Ebullated Bed Hydroprocessing with Solvent Deasphalting

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Solution Overview

Problem

Refineries face limitations in processing heavy crudes due to existing crude distillation column constraints, which hinder efficient conversion of carbon-rich hydrocarbons to carbon-poor hydrocarbons, and result in high asphaltene precipitation and increased operational costs.

Innovation Solution

Integrating virgin crude with synthetic crude in an ebullated bed hydroprocessing fractionation section, where the combined effluent is recycled and processed in a common atmospheric and vacuum distillation unit, allowing for higher conversion rates and reduced asphaltene precipitation by using virgin crude as a solvent, thereby enhancing reactor efficiency and reducing capital and operational expenditures.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If existing crude distillation columns are used to process heavy crudes, then operational constraints are imposed, but conversion efficiency of carbon-rich hydrocarbons to carbon-poor hydrocarbons is limited

Engineering Contradiction:
Improveconversion efficiencyVSAvoidoperational constraints
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The patent combines ebullated bed hydroprocessing with a common fractionation section that processes both virgin crude and synthetic crude together. This merging allows the system to overcome the limitations of existing distillation columns by integrating a conversion process (ebullated bed hydroprocessing) with fractionation, enabling efficient processing of heavy crudes and maximization of white oil products while removing operational constraints through unified processing.

Inventive Principle:
Principle #5Merging (Combining)

2Reliability

If heavy crudes are processed in existing distillation columns, then processing limitations occur, but asphaltene precipitation increases

Engineering Contradiction:
Improveprocessing stabilityVSAvoidasphaltene precipitation
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The patent uses virgin crude as a solvent intermediary when processing heavy crudes. The virgin crude acts as a mediator that prevents asphaltene precipitation by maintaining asphaltenes in solution during the ebullated bed hydroprocessing and fractionation process. This intermediary approach allows stable processing of heavy crudes without the harmful asphaltene precipitation that would otherwise occur.

Inventive Principle:
Principle #24Intermediary (Mediator)

3Productivity

If solvent deasphalting is applied to all crude streams, then conversion is improved, but capital and operational expenditures increase

Engineering Contradiction:
Improveoverall conversionVSAvoidcapital and operational expenditure
Core Design Contradiction:
ProductivityVSQuantity of substance

Solution Approach 1:

The patent applies solvent deasphalting selectively only to a slip stream of the combined vacuum column bottom rather than to all crude streams. This partial action approach achieves the necessary conversion improvement by treating only the portion that requires it, while avoiding the high capital and operational expenditures that would result from applying solvent deasphalting to all streams. The common fractionation section handles the majority of processing without intensive deasphalting.

Inventive Principle:
Principle #16Partial or excessive action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach achieves higher overall conversion of residuum oil, improves fractionation operations, and increases mechanical availability of the system by maintaining turndown ability without additional measures, while optimizing capital and operating expenditures.

Implementation Method 1

ebullated bed reactor effluent stream

Methodology Applied
Scientific EffectFluidization: Fluidisation

Implementation Method 2

common atmospheric and vacuum distillation unit

Methodology Applied
Scientific EffectDistillation: Distillation

Implementation Method 3

three-product cut solvent deasphalting unit (SDU)

Methodology Applied
Scientific EffectSolvent extraction: Liquid-Liquid Extraction

Data Source

PatentUS10836967B2Converting carbon-rich hydrocarbons to carbon-poor hydrocarbons
Publication Date: 2020.11.17 SAUDI ARABIAN OIL CO
  • US10836967B2 patent drawing
  • US10836967B2 patent drawing
  • US10836967B2 patent drawing

AI summary

A system for co-processing crude oil with residuum includes an ebullated bed hydrocracking unit; an atmospheric distillation column fluidly coupled to the ebullated bed hydrocracking unit; a vacuum distillation column fluidly coupled to the atmospheric distillation column and the ebullated bed hydrocracking unit; and a deasphalting unit fluidly coupled to the vacuum distillation column and the ebullated bed hydrocracking unit; and a control system communicably coupled to the ebullated bed hydrocracking unit, the atmospheric distillation column, the vacuum distillation column, and the deasphalting unit. The control system is configured to perform operations including operating the deasphalting unit to produce a first cut that includes deasphalting oil, a second cut that includes resin oil, and a third cut that includes asphaltene.