Electroactive Actuator with Zwitterion Polymer Electrolyte

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Solution Overview

Problem

Conventional electroactive actuators suffer from poor performance at low voltages, with slow response times and limited displacement, making them unsuitable for bio-mimic devices that require quick and large movements at low driving voltages, and they also face issues with electrochemical stability over long operations.

Innovation Solution

An electroactive actuator is developed using a polymer electrolyte with a self-assembled block copolymer, a conductive block, a non-conductive block, and a zwitterion, which forms a single ion conductor, enhancing ion conductivity and dielectric constant, allowing for rapid cation transport and high reactivity at low voltages.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Speed

If conventional actuators are used, then they can operate at low voltage, but the response speed is slow and displacement is limited

Engineering Contradiction:
Improveresponse speedVSAvoidoperational stability
Core Design Contradiction:
SpeedVSReliability

Solution Approach 1:

The patent changes the chemical and physical parameters of the polymer electrolyte by incorporating zwitterions and controlling the microstructure (lamellar, hexagonal, gyroid phases) to achieve high ion conductivity and fast response at low operating voltages, resolving the contradiction between speed and stability

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses composite polymer electrolyte materials combining zwitterionic compounds with specific polymer matrices to achieve both fast ion transport (high speed) and electrochemical stability (high reliability) simultaneously

Inventive Principle:
Principle #40Composite materials

2Duration of action of stationary object

If the actuator operates for long time, then it maintains initial performance, but electrochemical stability is limited at driving voltage

Engineering Contradiction:
Improvelongtime operation stabilityVSAvoidelectrochemical stability
Core Design Contradiction:
Duration of action of stationary objectVSReliability

Solution Approach 1:

The patent modifies the electrochemical parameters of the polymer electrolyte through zwitterion incorporation and microstructure control, enabling stable operation at low driving voltages without degradation, thus achieving both long duration and high reliability

Inventive Principle:
Principle #35Parameter changes

3Quantity of substance

If polymer electrolyte has high dielectric constant, then cation dissociation rate increases, but material complexity increases

Engineering Contradiction:
Improvecation dissociation rateVSAvoidpolymer electrolyte structure
Core Design Contradiction:
Quantity of substanceVSDevice complexity

Solution Approach 1:

The patent changes the dielectric parameter of the polymer electrolyte by incorporating zwitterions with high dipole moments, achieving high cation dissociation rates while the self-assembled microstructure provides a systematic and controllable approach rather than random complexity

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The actuator achieves a quick response time of several tens of milliseconds and significant displacement at voltages less than or equal to 1V, improving its suitability for small devices like micro sensors and artificial muscles, while maintaining durability and high reactivity.

Implementation Method 1

a high dielectric constant so having a high cation dissociation rate

Methodology Applied
Scientific EffectDielectric constant: Dielectric Permittivity

Implementation Method 2

a compound to form a single ion conductor with the self-assembled block copolymer

Methodology Applied
Scientific EffectIon dissociation: Electrolyte

Implementation Method 3

a self-assembled block copolymer including a conductive block and a non-conductive block

Methodology Applied
Scientific EffectSelf-assembly: Self-Assembly

Implementation Method 4

a compound to form a single ion conductor with the self-assembled block copolymer

Methodology Applied
Scientific EffectIon conduction: Conduction (electrical)

Implementation Method 5

an electrode configured to apply an electric field to the polymer electrolyte

Methodology Applied
Scientific EffectElectric field: Electric Field

Data Source

PatentEP3282494B1Electroactive actuator, mechanical device including the same, and polymer electrolyte
Publication Date: 2020.07.22 POSTECH ACADEMY INDUSTRY FOUNDATION
  • EP3282494B1 patent drawingFigure 1~2
  • EP3282494B1 patent drawingFigure 3~4
  • EP3282494B1 patent drawingFigure 5

AI summary

An electroactive actuator includes a polymer electrolyte and an electrode configured to apply an electric field to the polymer electrolyte, the polymer electrolyte includes a self-assembled block copolymer including a conductive block and a non-conductive block, a compound to form a single ion conductor with the self-assembled block copolymer, and a zwitterion. A mechanical device including the electroactive actuator and a polymer electrolyte are also disclosed.