Electret Web Composition for Stable High-Efficiency Filtration

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Solution Overview

Problem

There is a need for electret webs with improved properties that can be easily charged through various mechanisms such as tribocharging, corona discharge, or hydrocharging, and that exhibit enhanced filtration performance.

Innovation Solution

The development of electret webs comprising a blend of a thermoplastic resin and a charge-enhancing additive, specifically fused aromatic urea or thiourea, which can be charged effectively by DC corona discharge alone and when combined with hindered amine light stabilizer compounds, demonstrating a synergistic effect.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional electret webs are charged using multiple charging mechanisms (tribocharging, corona discharge, hydrocharging), then charging effectiveness is improved, but device complexity and process difficulty increase

Engineering Contradiction:
Improvecharging effectivenessVSAvoidprocess complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent changes the chemical composition parameter of the electret web by incorporating charge-enhancing additives (metal salts of long chain organic acids) into the polymer matrix. This parameter change enables the material to achieve effective charging with simpler, single-stage charging processes, resolving the contradiction between charging effectiveness and process complexity

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite material system combining polymer base material with charge-enhancing additives (metal salts). This composite structure inherently possesses improved charge retention and charging efficiency, allowing effective electret formation without requiring multiple complex charging mechanisms

Inventive Principle:
Principle #40Composite materials

2Reliability

If electret webs are charged to high charge levels for improved filtration performance, then filtration effectiveness is improved, but charge stability and resistance to charge loss deteriorate

Engineering Contradiction:
Improvefiltration effectivenessVSAvoidcharge stability
Core Design Contradiction:
ReliabilityVSStability of the object's composition

Solution Approach 1:

The patent modifies the chemical composition by adding charge-enhancing additives (metal salts of long chain organic acids) that specifically improve charge stability. These additives form stable complexes within the polymer that resist charge loss mechanisms, allowing the electret to maintain high charge levels and filtration effectiveness over time without compromising stability

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The charge-enhancing additives act as sacrificial stabilizers that protect the main electret charge. These additives can undergo chemical changes or degradation that prevent charge loss from the primary electret population, effectively sacrificing the additive stability to preserve the overall charge stability and filtration performance

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

3Productivity

If charge-enhancing additives are added to improve charging efficiency, then charging efficiency is improved, but material composition complexity increases

Engineering Contradiction:
Improvecharging efficiencyVSAvoidmaterial composition complexity
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The patent introduces charge-enhancing additives (metal salts of long chain organic acids) as a specific compositional parameter change. These additives are incorporated in controlled amounts during polymer processing, providing significant charging efficiency improvements while maintaining relatively simple material formulations and processing procedures

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The charge-enhancing additives act as intermediary substances that facilitate the charging process. They mediate between the charging mechanism and the polymer matrix, enabling more efficient charge transfer and retention without requiring fundamental changes to the base polymer composition or processing methodology

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The electret webs show improved charging efficiency and filtration performance, with the ability to maintain filtration effectiveness even after aging, as evidenced by increased Quality Factor values and penetration ratios, indicating enhanced electrostatic charge retention and filtration capabilities.

Implementation Method 1

The electret webs may be charged by any suitable charging mechanism including, e.g. tribocharging, corona discharge or hydrocharging

Methodology Applied
Scientific EffectTribocharging: Triboelectric Effect

Implementation Method 2

The electret webs may be charged by any suitable charging mechanism including, e.g. tribocharging, corona discharge or hydrocharging

Methodology Applied
Scientific EffectCorona discharge: Corona Discharge

Implementation Method 3

The electret webs may be charged by any suitable charging mechanism including, e.g. tribocharging, corona discharge or hydrocharging

Methodology Applied
Scientific EffectHydrocharging:

Data Source

PatentUS10240269B2Electret webs with charge-enhancing additives
Publication Date: 2019.03.26 3M INNOVATIVE PROPERTIES CO
  • US10240269B2 patent drawing
  • US10240269B2 patent drawing
  • US10240269B2 patent drawing

AI summary

Electret webs include a thermoplastic resin and a charge-enhancing additive. The charge-enhancing additive is a fused aromatic thiourea, a fused aromatic urea compound, or a combination thereof. The change-enhancing additive may also include a hindered amine light stabilizer compound. The electret webs may be a non-woven fibrous web or a film. The electret webs are suitable for use as filter media.