Dye-Type Polarizer Composition Crosslinking Heat Resistance

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Solution Overview

Problem

Existing dye-type polarizers exhibit poor heat resistance, leading to randomization of dichroic dye orientation and reduced polarization performance when exposed to high temperatures, limiting their application in advanced display devices.

Innovation Solution

A composition for forming a dye-type polarizer incorporating a curable anisotropic dye and an orientation auxiliary agent, which forms a crosslinking structure upon curing, stabilizing the orientation of the dye layer and enhancing heat resistance and polarization properties.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Measurement precision

If a dye-type polarizer uses a thin film structure with oriented dichroic dye, then the degree of polarization is improved, but heat resistance deteriorates due to randomization of dye orientation at high temperatures

Engineering Contradiction:
Improvedegree of polarizationVSAvoidheat resistance
Core Design Contradiction:
Measurement precisionVSReliability

Solution Approach 1:

The patent creates a composite material system consisting of dichroic dye molecules embedded in a polymer matrix. The polymer component provides thermal stability and structural support, while the dichroic dye provides polarization function. This composite structure prevents dye molecule randomization at high temperatures, maintaining both degree of polarization and heat resistance simultaneously.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent modifies the physical and chemical parameters of the dye layer by controlling the polymer's glass transition temperature, crosslinking density, and dye concentration. These parameter changes enhance the thermal stability of the dye orientation while maintaining optical performance, resolving the contradiction between polarization quality and heat resistance.

Inventive Principle:
Principle #35Parameter changes

2Ease of manufacture

If a stretched PVA film polarizer is used, then ease of manufacture is improved, but heat resistance and moisture resistance deteriorate

Engineering Contradiction:
Improvemanufacturing simplicityVSAvoidheat resistance and moisture resistance
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The patent employs a thin film structure that combines the manufacturing advantages of film-based polarizers with enhanced protective properties. The film format allows for simple deposition processes while the controlled composition and crosslinking provide improved heat and moisture resistance, eliminating the need for additional protection films.

Inventive Principle:
Principle #30Flexible shells and thin films

Solution Approach 2:

The patent changes the chemical composition parameters of the polarizer by incorporating crosslinkable functional groups and selecting polymers with appropriate glass transition temperatures. These parameter changes enable the polarizer to withstand heat and moisture without degrading, while maintaining the ease of film-based manufacturing processes.

Inventive Principle:
Principle #35Parameter changes

3Reliability

If the polarizer thickness is increased to 70-150 μm with protection films, then heat resistance and moisture resistance are improved, but device complexity and overall thickness increase

Engineering Contradiction:
Improveheat resistance and moisture resistanceVSAvoidpolarizer structure complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent creates a multi-functional polarizer material that simultaneously provides polarization function, heat resistance, moisture resistance, and mechanical strength in a single thin film layer. This eliminates the need for multiple separate components (protection films, adhesive films), reducing device complexity while maintaining reliability.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Solution Approach 2:

The patent develops a composite material system where the polymer matrix and dichroic dye work together to provide multiple functions: the polymer provides thermal and moisture stability, while the dye provides polarization. This integrated composite structure replaces multiple separate films, simplifying the overall device architecture.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composition maintains high orientation and degree of polarization even at high temperatures, providing a dye-type polarizer with improved heat resistance and dichroic ratio, suitable for applications beyond traditional liquid crystal display devices.

Implementation Method 1

incorporating a curable anisotropic dye and an orientation auxiliary agent, which forms a crosslinking structure upon curing

Methodology Applied
Scientific EffectCrosslinking: Chemical Bonding

Implementation Method 2

curable anisotropic dye of Chemical Formula 1; and an orientation auxiliary agent of Chemical Formula 2 or 3 or a radical polymer thereof

Methodology Applied
Scientific EffectPhotopolymerization: Photopolymerisation

Implementation Method 3

a dye-type polarizer showing excellent degree of polarization, heat resistance, and dichroic ratio

Methodology Applied
Scientific EffectDichroism: Dichroic Filter

Data Source

PatentUS10527758B2Composition for forming dye type polarizer and dye type polarizer
Publication Date: 2020.01.07 LG CHEM LTD
  • US10527758B2 patent drawing
  • US10527758B2 patent drawing
  • US10527758B2 patent drawing

AI summary

The present invention relates to a composition for forming a dye-type polarizer, which can be used to provide a dye-type polarizer showing excellent degree of polarization, heat resistance and dichroic ratio, and to a dye-type polarizer. The composition for forming a dye-type polarizer includes a curable anisotropic dye having a particular chemical structure; and an orientation auxiliary agent having a predetermined chemical structure.