Dyed Glass-Ceramic Cooktop Composition for LED Display and IR Transmission

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Solution Overview

Problem

Existing glass-ceramic cooktops with high-quartz mixed crystals struggle to achieve optimal light transmission and infrared transmission while maintaining effective display capabilities for various colored LEDs, particularly red, blue, and green LEDs, and ensuring safety and aesthetic appearance.

Innovation Solution

A glass-ceramic cooktop with a composition that includes V2O5 as the primary color oxide, combined with specific redox adjustments and refining agents like SnO2 and CeO2, to achieve light transmission values of 0.8 to 2.5% in the visible range and 45-85% in the infrared range, while minimizing the use of arsenic and antimony oxides for environmental safety.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Illumination intensity

If V2O5 is used as the primary color oxide to achieve black aesthetic appearance and control visible light transmission, then the aesthetic appearance and visible light transmission are improved, but the infrared transmission and display capability for colored LEDs deteriorate

Engineering Contradiction:
Improvevisible light transmissionVSAvoiddisplay capability for colored LEDs
Core Design Contradiction:
Illumination intensityVSAdaptability or versatility

Solution Approach 1:

The patent applies parameter changes by precisely controlling the concentration of V2O5 (0.01-0.06 wt%) and introducing Fe2O3 (0.05-0.2 wt%) to modify the optical transmission characteristics. By adjusting these chemical parameters and their ratios, the glass-ceramic achieves optimal balance between visible light absorption for aesthetic appearance and infrared transmission for cooking performance, while improving display capability for colored LEDs.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses composite materials by combining V2O5 with Fe2O3 and other metal oxides (TiO2, ZrO2, SnO2) in specific proportions. This composite approach creates a synergistic effect where V2O5 provides the primary black coloration and infrared transmission, while Fe2O3 enhances the display capability for colored LEDs and refines the overall optical properties, resolving the contradiction between aesthetic appearance and display versatility.

Inventive Principle:
Principle #40Composite materials

2Object-affected harmful factors

If SnO2 and CeO2 are used as refining agents to achieve good blister qualities and eliminate toxic compounds, then safety and environmental protection are improved, but the melting temperature and refining complexity increase

Engineering Contradiction:
Improvetoxic compound eliminationVSAvoidmelting temperature
Core Design Contradiction:
Object-affected harmful factorsVSTemperature

Solution Approach 1:

The patent uses CeO2 as an intermediary refining agent that facilitates the removal of toxic compounds (arsenic and antimony oxides) from the glass-ceramic melt. CeO2 acts as a mediator in the refining process, enabling effective blister quality improvement and toxic substance elimination while operating at controlled temperatures, thus resolving the contradiction between safety and processing temperature.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent replaces toxic refining agents (arsenic and antimony oxides) with safer alternatives (SnO2 and CeO2). This substitution strategy copies the refining function of the original toxic agents while eliminating their harmful effects, achieving the same blister quality improvement without the associated toxicity and environmental concerns.

Inventive Principle:
Principle #26Copying

3Adaptability or versatility

If light transmission is increased to enhance display capability for blue and green LEDs, then the display capability is improved, but the black aesthetic appearance and coverage of electronic components deteriorate

Engineering Contradiction:
Improvedisplay capabilityVSAvoidblack aesthetic appearance
Core Design Contradiction:
Adaptability or versatilityVSIllumination intensity

Solution Approach 1:

The patent applies local quality by creating wavelength-selective transmission characteristics. The glass-ceramic composition is designed to selectively transmit specific wavelengths (improving display capability for colored LEDs) while maintaining overall absorption in the visible range to preserve the black aesthetic appearance. This localized optimization of transmission properties at different wavelengths resolves the contradiction between display capability and aesthetic appearance.

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution provides improved visibility of radiant heating elements, enhanced display capabilities for different colored LEDs, and increased infrared transmission for faster cooking, while maintaining a black aesthetic appearance and ensuring safety by preventing UV light transmission, thus addressing the limitations of previous technologies.

Implementation Method 1

V2O5 is mostly used for the coloring as it has the special property of light absorbing within the visible range and allows a high transmission within the infrared radiation

Methodology Applied
Scientific EffectLight absorption: Absorption (EM radiation)

Implementation Method 2

The crystallization is started by a glass consisting of a mixture of broken pieces of glass and a powdered mixture of raw materials which is usually melted at temperatures between 1500 and 1650° C. During the melting process usually arsenic and/or antimony oxide are used as refining agents

Methodology Applied
Scientific EffectRefining: Redox Reactions

Implementation Method 3

allows a high transmission within the infrared radiation... transmission in the infrared at 1600 nm of 45-85%

Methodology Applied
Scientific EffectInfrared transmission: Infrared Radiation

Data Source

PatentUS9061937B2Transparent, dyed cooktop having improved color display capability, and method for producing such a cooktop
Publication Date: 2015.06.23 SCHOTT AG
  • US9061937B2 patent drawing
  • US9061937B2 patent drawing

AI summary

Transparent, dyed cook top or hob with improved color display capability, consisting of a glass ceramic with high quartz mixed crystals as predominant crystal phase, whereby the glass-ceramic contains none of the chemical refining agents arsenic oxide and/or antimony, with transmission values of greater than 0.1% in the range of the visible light within the entire wavelength range greater than 450 nm, a light transmission in the visible of 0.8-2.5% and a transmission in the infrared at 1600 nm of 45-85%.