Elastomer Laminate Adhesion via Ethylene-Diene Copolymer

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Solution Overview

Problem

The difference in composition between tire tread and sidewall layers and their adjacent layers leads to reduced adhesion, affecting the resistance of cooked interfaces in tires.

Innovation Solution

A laminate comprising two adjacent layers, where the first layer is a copolymer of ethylene and a 1,3-diene with a high ethylene unit content and a diene elastomer, and the second layer is a diene elastomer with a crosslinking system, enhancing adhesion between the layers.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If different compositions are used for tire tread and sidewall layers to achieve specific functional properties, then the functional performance of each layer is improved, but the adhesion between adjacent layers deteriorates

Engineering Contradiction:
Improvefunctional performanceVSAvoidadhesion between layers
Core Design Contradiction:
ReliabilityVSStrength

Solution Approach 1:

The patent introduces an intermediate layer with a specific copolymer composition (ethylene and 1,3-diene in ratios of 70:30 to 90:10) that acts as a mediator between the tread layer and sidewall layer. This intermediate composition provides chemical compatibility with both adjacent layers, enabling effective adhesion while maintaining the distinct functional properties of each layer. The intermediate layer serves as a bridge that reconciles the compositional differences between tread and sidewall materials.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent modifies the compositional parameters of the intermediate layer by controlling the ethylene-to-1,3-diene ratio and the molecular weight of the copolymer. By adjusting these parameters, the intermediate layer achieves optimal adhesion properties while maintaining compatibility with both the tread and sidewall layers. The specific parameter range (70:30 to 90:10 ethylene-to-1,3-diene ratio) is critical for achieving the desired balance between adhesion and functional performance.

Inventive Principle:
Principle #35Parameter changes

2Strength

If high ethylene content copolymer is used in the first layer to improve adhesion, then the adhesion between layers is enhanced, but the flexibility and elongation properties may deteriorate

Engineering Contradiction:
ImproveadhesionVSAvoidflexibility
Core Design Contradiction:
StrengthVSEase of operation

Solution Approach 1:

The patent optimizes the ethylene content parameter within a specific range (70:30 to 90:10 ethylene-to-1,3-diene ratio) rather than using maximum ethylene content. This controlled parameter change ensures sufficient adhesion while maintaining the flexibility and elongation properties necessary for tire performance. The 1,3-diene component provides the required elasticity and flexibility that would be lost with higher ethylene content.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The intermediate layer uses a composite copolymer structure combining ethylene and 1,3-diene units. This composite material approach allows the layer to exhibit both adhesive properties (from the ethylene component) and flexibility (from the 1,3-diene component). The synergistic combination of the two monomers in specific ratios creates a material that balances adhesion and flexibility requirements.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Improves adhesion and resistance of tire interfaces, enhancing the performance of tire components by optimizing the composition of the laminate layers.

Implementation Method 1

the use of a copolymer of ethylene and a specific 1,3-diene further improves the adhesion of the composition to a diene composition

Methodology Applied
Scientific EffectAdhesion: Adhesive

Data Source

PatentEP4076942B1Elastomer laminate
Publication Date: 2023.12.06 MICHELIN & CO (CIE GEN DES ESTAB MICHELIN)
  • EP4076942B1 patent drawing
  • EP4076942B1 patent drawing
  • EP4076942B1 patent drawing

AI summary

The invention relates to an elastomer laminate comprising at least two adjacent cohesive layers, the first layer consisting of a composition based on 10 to 100 phr of an ethylene copolymer and of a 1,3-diene of formula CH2=CR-CH=CH2, wherein the ethylene units in the copolymer represent more than 50 mol% of the monomer units of the copolymer, the symbol R representing a hydrocarbon chain having 3 to 20 carbon atoms, 0 to 90 phr of a diene elastomer having a percentage by weight of diene units greater than 50%, and of a crosslinking system; the second layer consisting of a composition based on a diene elastomer having a percentage by weight of diene units greater than 50%, and of a crosslinking system. The invention also relates to a pneumatic tire, in particular a pneumatic tire provided with a sidewall comprising said composition.