EB-PVD Columnated Vapor Stream Plasma Control

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Solution Overview

Problem

Existing electron beam vapor deposition processes face challenges in achieving desirable microstructural morphology and orientation with uniform thickness on work pieces due to high temperature requirements that degrade underlying base alloys and fluctuating energy states, leading to plasma formation and poor coating quality.

Innovation Solution

The process involves reducing power density in the source coating material melt pool and controlling pressure to stabilize the deposition, using sub-sonic gas jets to shape the vapor cloud and direct it towards the work piece, and adjusting the energy state to promote columnar coating microstructures at lower temperatures and pressures.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Stability of the object's composition

If high beam power density is used to increase vapor energy state, then coating morphology and orientation are improved, but plasma formation occurs reducing process stability

Engineering Contradiction:
Improvecoating morphology stabilityVSAvoidprocess stability
Core Design Contradiction:
Stability of the object's compositionVSReliability

Solution Approach 1:

The patent changes the physical state parameters of the vapor by introducing a supersonic gas stream, transforming the vapor from a static cloud to a directed supersonic flow. This parameter change allows the system to maintain high vapor energy state without requiring excessive beam power density, thereby preventing plasma formation while preserving coating morphology quality.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The supersonic gas stream acts as an intermediary between the vapor source and the substrate. It carries the vapor molecules in a directed flow, enabling controlled deposition with consistent energy state. This intermediary mechanism stabilizes the deposition process by preventing the vapor from stagnating and forming plasma, while still delivering the necessary energy for high-quality coating morphology.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Strength

If high temperature is applied to ensure columnar coating morphology, then coating durability is improved, but underlying base alloy strength is degraded

Engineering Contradiction:
Improvecoating durabilityVSAvoidbase alloy temperature
Core Design Contradiction:
StrengthVSTemperature

Solution Approach 1:

The patent changes the energy delivery mechanism by using a supersonic gas stream to transport vapor with high kinetic energy. This allows the deposition process to achieve columnar coating morphology and high coating durability without requiring high substrate temperature, thereby protecting the base alloy strength while still forming durable coatings.

Inventive Principle:
Principle #35Parameter changes

3Use of energy by moving object

If beam power density is increased to improve vapor energy state, then coating quality is improved, but plasma formation robs power from the beam reducing power delivery

Engineering Contradiction:
Improvevapor energy stateVSAvoidbeam power delivery
Core Design Contradiction:
Use of energy by moving objectVSPower

Solution Approach 1:

The supersonic gas stream serves as a mediator that transfers vapor molecules from the source to the substrate with controlled energy. Instead of relying on high beam power density to directly energize the vapor, the gas stream carries the vapor in a directed flow, maintaining vapor energy state while preventing plasma formation that would otherwise rob power from the beam.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent employs pneumatic principles by using a supersonic gas stream to transport and energize the vapor. The high-velocity gas flow provides the necessary energy state to the vapor molecules through kinetic energy transfer, eliminating the need for excessive beam power density and preventing plasma formation while maintaining high vapor energy state for quality coating deposition.

Inventive Principle:
Principle #29Pneumatics and hydraulics

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enlarges the process parameter window, improves coating structure stability, and enhances thickness uniformity on complex surfaces by reducing plasma generation and maintaining energy state consistency, resulting in improved durability and uniformity of ceramic coatings.

Implementation Method 1

electron beam physical vapor deposition (EB-PVD) involves using an electron beam to melt and evaporate a source coating material

Methodology Applied
Scientific EffectEvaporation: Evaporation

Implementation Method 2

The energy state of the evaporated material, i.e., vapor, can be increased by increasing the electron beam power density in the molten pool of the source coating material

Methodology Applied
Scientific EffectElectron beam heating: Electron Beam

Implementation Method 3

controlling the vapor cloud by injecting a stream of process gas thereinto downstream from the source coating material and shaping the vapor cloud with the stream of process gas

Methodology Applied
Scientific EffectGas flow:

Data Source

PatentEP3296421B1Ebpvd columnated vapor stream
Publication Date: 2021.12.29 RTX CORP
  • EP3296421B1 patent drawingFigure 1~2
  • EP3296421B1 patent drawingFigure 3~8
  • EP3296421B1 patent drawingFigure 9~10

AI summary

An electron beam vapor deposition process for depositing coatings includes placing a source coating material (34) in a crucible (32) of a vapor deposition apparatus; energizing the source coating material (34) with an electron beam raster pattern that delivers a controlled power density to the material (34) in the crucible (32) forming a vapor cloud (42) from the source coating material (34); and depositing the source coating material (34) onto a surface of a work piece (12).