ECA Electrolyte Recirculation for Concentrated Chlorine and Alkaline Solutions

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Solution Overview

Problem

Existing electro-chemical activation (ECA) systems for producing chlorine and alkaline solutions result in dilute concentrations, which are insufficient for maintaining detergent levels in washing machines due to dilution by fresh water intake, necessitating the development of a system for on-demand production of highly concentrated solutions.

Innovation Solution

An ECA system comprising an anode, cathode, and neutralization chambers, with recirculation of anodic and cathodic electrolytes to produce concentrated chlorine and alkaline solutions, utilizing membranes to control ion migration and an electronic controller for pH regulation, allowing for the creation of solutions with concentrations up to 14% chlorine and 50% alkalinity.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Quantity of substance

If existing ECA systems produce chlorine and alkaline solutions, then cleaning solutions are available for washing machines, but the solutions are dilute (chlorine concentration less than 0.02% and alkalinity less than 0.02% Na2O) and unable to maintain detergent concentration due to fresh water dilution

Engineering Contradiction:
Improveconcentration of chlorine and alkaline solutionsVSAvoidsystem complexity for recirculation and concentration
Core Design Contradiction:
Quantity of substanceVSDevice complexity

Solution Approach 1:

The system continuously recirculates the electrolyte solution through the electrochemical cell, maintaining continuous generation and concentration of chlorine and alkaline solutions. This continuous circulation allows the solution to reach and maintain high concentrations (up to 14% chlorine and 50% alkalinity) that can withstand dilution by fresh water in washing machines.

Inventive Principle:
Principle #20Continuity of useful action

Solution Approach 2:

The system changes the concentration parameter of the electrolyte solution by recirculating it through the electrochemical cell multiple times. The recirculation process progressively increases the concentration of chlorine and alkaline components until the desired high concentration is achieved, transforming the solution from dilute to concentrated state.

Inventive Principle:
Principle #35Parameter changes

2Quantity of substance

If ECA systems operate continuously to maintain detergent concentration, then concentrated solutions can be produced on demand, but production occurs during machine operation time which reduces productivity

Engineering Contradiction:
Improveconcentration of chlorine and alkaline solutionsVSAvoidwashing machine operational time
Core Design Contradiction:
Quantity of substanceVSProductivity

Solution Approach 1:

The system prepares concentrated cleaning solutions in advance during machine downtime or idle periods. By producing the concentrated chlorine and alkaline solutions beforehand, the washing machine can then use these pre-prepared solutions during its operational cycles without interruption, thus maintaining productivity while achieving the required concentration levels.

Inventive Principle:
Principle #10Preliminary action

3Reliability

If high concentration solutions are produced, then detergent concentration can be maintained despite fresh water dilution, but the system requires recirculation infrastructure that increases device complexity

Engineering Contradiction:
Improvemaintenance of detergent concentrationVSAvoidrecirculation system structure
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The recirculation system serves multiple functions: it concentrates the cleaning solutions, maintains the required concentration levels, and enables on-demand production. By making the recirculation system multi-functional, the patent reduces the need for separate dedicated systems for each function, thereby managing device complexity while achieving reliable concentration maintenance.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The system effectively produces highly concentrated, pH-neutral chlorine and alkaline solutions that maintain desired detergent concentrations, enhancing cleaning performance and reducing resource costs by producing solutions on demand during machine downtime.

Implementation Method 1

The anode is configured to convert water having an alkaline-metal chloride into an anodic electrolyte that includes hypochlorous acid

Methodology Applied
Scientific EffectElectrochemical oxidation: Oxidation

Implementation Method 2

The cathode is configured to convert water into a cathodic electrolyte

Methodology Applied
Scientific EffectElectrochemical reduction: Reduction

Implementation Method 3

The neutralization cathode is configured to remove protons from the anodic electrolyte after it leaves the anode chamber

Methodology Applied
Scientific EffectElectrochemical neutralization: Reduction

Implementation Method 4

the first membrane is configured to hinder the migration of CI- between the anode chamber and the cathode chamber

Methodology Applied
Scientific EffectIon rejection: Semipermeable Membrane

Data Source

PatentEP3458628A1Alkaline and chlorine solutions produced using electro-chemical activation
Publication Date: 2019.03.27 DIVERSEY INC

AI summary

An electro-chemical activation (ECA) system includes an anode chamber, a cathode chamber, and a neutralization chamber. The anode chamber includes an anode configured to convert water having an alkaline-metal chloride into an anodic electrolyte that includes hypochlorous acid. The cathode chamber includes a cathode configured to convert water into a cathodic electrolyte. The neutralization chamber includes a neutralization cathode configured to remove protons from the anodic electrolyte after it leaves the anode chamber. The ECA system is configured to recirculate the anodic electrolyte back through the anode chamber and the neutralization chamber at least one more time to produce a concentrated chlorine solution. The ECA system is further configured to recirculate the cathodic electrolyte back through the cathode chamber at least one additional time to produce a concentrated alkaline solution.