Easy-to-Clean Glass Coating with Alkali Diffusion Barrier

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Solution Overview

Problem

Glass substrates subjected to heat treatment experience deterioration and variation in easy-to-clean properties due to alkali metal element diffusion from the substrate into the coating, leading to non-uniform coefficient of kinetic friction.

Innovation Solution

A glass article with a glass substrate that suppresses alkali metal element diffusion into the coating, featuring an inorganic substance-based easy-to-clean coating, which can include alkali-free or low-alkali glass, a dealkalized layer, or an underlayer, and is formed through a process that maintains the coating's integrity during heat treatments.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If heat treatment is applied to the glass substrate, then the glass substrate can be processed or strengthened, but the easy-to-clean properties of the coating deteriorate due to alkali metal element diffusion

Engineering Contradiction:
Improveglass substrate strengthVSAvoideasy-to-clean properties
Core Design Contradiction:
StrengthVSReliability

Solution Approach 1:

An underlayer is introduced between the glass substrate and the easy-to-clean coating to act as a barrier that prevents alkali metal elements from diffusing from the glass substrate into the coating during heat treatment, thereby protecting the coating's easy-to-clean properties while allowing the glass substrate to undergo necessary heat processing

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent employs a composite structure consisting of the glass substrate, an intermediate underlayer, and the easy-to-clean coating. This multi-layer composite design allows each layer to fulfill its specific function: the glass substrate provides structural support, the underlayer prevents alkali diffusion, and the coating provides easy-to-clean properties

Inventive Principle:
Principle #40Composite materials

2Productivity

If heat treatment is applied to the glass substrate, then processing can be completed, but variation in easy-to-clean properties occurs depending on the region of the glass substrate

Engineering Contradiction:
Improveprocessing efficiencyVSAvoiduniformity of easy-to-clean properties
Core Design Contradiction:
ProductivityVSManufacturing precision

Solution Approach 1:

The underlayer serves as a uniform barrier across the entire glass substrate surface, preventing regional variations in alkali metal element diffusion that would otherwise cause non-uniform easy-to-clean properties in different areas of the coating after heat treatment

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The underlayer creates a homogeneous protective barrier that ensures consistent prevention of alkali diffusion across all regions of the glass substrate, resulting in uniform easy-to-clean properties throughout the coating surface after heat treatment

Inventive Principle:
Principle #33Homogeneity

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution effectively suppresses deterioration and variation in easy-to-clean properties, ensuring a low coefficient of kinetic friction and improved cleaning efficacy even after heat treatment.

Implementation Method 1

the glass substrate has a function or composition that suppresses diffusion of an alkali metal element into the coating

Methodology Applied
Scientific EffectDiffusion: Diffusion

Data Source

PatentEP4678608A1Glass article with easy-to-clean coating
Publication Date: 2026.01.14 NIPPON SHEET GLASS CO LTD
  • EP4678608A1 patent drawingFigure 1
  • EP4678608A1 patent drawing
  • EP4678608A1 patent drawing

AI summary

Provided is a coating-attached glass article including: a glass substrate; and an easy-to-clean coating on the glass substrate, wherein the glass substrate has a function or composition that suppresses diffusion of an alkali metal element into the coating, and the easy-to-clean coating contains an inorganic substance as a main component. The glass article satisfies at least one selected from the group consisting of the following (i) to (iv): (i) the glass substrate is formed of alkali-free glass; (ii) the glass substrate is formed of low-alkali glass; (iii) the glass substrate includes a dealkalized layer in a surface on a coating side; and (iv) an underlayer is provided between the glass substrate and the coating.