Electrochemical Cement Production via Acid-Base Gradient

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Solution Overview

Problem

Traditional cement production methods, such as thermal calcination, result in high CO2 emissions, and there is a need for more sustainable processes that reduce greenhouse gas production while maintaining cement quality.

Innovation Solution

The development of electrochemical systems that produce base and acid in a spatially varying chemical composition gradient, allowing for the collection and reaction of these chemicals to form metal hydroxides, which can be used in cement production, powered by renewable energy sources to minimize carbon footprint.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If thermal calcination is used for cement production, then cement can be produced efficiently, but CO2 emissions increase significantly

Engineering Contradiction:
Improvecement production efficiencyVSAvoidCO2 emissions
Core Design Contradiction:
ProductivityVSObject-generated harmful factors

Solution Approach 1:

The invention changes the fundamental parameter of the chemical reaction method from thermal calcination to electrochemical reaction. By applying electrical energy to drive the decomposition of carbonate minerals and subsequent cement hydration reactions, the process eliminates the need for high-temperature heating that generates CO2, while maintaining cement production efficiency through controlled electrochemical pathways

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention replaces the thermal/mechanical calcination system with an electrochemical system. Instead of using heat and mechanical grinding to produce cement, the process uses electrochemical reactions at electrodes to transform carbonate minerals into cement compounds, substituting a thermal-mechanical process with an electrical-chemical process that does not generate CO2 emissions

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

2Object-generated harmful factors

If electrochemical systems are used to produce base and acid, then carbon emissions are reduced, but system complexity increases

Engineering Contradiction:
Improvecarbon emissionsVSAvoidsystem complexity
Core Design Contradiction:
Object-generated harmful factorsVSDevice complexity

Solution Approach 1:

The electrochemical system is segmented into distinct functional zones: an anode compartment for acid generation, a cathode compartment for base generation, and intermediate reaction zones. This segmentation allows each electrode to perform its specific function independently, simplifying the control and operation of the overall system while maintaining the ability to produce both acid and base simultaneously for cement synthesis

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The electrochemical reactor is designed with multi-functionality, serving as both an acid generator and a base generator within a single device. The same electrochemical cell structure produces both H+ ions at the anode and OH- ions at the cathode, which are then used for different stages of cement production, eliminating the need for separate acid and base production systems and thereby reducing overall system complexity

Inventive Principle:
Principle #6Universality (Multi-functionality)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach reduces net carbon emissions by up to 90% compared to traditional methods, offering a more sustainable and environmentally friendly cement production process while maintaining or improving cement quality.

Implementation Method 1

electrolysis (e.g., electrolysis of water)

Methodology Applied
Scientific EffectElectrolysis: Electrolysis

Implementation Method 2

reacting the base with metal ions, such as calcium ions, to produce a metal hydroxide, such as Ca(OH)2

Methodology Applied
Scientific EffectPrecipitation: Precipitation

Data Source

PatentUS12252795B2Chemical reaction devices involving acid and/or base, and related systems and methods
Publication Date: 2025.03.18 MASSACHUSETTS INST OF TECH
  • US12252795B2 patent drawing
  • US12252795B2 patent drawing
  • US12252795B2 patent drawing

AI summary

Chemical reaction devices involving acid and/or base, and related systems and methods, are generally described.