce different lube grades, then optimal yield for each grade is achieved, but transition times and feed segregation requirements increase process complexity

Engineering Contradiction:
Improvelube grade yieldVSAvoidprocess operation complexity
Core Design Contradiction:
Quantity of substanceVSDevice complexity

Solution Approach 1:

Instead of using blocked operation with sequential production, the process segments feed streams into two parallel hydrocracking units that simultaneously produce different lube grades. The first unit produces heavy oil lube basestock while the second unit produces light oil lube basestock, eliminating transition times and feed segregation requirements.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The dual-unit configuration enables continuous simultaneous production of multiple lube grades without interruption. Both units operate continuously in parallel, maintaining steady-state operation and eliminating the transition periods inherent in blocked operation modes.

Inventive Principle:
Principle #20Continuity of useful action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This configuration enables the production of high yields of API Group II and Group III lubricating oil base stocks with similar or higher yields than blocked operation modes, eliminating the need for transition times and feed segregation, while maintaining optimal product qualities and reducing capital costs.

Implementation Method 1

The present disclosure relates to a process for converting heavy hydrocarbon oils into high quality lubes with the concomitant production of distillate fuels by hydrocracking

Methodology Applied
Scientific EffectHydrocracking: Chemical Bonding

Implementation Method 2

using a divided wall fractionator for product separation

Methodology Applied
Scientific EffectFractionation: Distillation

Implementation Method 3

common finishing units for hydrodewaxing and hydrofinishing

Methodology Applied
Scientific EffectHydrodewaxing: Chemical Bonding

Implementation Method 4

common finishing units for hydrodewaxing and hydrofinishing

Methodology Applied
Scientific EffectHydrofinishing: Chemical Bonding

Data Source

PatentEP3561024B1Hydrocracking process for high yields of high quality lube products
Publication Date: 2022.10.12 EXXONMOBIL TECHNOLOGY & ENGINEERING CO
  • EP3561024B1 patent drawingFigure 1
  • EP3561024B1 patent drawingFigure 2
  • EP3561024B1 patent drawingFigure 3

AI summary

A process for producing high yields of higher quality (API Group II, Group III') lubricating oil basestock fractions which allows the production of two or more types of high quality lubes in continuous mode (no blocked operation mode) without transition times and feed or intermediate product tankage segregation. Two consecutive hydroprocessing steps are used: the first step processes a wide cut feed at a severity needed to match heavy oil lube properties. The second step hydroprocesses a light oil after fractionation of the liquid product from the first step at a severity higher than for the heavy oil fraction. The two hydroprocessing steps will normally be carried out in separate reactors but they may be combined in a single reactor which allows for the two fractions to be processed with different degrees of severity.