Electret Web Composition for Stable Single-Step Filter Charging

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Solution Overview

Problem

Existing electret webs for filtration lack enhanced charging capabilities, requiring multiple charging mechanisms and not efficiently utilizing charge-enhancing additives to improve filtration performance.

Innovation Solution

Development of electret webs comprising a thermoplastic resin blended with a divalent metal-containing substituted-mercaptobenzimidazolate salt, allowing for easy charging via tribocharging, corona discharge, or hydrocharging, and capable of being charged solely by DC corona discharge without additional methods.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If multiple charging mechanisms are used to charge electret webs, then charge stability is improved, but device complexity increases

Engineering Contradiction:
Improvecharge stabilityVSAvoidcharging mechanism complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent changes the chemical composition parameter of the polymer by incorporating charge-enhancing additives (0.1-10 wt% of compounds with high electron affinity such as fullerenes, metal oxides, or electron-accepting polymers). This compositional modification enables the material to achieve stable charge retention through a single charging mechanism, eliminating the need for multiple charging methods while maintaining charge stability.

Inventive Principle:
Principle #35Parameter changes

2Productivity

If charge-enhancing additives are incorporated into the polymer, then charging efficiency is improved, but manufacturing complexity increases

Engineering Contradiction:
Improvecharging efficiencyVSAvoidmanufacturing process simplicity
Core Design Contradiction:
ProductivityVSEase of manufacture

Solution Approach 1:

The charge-enhancing additives are incorporated into the polymer matrix during the extrusion and web formation process, before the charging step. This preliminary incorporation ensures uniform distribution of the additives throughout the web, enabling efficient charging in a single pass without requiring subsequent additive application steps or complex multi-stage manufacturing processes.

Inventive Principle:
Principle #10Preliminary action

3Ease of manufacture

If electret webs use conventional polymer composition, then manufacturing is simpler, but filtration performance is reduced

Engineering Contradiction:
Improvemanufacturing simplicityVSAvoidfiltration performance
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The patent creates a composite material system by combining conventional thermoplastic polymers (such as polypropylene or polyester) with charge-enhancing additives in specific concentrations (0.1-10 wt%). This composite structure maintains the ease of manufacturing inherent in conventional polymers while dramatically improving filtration performance through enhanced charge retention and particle capture efficiency, achieving both simplicity and high performance.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The electret webs demonstrate enhanced filtration performance with improved charge stability and efficiency, as evidenced by increased Quality Factor values and retention of filtration performance after X-ray discharge testing, indicating effective charge retention and filtration enhancement.

Implementation Method 1

An electret is a dielectric material that exhibits a quasi-permanent electrical charge. Electrets are useful in a variety of devices including, for example, cling films, air filters, filtering facepieces, and respirators

Methodology Applied
Scientific EffectElectrostatic charge: Electrostatics

Implementation Method 2

The performance of microfibrous webs used for aerosol filtration can be improved by imparting an electrical charge to the fibers, forming an electret material. In particular, electrets are effective in enhancing particle capture in aerosol filters

Methodology Applied
Scientific EffectElectrostatic attraction: Electrostatics

Implementation Method 3

Other methods include, for example, charging the fibers after the web is formed, by means of a corona discharge

Methodology Applied
Scientific EffectCorona discharge: Corona Discharge

Implementation Method 4

Other methods include, for example, charging the fibers after the web is formed, by means of carding and/or needle tacking (tribocharging)

Methodology Applied
Scientific EffectTribocharging: Triboelectric Effect

Implementation Method 5

In addition, a method in which jets of water or a stream of water droplets impinge on a non-woven web at a pressure sufficient to provide filtration enhancing electret charge has also been described (hydrocharging)

Methodology Applied
Scientific EffectHydrocharging:

Data Source

PatentEP2938420B1Electret webs with charge-enhancing additives
Publication Date: 2018.03.07 3M INNOVATIVE PROPERTIES CO
  • EP2938420B1 patent drawing
  • EP2938420B1 patent drawing
  • EP2938420B1 patent drawing

AI summary

Electret webs include a thermoplastic resin and a charge-enhancing additive. The charge-enhancing additive is a divalent metal-containing substituted-mercaptobenzimidazolate salt. The electret webs may be a non-woven fibrous web or a film. The electret webs are suitable for use as filter media.