Elastomer Copolymer Formulation for Synergistic Stiffness Gain

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Solution Overview

Problem

Poly(propylene-co-ethylene) elastomer copolymers and poly(ethylene-co-1-octene) block copolymers exhibit insufficient stiffness for certain applications, necessitating a formulation that enhances stiffness beyond the mass-weighted average of their individual stiffness values.

Innovation Solution

A formulation comprising a poly(propylene-co-ethylene) elastomer copolymer with an isotactic segment distribution and a poly(ethylene-co-1-octene) block copolymer, optionally combined with a heterophasic polypropylene material and additives, which increases stiffness through a synergistic effect, characterized by a higher 5%-secant modulus than the mass-weighted average of the individual components.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If poly(propylene-co-ethylene) elastomer copolymer and poly(ethylene-co-1-octene) block copolymer are used separately, then flexibility and processability are maintained, but stiffness is insufficient for certain applications

Engineering Contradiction:
ImprovestiffnessVSAvoidapplication range
Core Design Contradiction:
StrengthVSAdaptability or versatility

Solution Approach 1:

The patent combines poly(propylene-co-ethylene) elastomer copolymer and poly(ethylene-co-1-octene) block copolymer in a formulation where they work synergistically. The composite material achieves stiffness values exceeding the mass-weighted average of individual components, resolving the contradiction between maintaining flexibility and achieving sufficient stiffness for diverse applications.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent optimizes the composition ratios and molecular characteristics of the copolymers to achieve enhanced stiffness. By adjusting parameters such as ethylene content, block length distribution, and copolymer composition, the formulation achieves unexpected stiffness enhancement while maintaining the flexibility and processability of the individual polymers.

Inventive Principle:
Principle #35Parameter changes

2Strength

If the concentration of poly(ethylene-co-1-octene) block copolymer is increased to enhance stiffness, then material stiffness increases, but cost and processing complexity may increase

Engineering Contradiction:
ImprovestiffnessVSAvoidformulation complexity
Core Design Contradiction:
StrengthVSDevice complexity

Solution Approach 1:

The patent identifies optimal concentration ranges for poly(ethylene-co-1-octene) block copolymer that achieve maximum stiffness enhancement with minimal formulation complexity. By optimizing parameters such as block copolymer concentration, block length distribution, and processing conditions, the patent achieves enhanced stiffness without excessive complexity in formulation or manufacturing.

Inventive Principle:
Principle #35Parameter changes

Data Source

PatentEP3519496B1Formulation of elastomer copolymer and block copolymer
Publication Date: 2023.12.06 DOW GLOBAL TECHNOLOGIES LLC

AI summary

A formulation of a poly(propylene-co-ethylene) elastomer copolymer and a poly(ethylene-co-1-octene) block copolymer; a method of making the formulation; a manufactured article comprising or made from the formulation; and a method of using the manufactured article.