Electret Microfiber Web Composition for Long-Lasting Filtration Charge

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Solution Overview

Problem

Existing electret webs for aerosol filtration lack improved properties for efficient charge retention and ease of charging using various mechanisms.

Innovation Solution

Incorporating ester-substituted and/or amide-substituted trianilino triazine materials as charge additives in thermoplastic resin blends for non-woven microfiber webs, allowing for enhanced charge retention and ease of charging through methods like DC corona discharge or hydrocharging.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Duration of action of stationary object

If conventional charging methods (DC corona discharge, hydrocharging) are used on standard thermoplastic microfiber webs, then the webs can be charged, but the charge retention capability is relatively short and filtration performance degrades over time

Engineering Contradiction:
Improvecharge retention capabilityVSAvoidfiltration performance stability
Core Design Contradiction:
Duration of action of stationary objectVSReliability

Solution Approach 1:

The patent modifies the chemical composition parameters of the thermoplastic resin by incorporating specific additives (ester-substituted and amide-substituted trianilino triazine materials) that alter the material's electrical properties. This enables the resin to retain electret charge much longer than conventional thermoplastics, maintaining filtration performance over extended periods.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention creates a composite material system by blending charge-enhancing additives into the thermoplastic resin matrix. This composite approach combines the processability of thermoplastics with the long-term charge retention properties of electret materials, achieving both ease of manufacture and sustained performance.

Inventive Principle:
Principle #40Composite materials

2Duration of action of stationary object

If charge-enhancing additives are incorporated into thermoplastic resin, then charge retention is improved, but the complexity of material formulation increases

Engineering Contradiction:
Improvecharge retention capabilityVSAvoidmaterial formulation complexity
Core Design Contradiction:
Duration of action of stationary objectVSDevice complexity

Solution Approach 1:

The patent specifies particular chemical structure parameters for the charge-enhancing additives (ester-substituted and amide-substituted trianilino triazine materials), which standardize the formulation process. By defining specific chemical families rather than allowing arbitrary additives, the invention manages complexity while achieving improved charge retention.

Inventive Principle:
Principle #35Parameter changes

3Ease of manufacture

If existing thermoplastic materials are used without charge additives, then the material is easy to process and manufacture, but the electret charge retention is insufficient for long-term filtration efficiency

Engineering Contradiction:
Improveprocessing easeVSAvoidcharge retention capability
Core Design Contradiction:
Ease of manufactureVSDuration of action of stationary object

Solution Approach 1:

The invention maintains the base thermoplastic resin as the continuous phase, preserving its excellent processability and ease of manufacture. The charge-enhancing additives are dispersed within this matrix in controlled amounts, providing long-term charge retention without significantly complicating the manufacturing process. The composite structure allows standard melt-blowing and processing techniques to be used.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The electret webs exhibit improved filtration performance with long charge retention capability and ease of charging, maintaining high filtration efficiency even after accelerated aging tests.

Implementation Method 1

An electret is a dielectric material exhibiting a quasi-permanent electrical charge. Electrets are useful in a variety of devices including, e.g. cling films, air filters, filtering facepieces, and respirators

Methodology Applied
Scientific EffectElectret: Electret

Implementation Method 2

Other methods include, for example, charging the fibers after the web is formed, by means of a DC corona discharge

Methodology Applied
Scientific EffectCorona discharge: Corona Discharge

Implementation Method 3

Recently, a method in which jets of water or a stream of water droplets impinge on a non-woven web at a pressure sufficient to provide filtration enhancing electret charge has been described (hydrocharging)

Methodology Applied
Scientific EffectHydrocharging:

Implementation Method 4

These charge enhancing additives provide electret webs that are easy to charge by a variety of different charging mechanisms such as DC corona discharge, hydrocharging or a combination thereof. In addition, the electret webs containing charge-enhancing additives have relatively long charge retention capability

Methodology Applied
Scientific EffectElectrostatic charge retention: Electrostatics

Data Source

PatentUS8529671B2Electret webs with charge-enhancing additives
Publication Date: 2013.09.10 3M INNOVATIVE PROPERTIES CO
  • US8529671B2 patent drawing
  • US8529671B2 patent drawing
  • US8529671B2 patent drawing

AI summary

Electret webs are presented which include a blend of a thermoplastic resin and a charge additive. The charge additives include ester-substituted and amide-substituted trianilino triazine materials. The webs prepared from the blends may be in the form of films or non-woven fibrous webs. Non-woven microfiber webs are useful as filtration media.