Electret Web Composition for Single-Step Corona Charging

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Solution Overview

Problem

There is a need for electret webs with improved properties that can be easily charged through various mechanisms such as tribocharging, corona discharge, or hydrocharging, and that exhibit enhanced filtration performance without requiring additional charging methods.

Innovation Solution

The development of electret webs comprising a blend of a thermoplastic resin and a charge-enhancing additive, specifically fused aromatic urea or thiourea, which can be synergistically enhanced with hindered amine light stabilizer compounds, allowing for efficient charging and improved filtration capabilities.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional electret webs are used without charge-enhancing additives, then the charging process requires multiple methods (tribocharging, corona discharge, hydrocharging), but the charging efficiency and filtration performance are limited

Engineering Contradiction:
Improvefiltration performanceVSAvoidcharging process complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent modifies the chemical composition parameters of the electret web by incorporating fused aromatic urea or thiourea compounds at concentrations of 0.01-10% by weight. This compositional parameter change enables the material to achieve enhanced charging efficiency and filtration performance through a single corona discharge process, eliminating the need for multiple charging methods while improving reliability

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite material system by combining thermoplastic polymers (such as polypropylene, polyester, or polyacrylonitrile) with fused aromatic urea or thiourea charge-enhancing additives. This composite structure synergistically combines the structural properties of the polymer matrix with the charge-enhancing properties of the fused aromatic compounds, enabling effective filtration performance with simplified charging processes

Inventive Principle:
Principle #40Composite materials

2Ease of operation

If multiple charging methods are applied to electret webs, then charging can be achieved, but the process time and manufacturing complexity increase

Engineering Contradiction:
Improvecharging easeVSAvoidcharging process time
Core Design Contradiction:
Ease of operationVSLoss of time

Solution Approach 1:

By changing the chemical composition to include fused aromatic urea or thiourea compounds, the material's charge acceptance properties are fundamentally altered. This enables the electret web to achieve sufficient charging through a single corona discharge process, reducing both the number of operational steps and the total charging time while improving ease of operation

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The charge-enhancing additives are incorporated into the electret web during the manufacturing process, before the charging step. This preliminary incorporation of functional additives ensures that the material is pre-prepared to accept and retain electrical charge efficiently, eliminating the need for subsequent multiple charging operations and reducing overall process time

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The electret webs demonstrate enhanced charging efficiency and filtration performance, with the ability to be charged by DC corona discharge alone, and maintain effective filtration properties even after aging, as evidenced by increased Quality Factor values and penetration ratios.

Implementation Method 1

An electret is a dielectric material that exhibits a quasi-permanent electrical charge. Electrets are useful in a variety of devices including, e.g. cling films, air filters, filtering facepieces, and respirators

Methodology Applied
Scientific EffectElectret: Electret

Implementation Method 2

charging the fibers after the web is formed, by means of a corona discharge or imparting a charge to the fiber mat by means of carding and/or needle tacking (tribocharging)

Methodology Applied
Scientific EffectTribocharging: Triboelectric Effect

Implementation Method 3

charging the fibers after the web is formed, by means of a corona discharge

Methodology Applied
Scientific EffectCorona discharge: Corona Discharge

Implementation Method 4

a method in which jets of water or a stream of water droplets impinge on a non-woven web at a pressure sufficient to provide filtration enhancing electret charge has also been described (hydrocharging)

Methodology Applied
Scientific EffectHydrocharging:

Data Source

PatentEP3157650B1Electret webs with charge-enhancing additives
Publication Date: 2018.04.11 3M INNOVATIVE PROPERTIES CO
  • EP3157650B1 patent drawing
  • EP3157650B1 patent drawing
  • EP3157650B1 patent drawing

AI summary

Electret webs include a thermoplastic resin and a charge-enhancing additive. The charge-enhancing additive is a fused aromatic thiourea, a fused aromatic urea compound, or a combination thereof. The change-enhancing additive may also include a hindered amine light stabilizer compound. The electret webs may be a non-woven fibrous web or a film. The electret webs are suitable for use as filter media.