Electric Calcination Device for Cement Clinker CO2 Capture

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Solution Overview

Problem

The cement industry is a significant emitter of CO2, primarily due to the decarbonation of raw meal during cement clinker production, which poses environmental concerns related to global warming and ocean acidification.

Innovation Solution

A method involving the preheating of cement raw meal, followed by partial decarbonation using electrical energy in a calcination device, where the decarbonated product is reintroduced into the rotary kiln, and the CO2 is drawn off for potential processing or sequestration.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Use of energy by moving object

If fossil fuels or alternative fuels are burned in the rotary kiln for calcination, then the thermal energy requirement is met, but CO2 emissions increase significantly

Engineering Contradiction:
Improvethermal energy for decarbonationVSAvoidCO2 emissions
Core Design Contradiction:
Use of energy by moving objectVSObject-generated harmful factors

Solution Approach 1:

The decarbonation process is divided into two separate stages: (1) pre-calcination in a pre-calciner using fossil/alternative fuels to perform partial decarbonation, and (2) final decarbonation in the rotary kiln. This segmentation allows the majority of CO2-emitting decarbonation to occur in the pre-calciner, while the rotary kiln focuses on high-temperature sintering with reduced fuel consumption and lower CO2 emissions.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The pre-calciner performs preliminary decarbonation of the raw meal before it enters the rotary kiln. By conducting the energy-intensive decarbonation reaction (CaCO3 → CaO + CO2) in advance in the pre-calciner, the amount of CO2 generated during the subsequent rotary kiln operation is significantly reduced, as less limestone needs to be decarbonated at that stage.

Inventive Principle:
Principle #10Preliminary action

2Object-generated harmful factors

If carbon capture and sequestration methods are implemented to separate CO2 from flue gases, then CO2 emissions are reduced, but capital and operating expenditures increase significantly

Engineering Contradiction:
ImproveCO2 emissionsVSAvoidseparation plants and capital expenditure
Core Design Contradiction:
Object-generated harmful factorsVSDevice complexity

Solution Approach 1:

The harmful CO2 is extracted and separated from the useful product (calcined clay) in the cyclone separator. The CO2-rich gas phase is drawn off separately through the gas outlet, while the decarbonated solid particles are recovered and returned to the process. This natural separation based on phase and density differences eliminates the need for complex CO2 separation plants.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The system uses its own operational characteristics to achieve separation: the decarbonation process naturally produces CO2 gas that rises and can be drawn off, while the decarbonated solid particles settle and are returned. The process itself generates the separation opportunity, requiring no external complex separation infrastructure.

Inventive Principle:
Principle #25Self-service

3Object-generated harmful factors

If the entire raw meal flow is decarbonated in the pre-calciner, then CO2 emissions from the rotary kiln are reduced, but the pre-calciner becomes overloaded and processing efficiency decreases

Engineering Contradiction:
ImproveCO2 emissions from rotary kilnVSAvoidpre-calciner processing capacity
Core Design Contradiction:
Object-generated harmful factorsVSProductivity

Solution Approach 1:

Instead of performing complete decarbonation in the pre-calciner, only partial decarbonation is carried out there (typically 50-70% of total decarbonation). This partial action prevents overloading the pre-calciner while still achieving significant CO2 emission reduction in the rotary kiln, as the majority of decarbonation occurs in the pre-calciner stage.

Inventive Principle:
Principle #16Partial or excessive action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach reduces the CO2 footprint of cement production by utilizing electricity for decarbonation, eliminating fossil fuel combustion, and enabling direct CO2 capture for further processing or sequestration, thus minimizing capital and operating expenditures.

Implementation Method 1

the calcination device is heated by electrical energy

Methodology Applied
Scientific EffectElectrical heating: Heating

Implementation Method 2

at least partially decarbonated in the calcination device in order to obtain an at least partially decarbonated product and CO2

Methodology Applied
Scientific EffectDecarbonation: Decomposition (biological)

Implementation Method 3

preheating cement raw meal in a preheater string, said preheater string comprising a plurality of preheater stages

Methodology Applied
Scientific EffectHeat transfer: Conduction (thermal)

Implementation Method 4

introducing the pre-calcined product into a rotary kiln for calcining the pre-calcined product to obtain cement clinker

Methodology Applied
Scientific EffectCalcination: Heating

Data Source

PatentEP4259591B1Method of producing clinker from cement raw meal
Publication Date: 2025.01.29 HOLCIM TECHNOLOGY LTD
  • EP4259591B1 patent drawingFigure 1

AI summary

Method of producing clinker form cement raw meal A method of producing clinker from cement raw meal, comprising the steps of: - preheating cement raw meal in a preheater string, said preheater string comprising a plurality of preheater stages, - pre-calcining preheated raw meal in a pre-calciner to obtain a pre-calcined product, - introducing the pre-calcined product into a rotary kiln for calcining the pre-calcined product to obtain cement clinker, wherein a partial flow of at least partly preheated raw meal is diverted from the preheater string, introduced into a calcination device and at least partially decarbonated in the calcination device in order to obtain an at least partially decarbonated product and CO2, wherein the calcination device is heated by electrical energy, and wherein the at least partially decarbonated product is fed into the rotary kiln and the CO2 is drawn off from the calcination device.