Efflorescent Coated Bleach and Enzyme Granulates for Dishwashing Detergent Stability

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Automatic dishwashing detergents face stability issues due to temperature changes, leading to caking and handling problems, and existing solutions often compromise performance under different temperature conditions.

Innovation Solution

A dishwashing detergent composition comprising at least 9% coated bleach particles with an efflorescent material coating and enzyme granulates containing at least 30% efflorescent material, specifically sodium sulphate, which maintains stability and performance across various temperature cycles.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Stability of the object's composition

If powder is protected from moisture under cold conditions, then caking is prevented, but under hot conditions the same protection causes handling problems

Engineering Contradiction:
Improvepowder stabilityVSAvoidhandling
Core Design Contradiction:
Stability of the object's compositionVSEase of operation

Solution Approach 1:

The patent uses efflorescent materials that change their hydration state based on temperature and humidity conditions. These materials absorb moisture under cold conditions to prevent caking, then release it under hot conditions to maintain handling properties, dynamically adjusting their properties to resolve the contradiction between stability and ease of operation.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The efflorescent materials in the detergent composition automatically regulate moisture content based on environmental conditions without external intervention. They self-adjust by absorbing or releasing water vapor, providing both protection against caking and maintaining handling properties through their inherent hygroscopic characteristics.

Inventive Principle:
Principle #25Self-service

2Stability of the object's composition

If efflorescent material is used to prevent caking under cold conditions, then storage stability is improved, but enzyme activity may be affected under hot conditions

Engineering Contradiction:
Improvestorage stabilityVSAvoidenzyme activity
Core Design Contradiction:
Stability of the object's compositionVSReliability

Solution Approach 1:

The efflorescent material acts as an intermediary between the enzyme granulates and the external environment. It provides a protective microenvironment that buffers temperature and humidity fluctuations, allowing the enzyme to maintain activity while the outer material handles moisture regulation, thus resolving the contradiction between storage stability and enzyme reliability.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The detergent composition has different functional zones: the efflorescent material on the outer surfaces handles moisture regulation and storage stability, while the inner enzyme granulates are protected in a microenvironment that maintains their activity. This spatial differentiation of functions resolves the contradiction between storage stability and enzyme reliability.

Inventive Principle:
Principle #3Local quality

3Reliability

If high level of efflorescent material is used in both bleach particles and enzyme granulates, then temperature cycle resistance is improved, but manufacturing complexity increases

Engineering Contradiction:
Improvetemperature cycle resistanceVSAvoidmanufacturing complexity
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent applies the same efflorescent material strategy to both bleach particles and enzyme granulates, merging the moisture protection approach across different functional components. This unified strategy simplifies the overall manufacturing process compared to developing separate protection systems for each component, while achieving superior temperature cycle resistance.

Inventive Principle:
Principle #5Merging (Combining)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composition provides excellent cleaning performance while being resistant to temperature changes, preventing caking and ensuring stable storage and handling, even under extreme conditions.

Implementation Method 1

the coating of the bleach particles and the enzyme-containing granulates comprise an efflorescent material

Methodology Applied
Scientific EffectEfflorescence: Efflorescence

Implementation Method 2

Some anhydrous materials (hygrocopic materials) have a strong tendency to absorb water vapour from the air, thus becoming hydrated compounds

Methodology Applied
Scientific EffectHygroscopy: Absorption (physical)

Implementation Method 3

the hydrated material forming a crystal bridge between particles reverts to the anhydrous (or less hydrated) form

Methodology Applied
Scientific EffectPhase transition: Phase Change

Implementation Method 4

moisture in the air within the granules can condense at particles contact points and can give rise to hydrated crystal bridges

Methodology Applied
Scientific EffectCrystal bridge formation: Crystallisation

Data Source

PatentEP2216393B1Detergent composition
Publication Date: 2024.04.24 PROCTER & GAMBLE CO
  • EP2216393B1 patent drawing
  • EP2216393B1 patent drawing
  • EP2216393B1 patent drawing

AI summary

An automatic dishwashing detergent composition comprising by weight of the composition: a) at least 9% of coated bleach particles the particles having a coating comprising at least 5% by weight of the particle of an efflorescent material; b) at least 0.5% of granulates containing active enzyme wherein the granulates comprise efflorescent material.