Dielectric Elastomer Electrode Composition for Stretchable Conductivity

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Solution Overview

Problem

Dielectric elastomer transducers face challenges in achieving both stretchability and electrical conductivity in their electrode layers, as they need to follow the deformation of the dielectric elastomer layer while maintaining conductivity.

Innovation Solution

The use of carbon black with a specific particle size distribution in the electrode layers, where not less than 95% of the particles fall in the range of 0.15 to 8.0 μm, and a dual peak distribution in particle sizes measured by dynamic light scattering and laser scattering, ensures both high conductivity and elasticity.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional electrode materials (silver nanowires, carbon nanowires, carbon nanotubes) are used to ensure electrical conductivity, then conductivity is improved, but stretchability and flexibility are compromised

Engineering Contradiction:
Improveelectrical conductivityVSAvoidstretchability
Core Design Contradiction:
ReliabilityVSAdaptability or versatility

Solution Approach 1:

The invention changes the particle size parameter of carbon black to a specific range (0.15 to 8.0 μm, with 95% or more of particles falling within this range). This parameter optimization enables the electrode layer to achieve both adequate electrical conductivity and sufficient stretchability, resolving the contradiction between conductivity and flexibility that plagues conventional electrode materials.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention uses a composite structure consisting of carbon black particles dispersed in a binder polymer matrix. This composite material approach allows the electrode layer to combine the electrical conductivity of carbon black with the flexibility and stretchability of the polymer binder, overcoming the limitations of using pure metallic or carbon-based conductive materials.

Inventive Principle:
Principle #40Composite materials

2Reliability

If the electrode layers are made highly conductive, then electrical performance is improved, but the electrode layers become rigid and cannot follow the deformation of the dielectric elastomer layer

Engineering Contradiction:
Improveelectrical conductivityVSAvoidflexibility
Core Design Contradiction:
ReliabilityVSStrength

Solution Approach 1:

By optimizing the carbon black particle size to 0.15 to 8.0 μm (with 95% or more within this range), the invention achieves a balance between conductivity and flexibility. The controlled particle size prevents excessive aggregation that would cause rigidity while maintaining sufficient conductive pathways, allowing the electrode to deform with the dielectric elastomer layer.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention creates local conductive networks through carbon black particle aggregation at optimal scales. The particle size distribution ensures that conductive pathways are formed locally without creating a rigid overall structure, allowing different regions of the electrode to deform independently while maintaining electrical connectivity.

Inventive Principle:
Principle #3Local quality

3Reliability

If carbon black with smaller particle size is used to improve conductivity, then electrical performance is improved, but the electrode layer becomes too rigid and loses stretchability

Engineering Contradiction:
Improveelectrical conductivityVSAvoidstretchability
Core Design Contradiction:
ReliabilityVSEase of operation

Solution Approach 1:

The invention specifies a carbon black particle size range of 0.15 to 8.0 μm with 95% or more of particles within this range. This parameter optimization prevents the electrode from becoming too rigid (which would occur with very fine particles) while maintaining adequate conductivity. The upper limit of 8.0 μm ensures particles are not too large to form effective conductive networks.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This configuration allows for a dielectric elastomer transducer that achieves both high stretchability and electrical conductivity, ensuring consistent performance during expansion and contraction.

Implementation Method 1

The electrode layers contain a binder and carbon black. The carbon black has a particle size distribution as measured by dynamic light scattering in which not less than 95% falls in a range of 0.15 to 8.0 μm

Methodology Applied
Scientific EffectElectrical conduction: Conduction (electrical)

Data Source

PatentUS11904358B2Dielectric elastomer transducer
Publication Date: 2024.02.20 ZEON CORP
  • US11904358B2 patent drawing
  • US11904358B2 patent drawing

AI summary

A dielectric elastomer transducer according to the present invention includes a dielectric elastomer layer, and a pair of electrode layers sandwiching the dielectric elastomer layer. The electrode layers contain a binder and carbon black. The carbon black has a particle size distribution as measured by dynamic light scattering in which not less than 95% falls in a range of 0.15 to 8.0 μm. The carbon black has a particle size as measured by laser scattering ranging from 0.4 to 50 μm. The particle size distribution of the carbon black as measured by dynamic light scattering has a first peak that falls in a first range of 0.15 to 1.0 μm and a second peak that falls in a second range of 1.0 μm to 8.0 μm. This structure achieves both stretchability and electrical conductivity of the electrode layers.