Elastomer Agglomerate Production via High-Pressure Homogenization

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Solution Overview

Problem

Current methods for increasing the average particle size of elastomeric particles for core-shell copolymers, such as ABS copolymers, face challenges including lengthy polymerization times, introduction of impurities, and difficulty in controlling particle size distribution, particularly with pressure agglomeration methods.

Innovation Solution

A high-pressure homogenizer with a valve assembly featuring a Y-shaped cross section and cone-shaped surface is used to control the particle size distribution of elastomer agglomerates, allowing for predictable increases in average particle size without introducing impurities, by adjusting the pressure and flow channel geometry.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Volume of moving object

If the elastomeric particles are subjected to a further polymerisation step using the monomer(s) that were used to form the initial elastomeric particles, then the average particle size is increased, but the polymerisation time required is significantly longer

Engineering Contradiction:
Improveaverage particle sizeVSAvoidpolymerisation time
Core Design Contradiction:
Volume of moving objectVSLoss of time

Solution Approach 1:

The patent replaces the chemical polymerisation process with a mechanical pressure agglomeration process. By applying high pressure (typically 10-100 MPa) to the elastomeric particle slurry, the particles are forced together and fuse to form agglomerates with the desired average particle size. This mechanical approach eliminates the need for lengthy polymerisation reactions while achieving the same particle size enlargement goal.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

2Volume of moving object

If the initial elastomeric particles are subjected to chemical agglomeration by reacting with a chemical such as acrylic acid, then the average particle size is increased, but impurities are introduced that may affect the final properties of the core-shell copolymers

Engineering Contradiction:
Improveaverage particle sizeVSAvoidimpurities
Core Design Contradiction:
Volume of moving objectVSObject-generated harmful factors

Solution Approach 1:

The patent substitutes the chemical agglomeration method with a mechanical pressure-based method. High pressure is applied to the elastomeric particle slurry to induce particle fusion and agglomeration without introducing any chemical reagents. This mechanical approach achieves particle size enlargement while keeping the elastomeric particles free from chemical impurities, ensuring the final core-shell copolymer properties are not compromised.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

3Productivity

If pressure agglomeration is used to increase the average particle size, then the process is relatively fast and does not introduce impurities, but the average particle size of the elastomer agglomerates is difficult to control

Engineering Contradiction:
Improveprocess speedVSAvoidparticle size control
Core Design Contradiction:
ProductivityVSManufacturing precision

Solution Approach 1:

The patent employs parameter optimization to control the particle size distribution during pressure agglomeration. By carefully adjusting key parameters including pressure magnitude (10-100 MPa), pressure duration, slurry composition, and temperature, the process achieves both high productivity and precise control over the average particle size of the elastomer agglomerates. This parameter-based control allows the fast mechanical process to produce consistent, predictable particle sizes suitable for core-shell copolymer synthesis.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This process enables the production of elastomer agglomerates with a desirable particle size distribution, improving the balance of material properties and processability of core-shell copolymers, such as ABS, while avoiding lengthy polymerization and impurity issues.

Implementation Method 1

The slurry is forced through an aperture in a high-pressure homogenizer

Methodology Applied
Scientific EffectPressure: Pressure Increase

Data Source

PatentEP3694635B1A process for production of elastomer agglomerate composition, elastomer agglomerate composition and its use
Publication Date: 2022.12.28 SABIC GLOBAL TECHNOLOGIES BV
  • EP3694635B1 patent drawingFigure 1A~3
  • EP3694635B1 patent drawingFigure 4
  • EP3694635B1 patent drawingFigure 5

AI summary

The invention relates to a process for the production of an elastomer agglomerate composition, comprising: forcing a slurry through an aperture in a valve assembly (1) to obtain the elastomer agglomerate composition; wherein the valve assembly (1) comprises the valve (2) and a seat (3) that are arranged opposite each other to provide a flow channel for the slurry to be homogenized with an emulsifying channel section (5) that is provided with the aperture; wherein the emulsifying flow channel section is arranged at an angle (a) with respect to an axial center line of the valve in a cross sectional view of the valve assembly; and wherein the slurry comprises elastomeric particles in water.