Dusting Material Interface for MRAM Reference Layer Stability

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Solution Overview

Problem

Conventional MRAM devices, particularly spin transfer torque MRAM (STT-MRAM), face challenges in forming stable reference layers due to interface energies between non-magnetic and magnetic layers, leading to non-continuous growth and significant roughness, which affects the reliability of perpendicular magnetic tunnel junction stacks.

Innovation Solution

Incorporating a dusting material, such as platinum (Pt), ruthenium (Ru), palladium (Pd), gold (Au), or nickel (Ni), between or into the non-magnetic layer to alter interface energies, enabling a two-dimensional growth mode and forming continuous, homogeneous magnetic layers, thereby improving the stability and reliability of the reference layer.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If a non-magnetic layer is formed directly over a magnetic layer without dusting material, then the structure is simpler and manufacturing is easier, but the interface roughness increases and growth continuity deteriorates

Engineering Contradiction:
Improveinterface smoothnessVSAvoidlayer structure
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

A dusting material layer (containing Pt, Ru, Pd, Au, or Ni) is introduced as an intermediary between the non-magnetic layer and the magnetic layer. This intermediate layer modifies the interface energy and growth characteristics, enabling continuous layer-by-layer growth and reducing interface roughness without compromising the overall device structure.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The non-magnetic layer is transformed into a composite structure by incorporating dusting materials either as a separate interfacial layer or by alloying them into the non-magnetic layer matrix. This composite approach maintains the non-magnetic properties while improving the growth characteristics and interface quality.

Inventive Principle:
Principle #40Composite materials

2Stability of the object's composition

If dusting material is incorporated into the non-magnetic layer to form an alloy, then growth continuity improves, but the material composition becomes more complex

Engineering Contradiction:
Improvelayer continuityVSAvoidmaterial composition complexity
Core Design Contradiction:
Stability of the object's compositionVSQuantity of substance

Solution Approach 1:

The dusting material is concentrated at the critical interface region between the non-magnetic and magnetic layers, rather than being uniformly distributed throughout the entire non-magnetic layer. This localized approach improves growth continuity at the interface while minimizing the overall material complexity and maintaining the bulk properties of the non-magnetic layer.

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The use of dusting materials allows for layer-by-layer growth, reducing roughness and enhancing the reliability of the reference layer, especially in small MRAM devices, leading to more stable and reliable perpendicular magnetic tunnel junction stacks.

Implementation Method 1

Incorporating a dusting material, such as platinum (Pt), ruthenium (Ru), palladium (Pd), gold (Au), or nickel (Ni), between or into the non-magnetic layer to alter interface energies

Methodology Applied
Scientific EffectSurface energy modification: Surface Tension

Implementation Method 2

The dusting material may be formed as a dusting layer disposed between the non-magnetic layer and the magnetic layer, or may be incorporated into the non-magnetic layer

Methodology Applied
Scientific EffectSputtering deposition: Sputtering

Data Source

PatentUS10340446B1Semiconductor structure multilayers having a dusting material at an interface between a non-magnetic layer and a magnetic layer
Publication Date: 2019.07.02 INTERNATIONAL BUSINESS MACHINE CORPORATION
  • US10340446B1 patent drawing
  • US10340446B1 patent drawing
  • US10340446B1 patent drawing

AI summary

A semiconductor structure includes a seed layer and a multilayer stack of one or more multilayers disposed over the seed layer, each of the one or more multilayers including a magnetic layer and an additional layer disposed over a top surface of the magnetic layer. The additional layer includes a non-magnetic material and a dusting material. The multilayer stack provides a reference layer of a perpendicular magnetic tunnel junction stack. The magnetic layer may be formed of cobalt, the non-magnetic material may be at least one of iridium and rhodium, and the dusting material may be at least one of platinum, ruthenium, palladium, gold and nickel.